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Creators/Authors contains: "Pereyra, Rodolfo"

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  1. Abstract The electrical charge carried by raindrops provides significant information about thunderstorm electrification mechanisms, since the charge acquired by hydrometeors is closely related to the microphysical processes that they undergo within clouds. Investigation of charges on raindrops was conducted during the Remote sensing of Electrification, Lightning, And Meso‐scale/micro‐scale Processes with Adaptive Ground Observations field campaign. A newly designed instrument was used to determine simultaneously the fall velocity and charge for precipitating particles. Hydrometeor size and charge were measured in Córdoba city, Argentina, during electrified storms. Temporal series of size‐charge of single raindrops were recorded for two storms, which were also monitored with a Parsivel disdrometer and Lightning Mapping Array. The results show that the magnitude of the electric charges range between 1 and 50 pC and more than 90% of the charges are mainly carried by raindrops >1 mm, even though most of the raindrops are smaller than 1 mm. Furthermore, the measurement series show charged hydrometeors of both signs all the time. A correlation between the sizes and the charges carried by the raindrops was found in both storms. 
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  2. null (Ed.)
    Outstanding questions about the RNA world hypothesis for the emergence of life on Earth concern the stability and self-replication of prebiotic aqueous RNA. Recent experimental work has suggested that solid substrates and low temperatures could help resolve these issues. Herein, we use classical molecular dynamics simulations to explore the possibility that the substrate is ice itself. Simulations at −20 °C show that an eight-nucleotide single strand of RNA, initially situated in the quasiliquid layer at the air/ice interface, exhibits a robust propensity to reorient itself -- its bases turn toward the (hydrophobic) air/ice interface, while its anionic phosphodiester oxygens align with the underlying ice lattice. Kinetic analysis of hydrogen bonding indicates resistance to hydrolysis that is greater than that of an aqueous single-strand RNA at the same temperature. This enhanced resistance, in turn, could increase the opportunities for polymerization and self-copying. These findings thus offer the possibility of a role for an ancient RNA world on ice distinct from that considered in extant elaborations of the RNA world hypothesis. This work is, to the best of our knowledge, the first molecular dynamics study of RNA on ice. 
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  3. Abstract During November 2018–April 2019, an 11-station very high frequency (VHF) Lightning Mapping Array (LMA) was deployed to Córdoba Province, Argentina. The purpose of the LMA was validation of the Geostationary Lightning Mapper (GLM), but the deployment was coordinated with two field campaigns. The LMA observed 2.9 million flashes (≥ five sources) during 163 days, and level-1 (VHF locations), level-2 (flashes classified), and level-3 (gridded products) datasets have been made public. The network’s performance allows scientifically useful analysis within 100 km when at least seven stations were active. Careful analysis beyond 100 km is also possible. The LMA dataset includes many examples of intense storms with extremely high flash rates (>1 s−1), electrical discharges in overshooting tops (OTs), as well as anomalously charged thunderstorms with low-altitude lightning. The modal flash altitude was 10 km, but many flashes occurred at very high altitude (15–20 km). There were also anomalous and stratiform flashes near 5–7 km in altitude. Most flashes were small (<50 km2 area). Comparisons with GLM on 14 and 20 December 2018 indicated that GLM most successfully detected larger flashes (i.e., more than 100 VHF sources), with detection efficiency (DE) up to 90%. However, GLM DE was reduced for flashes that were smaller or that occurred lower in the cloud (e.g., near 6-km altitude). GLM DE also was reduced during a period of OT electrical discharges. Overall, GLM DE was a strong function of thunderstorm evolution and the dominant characteristics of the lightning it produced. 
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