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Precise and accurate mass and radius measurements of evolved stars are crucial to calibrating stellar models. Stars in detached eclipsing binaries (EBs) are excellent potential calibrators because their stellar parameters can be measured with fractional uncertainties of a few percent, independent of stellar models. The All-Sky Automated Survey for Supernovae (ASAS-SN) has identified tens of thousands of EBs, >35,000 of which were included in the ASAS-SN eclipsing binaries catalog. Here, we select eight EBs from this sample that contain giants based on their Gaia colors and absolute magnitudes. We use LBT/PEPSI, APF, and CHIRON to obtain multi-epoch spectra of these binaries and measure their radial velocities using two-dimensional cross-correlation methods. We simultaneously fit the ASAS-SN light curves and the radial velocities with PHOEBE to derive accurate and precise masses and radii with fractional uncertainties of $\lesssim 3\%$. For four systems, we also include Transiting Exoplanet Survey Satellite (TESS) light curves in our PHOEBE models, which significantly improves the radius determinations. In seven of our systems, both components have evolved off of the main sequence, and one system has a giant star component with a main sequence, Sun-like companion. Finally, we compare our mass and radius measurements to single-star evolutionary tracks and distinguish between systems that are first ascent red giant branch stars and those that are likely core helium-burning stars. 

ABSTRACT The identification and characterization of massive (≳ 0.8 M⊙) white dwarfs is challenging in part due to their low luminosity. Here, we present two candidate single-lined spectroscopic binaries, Gaia DR3 4014708864481651840 and 5811237403155163520, with K-dwarf primaries and optically dark companions. Both have orbital periods of P ∼ 0.45 d and show rotational variability, ellipsoidal modulations, and high-amplitude radial velocity variations. Using light curves from the Transiting Exoplanet Survey Satellite (TESS), radial velocities from ground-based spectrographs, and spectral energy distributions, we characterize these binaries to describe the nature of the unseen companion. We find that both systems are consistent with a massive white dwarf companion. Unlike simple ellipsoidal variables, star-spots cause the light-curve morphology to change between TESS sectors. We attempt to constrain the orbital inclination using phoebe binary light-curve models, but degeneracies in the light curves of spotted stars prevent a precise determination. Finally, we search for similar objects using Gaia DR3 and TESS, and comment on these systems in the context of recently claimed compact object binaries. 

Binder Jetting (BJ) has increased in popularity and capability since its development at MIT as it offers advantages such as fast build rates, integrated overhang support, low-power requirements, and versatility in materials. However, defects arise during layer spreading and printing that are difficult to remove during post-processing. Many of these defects are caused by particle rearrangement/ejection during binder deposition. This study explores methods of reducing particle rearrangement and ejection by applying small amounts of moisture to increase the cohesive forces between powder particles. A moisture application system was built using a piezo-electric disk to atomize water to apply a desired liquid to the BJ powder bed without disruption. The moisture is applied after spreading a new layer. Lines of binder were printed using varying droplet spacings and moisture levels. Results show that the moisture delivery system applied moisture levels across the entire application area with a standard deviation under 23%. The moisture levels delivered also had a single position test-to-test uniformity standard deviation under 21%. All tested levels of moisture addition showed mitigation of the balling defects observed in lines printed using dry powder under the same parameters. Moisture addition decreased effective saturation and increased line dimensions (height and width), but lines printed using the smallest amount of moisture tested, showed similar saturation levels and line widths to lines printed in dry powder while still partially mitigating balling. 

Abstract We present the discovery of 118 new ultracool dwarf candidates, discovered using a new machine-learning tool, namedSMDET, applied to time-series images from the Wide-field Infrared Survey Explorer. We gathered photometric and astrometric data to estimate each candidate’s spectral type, distance, and tangential velocity. This sample has a photometrically estimated spectral class distribution of 28 M dwarfs, 64 L dwarfs, and 18 T dwarfs. We also identify a T-subdwarf candidate, two extreme T-subdwarf candidates, and two candidate young ultracool dwarfs. Five objects did not have enough photometric data for any estimations to be made. To validate our estimated spectral types, spectra were collected for two objects, yielding confirmed spectral types of T5 (estimated T5) and T3 (estimated T4). Demonstrating the effectiveness of machine-learning tools as a new large-scale discovery technique. 

An air-stable (amino)(amido)radical was synthesized by reacting a cyclic (alkyl)(amino)carbene with carbazoyl chloride, followed by one-electron reduction. We show that an adjacent radical center weakens the amide bond. It enables the amino group to act as a strong acceptor under steric contraint, thus enhancing the stabilizing capto-dative effect. 

We have used Liquid-Phase Transmission Electron Microscopy (LPTEM) to directly image the fundamental processes occurring at the electrode-solution interface during electrochemical deposition of poly(3,4-ethylenedioxythiophene) (PEDOT) from an isotropic 3,4-ethylenedioxythiophene (EDOT) monomer solution. We clearly observed the various stages of the electrodeposition process including the initial nucleation of liquid-like EDOT oligomer droplets onto the glassy carbon working electrode and then the merging, coalesce and growth in size and thickness of these droplets into solid, stable, and dark PEDOT conjugated polymer films. We also used correlative transmitted light optical microscopy to study this process, revealing the change in color of the translucent clusters to the dark polymer film caused by the increase in conjugation length. From our studies we have been able to correlate specific observations of local structure and dynamics to the liquid-like (EDOT oligomer) droplets and solid-like (PEDOT polymer) films including their mobility, mass thickness, edge roughness, size, circularity, and optical absorption. 

Abstract We report the identification of 89 new systems containing ultracool dwarf companions to main-sequence stars and white dwarfs, using the citizen science project Backyard Worlds: Planet 9 and cross-reference between Gaia and CatWISE2020. 32 of these companions and 33 host stars were followed up with spectroscopic observations, with companion spectral types ranging from M7–T9 and host spectral types ranging from G2–M9. These systems exhibit diverse characteristics, from young to old ages, blue to very red spectral morphologies, potential membership to known young moving groups, and evidence of spectral binarity in nine companions. 20 of the host stars in our sample show evidence for higher-order multiplicity, with an additional 11 host stars being resolved binaries themselves. We compare this sample’s characteristics with those of the known stellar binary and exoplanet populations, and find our sample begins to fill in the gap between directly imaged exoplanets and stellar binaries on mass ratio–binding energy plots. With this study, we increase the population of ultracool dwarf companions to FGK stars by ∼42%, and more than triple the known population of ultracool dwarf companions with separations larger than 1000 au, providing excellent targets for future atmospheric retrievals. 

The commercially available polyelectrolyte complex poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is ubiquitous in organic and hybrid electronics. As such, it has often been used as a benchmark material for fundamental studies and the development of new electronic devices. Yet, most studies on PEDOT:PSS have focused on its electronic conductivity in dry environments, with less consideration given to its ion transport, coupled ionic-electronic transport, and charge storage properties in aqueous environments. These properties are essential for applications in bioelectronics (sensors, actuators), charge storage devices, and electrochromic displays. Importantly, past studies on mixed ionic-electronic transport in PEDOT:PSS neglected to consider how the molecular structure of PSS affects mixed ionic-electronic transport. Herein, we therefore investigated the effect of the molecular weight and size distribution of PSS on the electronic properties and morphology of PEDOT:PSS both in dry and aqueous environments, and overall performance in organic electrochemical transistors (OECTs). Using reversible addition–fragmentation chain transfer (RAFT) polymerization with two different chain transfer agents, six PSS samples with monomodal, narrow ( Đ = 1.1) and broad ( Đ = 1.7) size distributions and varying molecular weights were synthesized and used as matrices for PEDOT. We found that using higher molecular weight of PSS ( M n = 145 kg mol −1 ) and broad dispersity led to OECTs with the highest transconductance (up to 16 mS) and [ μC *] values (∼140 F cm −1 V −1 s −1 ) in PEDOT:PSS, despite having a lower volumetric capacitance ( C * = 35 ± 4 F cm −3 ). The differences were best explained by studying the microstructure of the films by atomic force microscopy (AFM). We found that heterogeneities in the PEDOT:PSS films (interconnected and large PEDOT- and PSS-rich domains) obtained from high molecular weight and high dispersity PSS led to higher charge mobility ( μ OECT ∼ 4 cm 2 V −1 s −1 ) and hence transconductance. These studies highlight the importance of considering molecular weight and size distribution in organic mixed ionic-electronic conductor, and could pave the way to designing high performance organic electronics for biological interfaces.