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To address the alerting issue of energy demand, lithium-ion capacitors (LICs) have been widely studied as promising electrochemical energy storage devices, which can deliver higher energy density than supercapacitors (SCs), and have higher power density with longer cycling life than lithium-ion batteries (LIBs). In this work, the active material lithium nickel cobalt manganese oxide LiNi_0.5Co_0.2Mn_0.3O₂(NCM523) is grown on a cotton textile template and building a 3-dimensional (3D) integrity to improve capacitance and energy density of LICs by enhancing the interfacial ion-exchange process. With the 3D structure, the specific discharge capacitance is increased to 718.67 $F{g}^{-1}$at 0.1 $A{g}^{-1}$from that of non-textile NCM523 (265.97 $F{g}^{-1}$), and remains a high capacitance of 254.48 $F{g}^{-1}$at 10 $A{g}^{-1}$in the half-cell capacitors. In addition, the energy density can achieve up to 36.17 $Whk{g}^{-1}$at the power density of 1,200 $Wk{g}^{-1}$in the full-cell capacitor. The textile NCM can maintain an energy density of 28.26 $Whk{g}^{-1}$at the current density of 10 $A{g}^{-1}$and power density of 6,000 $Wk{g}^{-1}$. Our results present promising applications of electrodes with the 3D porous structure for high energy density LICs. 

A scanning electrochemical microscope (SECM) can directly monitor electrochemical processes at interfaces of electrodes and electrolytes and has been used as an analytical tool for lithium-ion battery (LIB) studies. Through SECM, we can visualize the electrochemical reactivities of active species in LIBs in-situ during cycling. This review begins with introducing SECM-based LIB research and then summarizes the working mechanism and operating modes of the technique as well as combinations of SECM with other techniques for LIB studies. We review the results with a focus on the interfacial properties, surface reactions and electrochemical activity of different electrode materials for LIBs. The investigations of battery degradation, kinetic parameters and electrolyte swelling by SECM are also discussed. Finally, the current limitations and perspectives are also described regarding future developments. 

Abstract In this work, an organic‐inorganic hybrid crystal, violet‐crystal (VC), was used to etch the nickel foam (NF) to fabricate a self‐standing electrode for the water oxidation reaction. The efficacy of VC‐assisted etching manifests the promising electrochemical performance towards the oxygen evolution reaction (OER), requiring only ~356 and ~376 mV overpotentials to reach 50 and 100 mA cm⁻², respectively. The OER activity improvement is attributed to the collectively exhaustive effects arising from the incorporation of various elements in the NF, and the enhancement of active site density. Furthermore, the self‐standing electrode is robust, exhibiting a stable OER activity after 4,000 cyclic voltammetry cycles, and ~50 h. The anodic transfer coefficients (α_a) show that the first electron transfer step is the rate‐determining step on the surface of NF‐VCs‐1.0 (NF etched by 1 g of VCs) electrode, while the chemical step involving dissociation following the first electron transfer step is identified as the rate‐limiting step in other electrodes. The lowest Tafel slope value observed in the NF‐VCs‐1.0 electrode indicates the high surface coverage of oxygen intermediates and more favorable OER reaction kinetics, as confirmed by high interfacial chemical capacitance and low charge transport/interfacial resistance. This work demonstrates the importance of VCs‐assisted etching of NF to activate the OER, and the ability to predict reaction kinetics and rate‐limiting step based onα_avalues, which will open new avenues to identify advanced electrocatalysts for the water oxidation reaction. 

Millimeter-wave (mmWave) with large spectrum available is considered as the most promising frequency band for future wireless communications. The IEEE 802.11ad and IEEE 802.11ay operating on 60 GHz mmWave are the two most expected wireless local area network (WLAN) technologies for ultra-high-speed communications. For the IEEE 802.11ay standard still under development, there are plenty of proposals from companies and researchers who are involved with the IEEE 802.11ay task group. In this survey, we conduct a comprehensive review on the medium access control layer (MAC) related issues for the IEEE 802.11ay, some cross-layer between physical layer (PHY) and MAC technologies are also included. We start with MAC related technologies in the IEEE 802.11ad and discuss design challenges on mmWave communications, leading to some MAC related technologies for the IEEE 802.11ay. We then elaborate on important design issues for IEEE 802.11ay. Specifically, we review the channel bonding and aggregation for the IEEE 802.11ay, and point out the major differences between the two technologies. Then, we describe channel access and channel allocation in the IEEE 802.11ay, including spatial sharing and interference mitigation technologies. After that, we present an in-depth survey on beamforming training (BFT), beam tracking, single-user multiple-input-multiple-output (SU-MIMO) beamforming and multi-user multiple-input-multiple-output (MU-MIMO) beamforming. Finally, we discuss some open design issues and future research directions for mmWave WLANs. We hope that this paper provides a good introduction to this exciting research area for future wireless systems.