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Abstract The biogeochemistry of rapidly retreating Andean glaciers is poorly understood, and Ecuadorian glacier dissolved organic matter (DOM) composition is unknown. This study examined molecular composition and carbon isotopes of DOM from supraglacial and outflow streams (n = 5 and 14, respectively) across five ice capped volcanoes in Ecuador. Compositional metrics were paired with streamwater isotope analyses (δ¹⁸O) to assess if outflow DOM composition was associated with regional precipitation gradients and thus an atmospheric origin of glacier DOM. Ecuadorian glacier outflows exported ancient, biolabile dissolved organic carbon (DOC), and DOM contained a high relative abundance (RA) of aliphatic and peptide‐like compounds (≥27%RA). Outflows were consistently more depleted in Δ¹⁴C‐DOC (i.e., older) compared to supraglacial streams (mean −195.2 and −61.3‰ respectively), perhaps due to integration of spatially heterogenous and variably aged DOM pools across the supraglacial environment, or incorporation of aged subglacial OM as runoff was routed to the outflow. Across Ecuador, Δ¹⁴C‐DOC enrichment was associated with decreased aromaticity of DOM, due to increased contributions of organic matter (OM) from microbial processes or atmospheric deposition of recently fixed and subsequently degraded OM (e.g., biomass burning byproducts). There was a regional gradient between glacier outflow DOM composition and streamwater δ¹⁸O, suggesting covariation between regional precipitation gradients and the DOM exported from glacier outflows. Ultimately, this highlights that atmospheric deposition may exert a control on glacier outflow DOM composition, suggesting regional air circulation patterns and precipitation sources in part determine the origins and quality of OM exported from glacier environments. 

Abstract. We combine a glacier outburst flood model with a glacier flow model to investigate decadal to centennial variations in outburst floods originating from ice-dammed marginal basins. Marginal basins can form due to the retreat and detachment of tributary glaciers, a process that often results in remnant ice being left behind. The remnant ice, which can act like an ice shelf or break apart into a pack of icebergs, limits a basin's water storage capacity but also exerts pressure on the underlying water and promotes drainage. We find that during glacier retreat there is a strong, nearly linear relationship between flood water volume and peak discharge for individual basins, despite large changes in glacier and remnant ice volumes that are expected to impact flood hydrographs. Consequently, peak discharge increases over time as long as there is remnant ice remaining in a basin, and peak discharge begins to decrease once a basin becomes ice-free. Thus, similar size outburst floods can occur at very different stages of glacier retreat. We also find that the temporal variability in outburst flood magnitude depends on how the floods initiate. Basins that connect to the subglacial hydrological system only after reaching flotation depth yield greater long-term variability in outburst floods than basins that are continuously connected to the subglacial hydrological system (and therefore release floods that initiate before reaching flotation depth). Our results highlight the importance of improving our understanding of both changes in basin geometry and outburst flood initiation mechanisms in order to better assess outburst flood hazards and their impacts on landscape and ecosystem evolution. 

Abstract Biospheric particulate organic carbon (POC_bio) burial and rock petrogenic particulate organic carbon (POC_petro) oxidation are opposing long‐term controls on the global carbon cycle, sequestering and releasing carbon, respectively. Here, we examine how watershed glacierization impacts the POC source by assessing the concentration and isotopic composition (δ¹³C and Δ¹⁴C) of POC exported from four watersheds with 0%–49% glacier coverage across a melt season in Southeast Alaska. We used two mixing models (age‐weight percent and dual carbon isotope) to calculate concentrations of POC_bioand POC_petrowithin the bulk POC pool. The fraction POC_petrocontribution was highest in the heavily glacierized watershed (age‐weight percent: 0.39 ± 0.05; dual isotope: 0.42 (0.37–0.47)), demonstrating a glacial source of POC_petroto fjords. POC_petrowas mobilized via glacier melt and subglacial flow, while POC_biowas largely flushed from the non‐glacierized landscape by rain. Flow normalized POC_bioconcentrations exceeded POC_petroconcentrations for all streams, but surprisingly were highest in the heavily glacierized watershed (mean: 0.70 mgL⁻¹; range 0.16–1.41 mgL⁻¹), suggesting that glacier rivers can contribute substantial POC_bioto coastal waters. Further, the most heavily glacierized watershed had the highest sediment concentration (207 mgL⁻¹; 7–708 mgL⁻¹), and thus may facilitate long‐term POC_bioprotection via sediment burial in glacier‐dominated fjords. Our results suggest that continuing glacial retreat will decrease POC concentrations and increase POC_bio:POC_petroexported from currently glacierized watersheds. Glacier retreat may thus decrease carbon storage in marine sediments and provide a positive feedback mechanism to climate change that is sensitive to future changes in POC_petrooxidation. 

Abstract Glacier retreat poses risks and benefits for species of cultural and economic importance. One example is Pacific salmon ( Oncorhynchus spp.), supporting subsistence harvests, and commercial and recreational fisheries worth billions of dollars annually. Although decreases in summer streamflow and warming freshwater is reducing salmon habitat quality in parts of their range, glacier retreat is creating new streams and lakes that salmon can colonize. However, potential gains in future salmon habitat associated with glacier loss have yet to be quantified across the range of Pacific salmon. Here we project future gains in Pacific salmon freshwater habitat by linking a model of glacier mass change for 315 glaciers, forced by five different Global Climate Models, with a simple model of salmon stream habitat potential throughout the Pacific Mountain ranges of western North America. We project that by the year 2100 glacier retreat will create 6,146 (±1,619) km of new streams accessible for colonization by Pacific salmon, of which 1,930 (±569) km have the potential to be used for spawning and juvenile rearing, representing 0 to 27% gains within the 18 sub-regions we studied. These findings can inform proactive management and conservation of Pacific salmon in this era of rapid climate change.