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Abstract Batteries and supercapacitors have emerged as promising candidates for next-generation energy storage technologies. The rapid development of new two-dimensional (2D) electrode materials indicates a new era in energy storage devices. MXenes are a new type of layered 2D transition metal carbides, nitrides, or carbonitrides that have drawn much attention because of their excellent electrical conductivity, electrochemical and hydrophilic properties, large surface area, and attractive topological structure. This review focuses on various synthesis methods to prepare vanadium carbide MXenes with and without etchants like hydrofluoric acid, lithium fluoride, and hydrochloric acid to remove the ‘A’ layers of the MAX phase. The goal is to demonstrate the utilization of a less toxic etching method to achieve MXenes of comparable properties to those prepared by traditional methods. The influence of intercalation on the effect of high interlayer spacing between the MXene layers and the performance of MXenes as supercapacitor and battery electrodes is also addressed in this review. Lastly, the gaps in the current knowledge for vanadium carbide MXenes in synthesis, scalability, and utilization in more energy storage devices were discussed. 

Composite materials have gained increased usage due to their unique characteristic of a high-stiffness-to-weight ratio. High-performing composite materials are produced in the autoclave by applying elevated pressure and temperature. However, the process is characterized by numerous disadvantages, such as long cycle time, massive investment, costly tooling, and excessive energy consumption. As a result, composite manufacturers seek a cheap alternative to reduce cost and increase productivity. The out-of-autoclave (OoA) process manufactures composites by applying vacuum, pressure, and heat outside of the autoclave. This review discusses the common out-of-autoclave processes for various applications. The theoretical and practical merits and demerits are presented, and areas for future research are discussed.

 

Inorganic CsPbIBr₂perovskites have recently attracted enormous attention as a viable alternative material for optoelectronic applications due to their higher efficiency, thermal stability, suitable bandgap, and proper optical absorption. However, the CsPbIBr₂perovskite films fabricated using a one-step deposition technique is usually comprised of small grain size with a large number of grain boundaries and compositional defects. In this work, silver iodide (AgI) will be incorporated as an additive into the CsPbIBr₂perovskite precursor solution to prepare the unique perovskite CsI(PbBr₂)_1-x(AgI)_x.The AgI additive in the precursor solution works as a nucleation promoter which will help the perovskite to grow and merge into a continuous film with reduced defects. With detailed characterizations, we found that incorporating AgI additive resulted in a uniform perovskite film with fewer grain boundaries, increased grain size, crystallinity, optical absorption while decreasing carrier recombination and trap density. Using the AgI in an optimum amount, we fabricated CsPbIBr₂perovskite solar cells (PSCs) with a simple structure and achieved a power conversion efficiency (PCE) of 7.2% with a reduced hysteresis index. This work offers an alternative approach towards preparing high-quality CsPbIBr₂perovskite films for solar cells with higher stability and other optoelectronic applications.

 

Recent developments in sensing technologies have triggered a lot of research interest in exploring novel self-powered, inexpensive, compact and flexible pressure sensors with the potential for structural health monitoring (SHM) applications. Herein, we assessed the performance of an embedded mechanoluminescent (ML) and perovskite pressure sensor that integrates the physical principles of mechanoluminescence and perovskite materials. For a continuous in-situ SHM, it is crucial to evaluate the capabilities of the sensing device when embedded into a composite structure. An experimental study of how the sensor is affected by the embedment process into a glass fiber-reinforced composite has been conducted. A series of devices with and without ML were embedded within a composite laminate, and the signal responses were collected under different conditions. We also demonstrated a successful encapsulation process in order for the device to withstand the composite manufacturing conditions. The results show that the sensor exhibits distinct signals when subjected to different load conditions and can be used for the in-situ SHM of advanced composite structures.