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Abstract: This dataset includes field and laboratory analyses of water samples collected from lakes, ponds, rivers, and streams in northwest Alaska within Cape Krusenstern National Monument, Noatak National Preserve, Kobuk Valley National Park, Gates of the Arctic National Park and Preserve, and Bering Land Bridge National Preserve. At sites across the five national park units, in situ water quality measurements were made and water samples were collected from lakes, ponds, rivers, and streams. Pore waters were collected from below the sediment-water interface from lakes and ponds. Field measurements included pH, temperature, dissolved oxygen concentration and percent saturation, specific conductance, oxidation-reduction potential, and turbidity. Water samples were processed (details provided in the metadata file) and analyzed for water isotopes, dissolved inorganic carbon concentration and isotopic composition, alkalinity, total organic carbon, nutrients (nitrate, nitrite, phosphate, total dissolved nitrogen and total dissolved phosphorus), inorganic anions, major cations, iron oxidation state, dissolved organic carbon concentration, isotopic composition, and optical properties (UV-vis absorption and fluorescence spectroscopy), inorganic sulfide, dissolved methane, total mercury and methylmercury, and filter-passing and total recoverable elements (silicon (as silicon dioxide), aluminum, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, arsenic, selenium, yttrium, silver, cadmium, barium, lanthanum, cerium, praseodymium, neodymium, dysprosium, thallium, uranium, lead). 

Abstract Permafrost thaw alters groundwater flow, river hydrology, stream‐catchment interactions, and the availability of carbon and nutrients in headwater streams. The impact of permafrost on watershed hydrology and biogeochemistry of headwater streams has been demonstrated, but there is little understanding of how permafrost influences fish in these ecosystems. We examined relations among permafrost characteristics, the resulting changes in water temperature, stream hydrology (e.g., discharge flashiness), and macroinvertebrates, with the abundance, biomass, and energy density of juvenile Dolly Varden (Salvelinus malma) and Arctic Grayling (Thymallus arcticus) across 10 headwater streams in northwestern Alaska. Macroinvertebrate density was driven by concentrations of dissolved carbon and nutrients supporting stream food webs. Dolly Varden abundance was primarily related to water temperature with fewer fish in warmer streams, whereas Dolly Varden energy density decreased with the flashiness of the headwater streams. Dolly Varden biomass was related to both temperature and bottom‐up food web effects. The energy density of Arctic Grayling decreased with warmer temperatures and discharge flashiness. These relations demonstrate the importance of terrestrial–aquatic connections in permafrost landscapes and indicate the complexity of landscape effects on fish. Because permafrost thaw is one of the most impactful changes occurring as the Arctic warms, an improved understanding of how stream temperature, hydrology, and bottom‐up food web processes influence fish populations can aid forecasting of future conditions across the Arctic. 

Abstract Arctic streams and rivers are increasingly vulnerable to degradation from permafrost thaw that releases toxic elements via natural acid rock drainage. However, the spatial and temporal evolution of acid rock drainage on river chemistry across diverse mineral settings remain poorly constrained. Here, water chemistry in six watersheds across Alaska's Brooks Range (2022–2024) quantified the effects of acid rock drainage on river chemistry. Point‐source acid rock drainage inputs (seeps and impaired tributaries) exhibited lower pH (median; pH: 3.2 and 6.9, respectively), higher sulfate (SO₄²⁻: 3,025 and 390 mg L⁻¹, respectively), and elevated major and trace element concentrations (sum of 23 metals: 451 and 9.2 mg L⁻¹, respectively), compared to upstream unimpaired mainstem rivers (pH = 8.3, SO₄²⁻ = 68 mg L⁻¹; metals = 0.1 mg L⁻¹). Across watersheds, these inputs increased mainstem concentrations of major and trace elements (e.g., Fe, Al, Mn, Zn, Ni, Cd, and rare earth elements) and SO₄²⁻; however, mainstem river pH remained stable due to sufficient buffering. Within the Salmon River, concentrations of filter‐passing and particulate fractions of constituents (SO₄²⁻, Fe, Zn, Ni, and Cd) were elevated ≤70‐fold at >100 km downstream of acidic inputs, documenting long‐range transport. Temporal analyses of SO₄²⁻and Zn concentration (2015–2024) revealed abrupt increases (≤263%) in two watersheds between 2019 and 2020, aligning with antecedent record warm and snowy winter conditions. Collectively, our results document the abrupt onset of acid rock drainage across Arctic rivers with potential for long‐range downstream transport and implications for biogeochemical cycles and ecological and human health. 

Permafrost holds more than twice the amount of carbon currently in the atmosphere, but this large carbon reservoir is vulnerable to thaw and erosion under a rapidly changing Arctic climate. Convective storms are becoming increasingly common during Arctic summers and can amplify runoff and erosion. These extreme events, in concert with active layer deepening, may accelerate carbon loss from the Arctic landscape. However, we lack measurements of carbon fluxes during these events. Rivers are sensitive to physical, chemical, and hydrological perturbations, and thus are excellent systems for studying landscape responses to thunderstorms. We present observations from the Canning River, Alaska, which drains the northern Brooks Range and flows across a continuous permafrost landscape to the Beaufort Sea. During summer 2022 and 2023 field campaigns, we opportunistically monitored river discharge, sediment, and organic carbon fluxes during several thunderstorms. During one notable storm, river discharge nearly doubled from ~130 m3/s to ~240 m3/s, suspended sediment flux increased 70-fold, and the particulate organic carbon (POC) flux increased 90-fold relative to non-storm conditions. Taken together, the river exported ~16 metric tons of POC over one hour of this sustained event, not including the additional flux of woody debris. Furthermore, the dissolved organic carbon (DOC) flux nearly doubled. Although these thunderstorm-driven fluxes are short-lived (hours to days), they play an outsized role in exporting organic carbon from Arctic rivers. Understanding how these extreme events impact river water, sediment, and carbon dynamics will help predict how Arctic climate change will modify the global carbon cycle. 

Abstract Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska. 

This data release includes continuous measurements of stream temperature and specific conductance from 24 sites on the Yukon River and other arctic rivers in Alaska. Measurements were collected at selected U.S. Geological Survey stream gages and in communities along major rivers. 

Water quality and freshwater ecosystems are affected by river discharge and temperature. Models are frequently used to estimate river temperature on large spatial and temporal scales due to limited observations of discharge and temperature. In this study, we use physically based river routing and temperature models to simulate daily discharge and river temperature for rivers in 138 basins in Alaska, including the entire Yukon River basin, from 1990–2021. The river temperature model was optimized for ice free months using a surrogate‐based model optimization method, improving model performance at uncalibrated river gages. A common statistical model relating local air and water temperature was used as a benchmark. The physically based river temperature model exhibited superior performance compared to the benchmark statistical model after optimization, suggesting river temperature model optimization could become more routine. The river temperature model demonstrated high sensitivity to air temperature and model parameterization, and lower sensitivity to discharge. Validation of the models showed a Kling‐Gupta Efficiency of 0.46 for daily river discharge and a root mean square error of 2.04°C for daily river temperature, improving on the non‐optimized physical model and the benchmark statistical model, which had root mean square errors of 3.24 and 2.97°C, respectively. The simulation shows that rivers in northern Alaska have higher maximum summer temperatures and more variability than rivers in the Central and Southern regions. Furthermore, this framework can be readily adapted for use across models and regions. 

Abstract Bank erosion in Arctic rivers helps shape channel geometry, mobilizes carbon from permafrost and influences sediment delivery to the Arctic Ocean. On Alaska's Arctic coastal plain, rivers begin flowing during snowmelt in late spring while extensive river ice persists in channels, such that hydraulics are altered and water is kept cool. The effects of river ice on permafrost bank erosion are poorly understood, primarily due to a dearth of field observations and a lack of river ice in existing models. To address this knowledge gap, we developed a numerical model to simulate the melt of substrate interstitial ice and bank collapse along individual permafrost river banks. We parameterize the model with field observations from riverbanks in three different channels on the Canning River delta, which are disparately impacted by river ice during snowmelt. We explore the bank erosion produced without river ice in the model and with modern river ice model scenarios that we drive with different stages and water temperature boundary conditions. We also compare predicted erosion rates to observations from satellite imagery to validate this approach. In the model, banks are idealized as vertical profiles that rise 1–2 m above the river bed and are comprised of silt‐ to sand‐sized sediment with dense roots in the active layer. Underneath, we generalize bank ice content underneath the active layer to represent ice‐rich permafrost on the river corridor boundaries. The model predicts that these ice‐rich river banks can erode by 2–6 m/yr. Scenarios without ice underpredict erosion in the distributary channels. Scenarios with varying river ice for different deltaic channels produce erosion rates similar to observations. Our results suggest that the prolonged melt of thick river ice in a delta nonlinearly impacts permafrost bank erosion by blocking river discharge to certain branches, heightening stage across the distributary network and locally limiting river water warming. Given expected changes in air temperature and hydrology, future estimates of Arctic river bank erosion could be improved by considering river ice. 

High spatial and temporal resolution models are essential for understanding future climate impacts and developing effective climate resilience plans. However, existing regional and global river models often lack the resolution needed to accurately capture local conditions. This study uses a series of high-resolution models, including the Regional Arctic System Model, mizuRoute, and the river basin model, to analyze Arctic and sub-Arctic Alaskan hydrology. We compare a historical baseline (1991–2020) with six midcentury (2035–64) futures: two pseudo–global warming scenarios based on historical meteorology and four direct dynamically downscaled global climate models. The six futures reveal significant uncertainty in future annual discharge and peak flows, although a widespread increase in discharge during April (+63%) and October (+31%) is consistently shown across models. Projected increases in rain and shifting weather patterns lead to a transition from snow to rain in spring and autumn, reducing the fraction of snowmelt contributing to river discharge. Rising evapotranspiration moderates discharge changes, particularly in autumn, by offsetting precipitation increases. Average summer river temperatures are projected to increase by approximately 1.5°C, doubling the number of river segments that experience 18°C days, a critical threshold for salmon survival, and intensifying the heat flux to the ocean adding an average of 3.3 × 10¹²MJ yr⁻¹. These changes in the hydrologic cycle could profoundly impact riverine and oceanic ecosystems, posing substantial challenges to communities reliant on these environments. Significance StatementThe purpose of this study is to enhance our understanding of the midcentury climate change impacts on the Alaskan hydrologic cycle. In all six of the potential future scenarios, river flows in spring and autumn are predicted to increase and river temperatures are projected to be warmer throughout the year. These changes are significant as higher river temperatures could jeopardize fish survival. Additionally, the combined effect of increased river water and higher temperatures during spring and autumn will contribute more heat to the ocean, possibly reducing nearshore sea ice. This is crucial because many communities depend on rivers and sea ice for transportation and subsistence activities. 

Abstract Arctic hydrology is experiencing rapid changes including earlier snow melt, permafrost degradation, increasing active layer depth, and reduced river ice, all of which are expected to lead to changes in stream flow regimes. Recently, long-term (>60 years) climate reanalysis and river discharge observation data have become available. We utilized these data to assess long-term changes in discharge and their hydroclimatic drivers. River discharge during the cold season (October–April) increased by 10% per decade. The most widespread discharge increase occurred in April (15% per decade), the month of ice break-up for the majority of basins. In October, when river ice formation generally begins, average monthly discharge increased by 7% per decade. Long-term air temperature increases in October and April increased the number of days above freezing (+1.1 d per decade) resulting in increased snow ablation (20% per decade) and decreased snow water equivalent (−12% per decade). Compared to the historical period (1960–1989), mean April and October air temperature in the recent period (1990–2019) have greater correlation with monthly discharge from 0.33 to 0.68 and 0.0–0.48, respectively. This indicates that the recent increases in air temperature are directly related to these discharge changes. Ubiquitous increases in cold and shoulder-season discharge demonstrate the scale at which hydrologic and biogeochemical fluxes are being altered in the Arctic.