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Due to the incapability of one-dimensional (1D) and two-dimensional (2D) models in simulating the frontal polymerization (FP) process in laminated composites with multiple fiber angles (e.g., cross-ply, angle-ply), modeling a three-dimensional (3D) domain, which is more representative of practical applications, provides critical guidance in the control and optimization of the FP process. In this paper, subroutines are developed to achieve the 3D modeling of FP in unidirectional and cross-ply carbon fiber laminates with finite element analysis, which are validated against the experimental data. The 3D model is employed to study the effect of triggering direction in relevance to the fiber direction on the FP process, which cannot be studied using traditional 1D/2D models. Our findings suggest that triggering in the fiber direction leads to a higher front velocity, in comparison to cases where front was triggered in the direction perpendicular to the fiber. Moreover, the average front velocity in cross-ply laminates is on average 20~25% lower than that in unidirectional laminates. When triggered using two opposite fronts in the in-plane direction, the maximum temperature of the thermal spike in the cross-ply laminate, when two fronts merge, is about 100 °C lower than that in the unidirectional laminate. In cross-ply laminates, a sloped pattern forms across the thickness direction as the front propagates in the in-plane direction, as opposed to the traditionally observed uniform propagation pattern in unidirectional cases. Furthermore, the effect of thermal conductivity is studied using two additional composite laminates with glass (1.14 W/m·K) and Kevlar fibers (0.04 W/m·K). It is shown that the frontal velocity, degree of cure, and the thermal spike temperature decrease as the thermal conductivity reduces. 

for thermoset-based fiber-reinforced polymer composites (FRP) in comparison with the traditional autoclave/oven-curing method, due to its rapid curing process, low energy consumption, and low cost. Optimizing the weight contents of initiators relative to the resin’s mass is needed to adjust the mechanical properties of FRPs in industrial applications. This study investigates the effect of varying the photoinitiator (PI) weight content on tensile properties and the frontal polymerization characteristics, including the front velocity, front temperature, and degree of cure, in the FP process of the epoxy resin. Specifically, a dual-initiator system, including PI and thermal-initiator (TI), is used to initiate the polymerization process by ultraviolent (UV) light. The weight content of the TI is fixed at 1 w%, and the relative PI concentration is varied from 0.2 w% to 0.5 wt%. Results show that increasing the PI amount from 0.2 wt% to 0.3 wt% significantly improves the front velocity and the degree of cure by about two times. Increasing the PI content from 0.3 wt% to 0.4 wt% results in 15% and 26% higher degree of cure and front velocity, respectively. Moreover, due to the different front velocity in the top and bottom regions of the specimen, the specimens with 0.4 wt% PI exhibited a curved shape. The specimen with 0.5 wt% PI is thermally degraded and foamed. By comparing tensile properties, it is found that increasing the PI concentration from 0.2 wt% to 0.3 wt% improves the tensile strength and Young’s modulus by 3.91% and 7%, respectively, while the tensile strength and the Young’s modulus of frontal polymerized specimens are on average 8% and 14% higher than traditionally ovencured ones, respectively. 

Deriving battery grade materials from natural sources is a key element to establishing sustainable energy storage technologies. In this work, we present the use of avocado peels as a sustainable source for conversion into hard carbon-based anodes for sodium ion batteries. The avocado peels are simply washed and dried then proceeded to a high temperature conversion step. Materials characterization reveals conversion of the avocado peels in high purity, highly porous hard carbon powders. When prepared as anode materials they show to the capability to reversibly store and release sodium ions. The hard carbon-based electrodes exhibit excellent cycling performance, namely, a reversible capacity of 352.55 mAh g⁻¹at 0.05 A g⁻¹, rate capability up to 86 mAh g⁻¹at 3500 mA g⁻¹, capacity retention of >90%, and 99.9% coulombic efficiencies after 500 cycles. Cyclic voltammetry studies indicated that the storage process was diffusion-limited, with diffusion coefficient of 8.62 × 10⁻⁸cm²s⁻¹. This study demonstrates avocado derived hard carbon as a sustainable source that can provide excellent electrochemical and battery performance as anodes in sodium ion batteries. 

Microfiber optic array structures are fabricated and employed as an optical structure overlaying a front-contact silicon solar cell. The arrays are synthesized through light-induced self-writing in a photo-crosslinking acrylate resin, which produces periodically spaced, high-aspect-ratio, and vertically aligned tapered microfibers deposited on a transparent substrate. The structure is then positioned over and sealed onto the solar cell surface. Their fiber optic properties enable collection of non-normal incident light, allowing the structure to mitigate shading loss through the redirection of incident light away from contacts and toward the solar cell. Angle-averaged external quantum efficiency increases nominally by 1.61%, resulting in increases in short-circuit current density up to 1.13 mA/cm2. This work demonstrates a new approach to enhance light collection and conversion using a scalable, straightforward, light-based additive manufacturing process. 

We report observations of photopolymerization driven phase-separation in a mixture of a photo-reactive monomer and inorganic nanoparticles. The mixture is irradiated with visible light possessing a periodic intensity profile that elicits photopolymerization along the depth of the mixture, establishing a competition between photo-crosslinking and thermodynamically favorable phase-separating behavior inherent to the system. In situ Raman spectroscopy was used to monitor the polymerization reaction and morphology evolution, and reveals a key correlation between irradiation intensity and composite morphology extending the entire depth of the mixture, i.e. unhindered phase-separation at low irradiation intensity and arrested phase-separation at high irradiation intensity. 3D Raman volume mapping and energy dispersive X-ray mapping confirm that the intensity-dependent irradiation process dictates the extent of phase separation, enabling single-parameter control over phase evolution and subsequent composite morphology. These observations can potentially enable a single-step route to develop polymer–inorganic composite materials with tunable morphologies.