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Abstract The jet composition of gamma-ray bursts (GRBs), as well as how efficiently the jet converts its energy to radiation, are long-standing problems in GRB physics. Here, we reported a comprehensive temporal and spectral analysis of the TeV-emitting bright GRB 190114C. Its high fluence (∼4.4 × 10⁻⁴erg cm⁻²) allows us to conduct the time-resolved spectral analysis in great detail and study their variations down to a very short timescale (∼0.1 s) while preserving a high significance. Its prompt emission consists of three well-separated pulses. The first two main pulses (P₁andP₂) exhibit independently strong thermal components, starting from the third pulse (P₃) and extending to the entire afterglow, the spectra are all nonthermal, and the synchrotron plus Compton upscattering model well interprets the observation. By combining the thermal (P₁andP₂) and the nonthermal (P₃) observations based on two different scenarios (global and pulse properties) and following the method described in Zhang et al., we measure the fireball parameters and GRB radiative efficiency with little uncertainties for this GRB. A relevantly high GRB radiative efficiency is obtained based on both the global and pulse properties, suggesting that if GRBs are powered by fireballs, the efficiency can sometimes be high. More interestingly, though the observed parameters are individually different (e.g., the amount of mass loadingM), the radiative efficiency obtained fromP₁(η_γ= 36.0% ± 6.5%) andP₂(η_γ= 41.1% ± 1.9%) is roughly the same, which implies that the central engine of the same GRB has some common properties. 

Abstract Metal-metal contacts, though not yet widely realized, may provide exciting opportunities to serve as tunable and functional interfaces in single-molecule devices. One of the simplest components which might facilitate such binding interactions is the ferrocene group. Notably, direct bonds between the ferrocene iron center and metals such as Pd or Co have been demonstrated in molecular complexes comprising coordinating ligands attached to the cyclopentadienyl rings. Here, we demonstrate that ferrocene-based single-molecule devices with Fe-Au interfacial contact geometries form at room temperature in the absence of supporting coordinating ligands. Applying a photoredox reaction, we propose that ferrocene only functions effectively as a contact group when oxidized, binding to gold through a formal Fe³⁺center. This observation is further supported by a series of control measurements and density functional theory calculations. Our findings extend the scope of junction contact chemistries beyond those involving main group elements, lay the foundation for light switchable ferrocene-based single-molecule devices, and highlight new potential mechanistic function(s) of unsubstituted ferrocenium groups in synthetic processes. 

The development of efficient quantum communication technologies depends on the innovation in multiple layers of its implementation, a challenge we address from the fundamental properties of the physical system at the nano-scale to the instrumentation level at the macro-scale. We select a promising near infrared quantum emitter, the nitrogen-vacancy (NV) center in 4H-SiC, and integrate it, at an ensemble level, with nanopillar structures that enhance photon collection efficiency into an objective lens. Moreover, changes in collection efficiency in pillars compared to bulk can serve as indicators of color center orientation in the lattice. To characterize NV center properties at the unprecedented sub-2 Kelvin temperatures, we incorporate compatible superconducting nanowire single photon detectors inside the chamber of an optical cryostat and create the ICECAP, the Integrated Cryogenic system for Emission, Collection And Photon-detection. ICECAP measurements show no significant linewidth broadening of NV ensemble emission and up to 14-fold enhancement in collected emission. With additional filtering, we measure emitter lifetimes of NV centers in a basal (hk) and an axial (kk) orientation unveiling their cryogenic values of 2.2 ns and 2.8 ns. 

Gold-dithiol molecular junctions have been studied both experimentally and theoretically. However, the nature of the gold-thiolate bond as it relates to the solvent has been seldom investigated. It is known that solvents can impact the electronic structure of single molecule junctions, but the correlation between the solvent and dithiol-linked single-molecule junction conductance is not well understood. We study molecular junctions formed with thiol terminated phenylenes from both 1-chloronaphthalene and 1-bromonaphthalene solutions. We find that the most probable conductance and the distribution of conductances are both affected by the solvent. First-principles calculations show that junction conductance depends on the binding configurations (adatom, atop, bridge) of the thiolate on the Au surface as has been shown previously. More importantly, we find that brominated solvents can restrict the binding of thiols to specific Au sites. This mechanism offers new insight into the effects of the solvent environment on covalent bonding in molecular junctions. 

Abstract Gamma-ray bursts (GRBs) exhibit a diversity of spectra. Several spectral models (e.g., Band, cutoff power law (CPL), and blackbody) and their hybrid versions (e.g., Band+blackbody) have been widely used to fit the observed GRB spectra. Here, we attempt to collect all the bursts detected by Fermi/GBM with known redshifts from 2008 July to 2022 May, having been motivated to (i) provide a parameter catalog independent of the official Fermi/GBM team and (ii) achieve a “clean” model-based GRB spectral energy correlation analysis. A nearly complete GRB sample is created, containing 153 such bursts (136 long GRBs and 17 short GRBs). Using the sample and by performing detailed spectral analysis and model comparisons, we investigate two GRB spectral energy correlations: the correlation of the cosmological rest-frame peak energy ( E p, z ) of the ν F ν prompt emission spectrum with (i) the isotropic-bolometric-equivalent emission energy E γ ,iso (the Amati relation) and (ii) the isotropic-bolometric-equivalent peak luminosity L p,iso (the Yonetoku relation). From a linear regression analysis, a tight correlation between E p, z and E γ ,iso (and L γ ,iso ) is found for both Band-like and CPL-like bursts (except for CPL-like long burst E p, z – E γ ,iso correlation). More interestingly, CPL-like bursts do not fall on the Band-like burst Amati and Yonetoku correlations, suggesting distinct radiation processes, and pointing to the fact that these spectral energy correlations are tightly reliant on the model-wise properties.