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Real-time detection of intermediate species and final products at the surface and near-surface in interfacial solid–gas reactions is critical for an accurate understanding of heterogeneous reaction mechanisms. In this article, an experimental method that can simultaneously monitor the ultrafast dynamics at the surface and above the surface in photoinduced heterogeneous reactions is presented. This method relies on a combination of mass spectrometry and femtosecond pump–probe spectroscopy. As a model system, the photoinduced reaction of methyl iodide on and above a cerium oxide surface is investigated. The species that are simultaneously detected from the surface and gas-phase present distinct features in the mass spectra, such as a sharp peak followed by an adjacent broad shoulder. The sharp peak is attributed to the species detected from the surface, while the broad shoulder is due to the detection of gas-phase species above the surface, as confirmed by multiple experiments. By monitoring the evolution of the sharp peak and broad shoulder as a function of the pump–probe time delay, transient signals are obtained that describe the ultrafast photoinduced reaction dynamics of methyl iodide on the surface and in the gas-phase. Finally, SimION simulations are performed to confirm the origin of the ions produced on the surface and in the gas-phase.

 

A power take-off based on the inerter pendulum vibration absorber (called IPVA-PTO) is integrated with a spar-floater system to study its hydrodynamic response suppression and wave energy conversion capabilities in regular waves. The hydrodynamics of the spar-floater system is computed using the boundary element method with linear wave theory. With the wave height and wave frequency as the bifurcation parameters, it is found that the system can undergo two bifurcations: period-doubling bifurcation around the first resonance frequency (spar mode) and secondary Hopf bifurcation around the second resonance frequency (floater mode). The period-doubling bifurcation results in an energy transfer between the spar-floater system and the IPVA-PTO for small electrical damping values. As a result, the IPVA-PTO system simultaneously reduces the maximum response amplitude operator (RAO) of the spar and increases the normalized capture width in comparison with the optimal linear benchmark. Experiments performed on a ‘‘dry’’ single-degree-of-freedom system integrated with the IPVAPTO where the base excitation is substituted for the wave excitation verify the simultaneous performance enhancement due to the period-doubling bifurcation. The system performance beyond the period-doubling bifurcation is also experimentally investigated. On the other hand, as the wave height approaches and passes the secondary Hopf bifurcation, the pendulum responses transition from primary harmonic responses to quasi-periodic responses to rotations. When the rotations occur, the IPVA-PTO system increases the maximum normalized capture width threefold to fivefold compared with the optimal linear benchmark, yet slightly increases the RAO around the second resonance frequency. Nevertheless, the RAO remains smaller than the global maximum RAO of the optimal linear benchmark. Finally, parametric studies are performed to study the effects of parameters on the bifurcations. It is observed that by varying the electrical damping, the wave height required for achieving the period-doubling bifurcation can be changed significantly, which can be exploited to stabilize the spar. 

Real-time detection of intermediate species and final products at the surface and near-surface in interfacial solid-gas reactions is critical for an accurate understanding of heterogeneous reaction mechanisms. In this contribution, an experimental method that can simultaneously monitor the ultrafast dynamics at the surface and above the surface in photoinduced heterogeneous reactions is presented. The method relies on a combination of mass spectrometry and femtosecond pump-probe spectroscopy. As a model system, the photoinduced reaction of methyl iodide on and above a cerium oxide surface is investigated. The species that are simultaneously detected from the surface and gas-phase present distinct features in the mass spectra, such as a sharp peak followed by an adjacent broad shoulder. The sharp peak is attributed to the species detected from the surface while the broad shoulder is due to the detection of gas-phase species above the surface, as confirmed by multiple experiments. By monitoring the evolution of the sharp peak and broad shoulder as a function of the pump-probe time delay, transient signals are obtained that describe the ultrafast photoinduced reaction dynamics of methyl iodide on the surface and in gas-phase. Finally, SimION simulations are performed to confirm the origin of the ions produced on the surface and gas-phase.

 

Zinc oxide nanoparticles (ZnO NPs) are versatile and promising, with diverse applications in environmental remediation, nanomedicine, cancer treatment, and drug delivery. In this study, ZnO NPs were synthesized utilizing extracts derived fromAcacia catechu, Artemisia vulgaris, andCynodon dactylon. The synthesized ZnO NPs showed an Ultraviolet–visible spectrum at 370 nm, and X-ray diffraction analysis indicated the hexagonal wurtzite framework with the average crystallite size of 15.07 nm, 16.98 nm, and 18.97 nm for nanoparticles synthesized utilizingA. catechu, A. vulgaris,andC. dactylonrespectively. Scanning electron microscopy (SEM) demonstrated spherical surface morphology with average diameters of 18.5 nm, 17.82 nm, and 17.83 nm for ZnO NPs prepared fromA. catechu, A. vulgaris, andC. dactylon,respectively. Furthermore, ZnO NPs tested againstStaphylococcus aureus, Kocuria rhizophila, Klebsiella pneumonia,andShigella sonneidemonstrated a zone of inhibition of 8 to 14 mm. The cell viability and cytotoxicity effects of ZnO NPs were studied on NIH-3T3 mouse fibroblast cells treated with different concentrations (5 μg/mL, 10 μg/mL, and 50 μg/mL). The results showed biocompatibility of all samples, except with higher doses causing cell death. In conclusion, the ZnO NPs synthesized through plant-mediated technique showed promise for potential utilization in various biomedical applications in the future.

 

The inerter pendulum vibration absorber (IPVA) is integrated between a spar and an annulus floater using a ball-screw mechanism to study its wave energy conversion potential. Hydrodynamic stiffness, added mass, and radiation damping effects on the spar-floater system are characterized using the boundary element method. It is found that a 1:2 internal resonance via a period-doubling bifurcation in the system is responsible for nonlinear energy transfer between the spar-floater system and the pendulum vibration absorber. This nonlinear energy transfer occurs when the primary harmonic solution of the system becomes unstable due to the 1:2 internal resonance phenomenon. The focus of this paper is to analyze this 1:2 internal resonance phenomenon near the first natural frequency of the system. The IPVA system when integrated with the spar-floater system is shown to outperform a linear coupling between the spar and the floater both in terms of the response amplitude operator (RAO) of the spar and one measure of the energy conversion potential of the system. Finally, experiments are performed on the IPVA system integrated with single-degree-of-freedom system (without any hydrodynamic effects) to observe the 1:2 internal resonance phenomenon and the nonlinear energy transfer between the primary mass and the pendulum vibration absorber. It is shown experimentally that the IPVA system outperforms a linear benchmark in terms of vibration suppression due to the energy transfer phenomenon.

 

The inerter pendulum vibration absorber is connected with a power take-off mechanism (called IPVA-PTO) to study its wave energy conversion potential. The resulting IPVA-PTO system is integrated between a spar and a floater (torus) using a ballscrew mechanism. The hydrodynamic stiffness, added mass and radiation damping effects on the spar-floater system are characterized using boundary element method via Ansys Aqwa. It has been observed that a 1:2 internal resonance between the spar-floater system and the pendulum is responsible for nonlinear energy transfer between the two systems. This nonlinear energy transfer occurs when the primary harmonic solution of the system becomes unstable, and a secondary solution emerges in the system characterized by harmonics of frequency half the excitation frequency. As a result of this energy transfer, the vibration of the spar-floater system is suppressed, and the energy is transferred to the pendulum. The focus of this paper is to analyze this 1:2 internal resonance phenomenon near the resonant frequency of the spar. The IPVA-PTO system, when integrated with the spar-floater system, is compared to a linear coupling between the spar and the floater in terms of the response amplitude operator (RAO) of the spar and the energy conversion capability defined by the capture width of the energy converter.

 

A nonlinear inerter pendulum vibration absorber is integrated with an electromagnetic power take-off system (called IPVA-PTO) and is analyzed for its efficacy in ocean wave energy conversion of a spar platform. The IPVA-PTO system shows a nonlinear energy transfer phenomenon between the spar and the IPVA-PTO which can be used to convert the vibration energy of the spar into electricity while reducing the hydrodynamic response of the spar. The hydrodynamic coefficients of the spar are computed using a commercial boundary-element-method (BEM) code. It is shown that the energy transfer is associated with 1:2 internal resonance of the pendulum vibration absorber, which is induced by a period-doubling bifurcation. The period-doubling bifurcation is studied using the harmonic balance method. A modified alternating frequency/time (AFT) approach is developed to compute the Jacobian matrix involving nonlinear inertial effects of the IPVA-PTO system. It is shown that the period doubling bifurcation leads to 1:2 internal resonance and plays a major role in the energy transfer between the spar and the pendulum. The response amplitude operator (RAO) in heave and the capture width of the IPVA-PTO-integrated spar are compared with its linear counterpart and it is shown that the IPVA-PTO system outperforms the linear energy harvester as the former has a lower RAO and higher capture width. 

A nonlinear inerter pendulum vibration absorber is integrated with an electromagnetic power take-off system (called IPVA-PTO) and is analyzed for its efficacy in ocean wave energy conversion of a spar platform. The IPVA-PTO system shows a nonlinear energy transfer phenomenon between the spar and the IPVA-PTO which can be used to convert the vibration energy of the spar into electricity while reducing the hydrodynamic response of the spar. The hydrodynamic coefficients of the spar are computed using a commercial boundary-element-method (BEM) code. It is shown that the energy transfer is associated with 1:2 internal resonance of the pendulum vibration absorber, which is induced by a period-doubling bifurcation. The period-doubling bifurcation is studied using the harmonic balance method. A modified alternating frequency/time (AFT) approach is developed to compute the Jacobian matrix involving nonlinear inertial effects of the IPVA-PTO system. It is shown that the period-doubling bifurcation leads to 1:2 internal resonance and plays a major role in the energy transfer between the spar and the pendulum. The response amplitude operator (RAO) in heave and the capture width of the IPVA-PTO-integrated spar are compared with its linear counterpart and it is shown that the IPVA-PTO system outperforms the linear energy harvester as the former has a lower RAO and higher capture width.

 

Abstract The inerter has been integrated into various vibration mitigation devices, whose mass amplification effect could enhance the suppression capabilities of these devices. In the current study, the inerter is integrated with a pendulum vibration absorber, referred to as inerter pendulum vibration absorber (IPVA). To demonstrate its efficacy, the IPVA is integrated with a linear, harmonically forced oscillator seeking vibration mitigation. A theoretical investigation is conducted to understand the nonlinear response of the IPVA. It is shown that the IPVA operates based on a nonlinear energy transfer phenomenon wherein the energy of the linear oscillator transfers to the pendulum vibration absorber as a result of parametric resonance of the pendulum. The parametric instability is predicted by the harmonic balance method along with the Floquet theory. A perturbation analysis shows that a pitchfork bifurcation and period doubling bifurcation are necessary and sufficient conditions for the parametric resonance to occur. An arc-length continuation scheme is used to predict the boundary of parametric instability in the parameter space and verify the perturbation analysis. The effects of various system parameters on the parametric instability are examined. Finally, the IPVA is compared with a linear benchmark and an autoparametric vibration absorber and shows more efficacious vibration suppression.