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ABSTRACT The initial mass and metallicity of stars both have a strong impact on their fate. Stellar axial rotation also has a strong impact on the structure and evolution of massive stars. In this study, we exploit the large grid of GENEC models, covering initial masses from 9 to 500 $${\rm M}_{\odot }$$ and metallicities ranging from $$Z=10^{-5}$$ (nearly zero) to 0.02 (supersolar), to determine the impact of rotation on their fate across cosmic times. Using the carbon–oxygen core mass and envelope composition as indicators of their fate, we predict stellar remnants, supernova engines, and spectroscopic supernova types for both rotating and non-rotating stars. We derive rates of the different supernova and remnant types considering two initial mass functions to help solve puzzles such as the absence of observed pair-instability supernovae. We find that rotation significantly alters the remnant type and supernova engine, with rotating stars favouring black hole formation at lower initial masses than their non-rotating counterparts. Additionally, we confirm the expected strong metallicity dependence of the fates with a maximum black hole mass predicted to be below 50 $${\rm M}_{\odot }$$ at SMC or higher metallicities. A pair-instability mass gap is predicted between about 90 and 150 $${\rm M}_{\odot }$$, with the most massive black holes below the gap found at the lowest metallicities. Considering the fate of massive single stars has far-reaching consequences across many different fields within astrophysics, and understanding the impact of rotation and metallicity will improve our understanding of how massive stars end their lives, and their impact on the Universe. 

β -Ga2O3 is actively touted as the next ultrawide bandgap material for power electronics. To fully utilize its high intrinsic critical electric field, development of high-quality robust large-barrier height junctions is essential. To this end, various high-work function metals, metal oxides, and hole-conducting oxides have been deposited on Ga2O3, primarily formed by sputter deposition. Unfortunately, reports to date indicate that measured barrier heights often deviate from the Schottky–Mott model as well as x-ray photoelectron spectroscopy (XPS) extractions of conduction band offsets, suggesting significant densities of electrically active defects at these junctions. We report Schottky diodes made from noble metal oxides, IrO2 and RuO2, deposited by ozone molecular beam epitaxy (ozone MBE) with barrier heights near 1.8 eV. These barriers show close agreement across extraction methods and robust to high surface electric fields upward of 6 MV/cm and 60 A/cm2 reverse current without degradation. 

All ten LIGO/Virgo binary black hole (BH-BH) coalescences reported following the O1/O2 runs have near-zero effective spins. There are only three potential explanations for this. If the BH spin magnitudes are large, then: (i) either both BH spin vectors must be nearly in the orbital plane or (ii) the spin angular momenta of the BHs must be oppositely directed and similar in magnitude. Then there is also the possibility that (iii) the BH spin magnitudes are small. We consider the third hypothesis within the framework of the classical isolated binary evolution scenario of the BH-BH merger formation. We test three models of angular momentum transport in massive stars: a mildly efficient transport by meridional currents (as employed in the Geneva code), an efficient transport by the Tayler-Spruit magnetic dynamo (as implemented in the MESA code), and a very-efficient transport (as proposed by Fuller et al.) to calculate natal BH spins. We allow for binary evolution to increase the BH spins through accretion and account for the potential spin-up of stars through tidal interactions. Additionally, we update the calculations of the stellar-origin BH masses, including revisions to the history of star formation and to the chemical evolution across cosmic time. We find that we can simultaneously match the observed BH-BH merger rate density and BH masses and BH-BH effective spins. Models with efficient angular momentum transport are favored. The updated stellar-mass weighted gas-phase metallicity evolution now used in our models appears to be key for obtaining an improved reproduction of the LIGO/Virgo merger rate estimate. Mass losses during the pair-instability pulsation supernova phase are likely to be overestimated if the merger GW170729 hosts a BH more massive than 50  M ⊙ . We also estimate rates of black hole-neutron star (BH-NS) mergers from recent LIGO/Virgo observations. If, in fact. angular momentum transport in massive stars is efficient, then any (electromagnetic or gravitational wave) observation of a rapidly spinning BH would indicate either a very effective tidal spin up of the progenitor star (homogeneous evolution, high-mass X-ray binary formation through case A mass transfer, or a spin- up of a Wolf-Rayet star in a close binary by a close companion), significant mass accretion by the hole, or a BH formation through the merger of two or more BHs (in a dense stellar cluster).