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null (Ed.)Abstract Groundwater-derived solute fluxes to the ocean have long been assumed static and subordinate to riverine fluxes, if not neglected entirely, in marine isotope budgets. Here we present concentration and isotope data for Li, Mg, Ca, Sr, and Ba in coastal groundwaters to constrain the importance of groundwater discharge in mediating the magnitude and isotopic composition of terrestrially derived solute fluxes to the ocean. Data were extrapolated globally using three independent volumetric estimates of groundwater discharge to coastal waters, from which we estimate that groundwater-derived solute fluxes represent, at a minimum, 5% of riverine fluxes for Li, Mg, Ca, Sr, and Ba. The isotopic compositions of the groundwater-derived Mg, Ca, and Sr fluxes are distinct from global riverine averages, while Li and Ba fluxes are isotopically indistinguishable from rivers. These differences reflect a strong dependence on coastal lithology that should be considered a priority for parameterization in Earth-system models.more » « less
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Expansion (version 2.0) of the original Land2Sea database of exorheic rivers (Peucker-Ehrenbrink, 2009, doi:10.1029/2008GC002356) that contains information on 1519 rivers, with additional literature estimates of basin size, water discharge (runoff) under current conditions and prior to human intervention, suspended sediment discharge under current conditions and prior to human intervention, estimate of sediment bedload flux, dissolved strontium concentration and radiogenic isotope value as well as particulate (silt or clay) neodymium concentration, isotope composition and Nd model ages. A large addition to the original river database that contains a significant amount of data from the compilation of Meybeck and Ragu (1996) is from Milliman and Farnsworth (2011). The compilation is not yet geo-referenced. The 2156 rivers are sorted alphabetically within each large-scale drainage region (Graham et al., 1999, 2000). In addition, the compilation includes data on sizes of, and sediment discharge from 48 small islands in Oceania with very high sediment yields. Any errors in transcribing data or converting units from their primary sources into this compilation are entirely mine. Acknowledgements: BPE acknowledges financial support from NSR-EAR-0087697, -0125873, -1226818 and ICER-1639557, as well as from WHOI's Investment in Research and Development Fund.more » « less
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Terrestrial vegetation and soils hold three times more carbon than the atmosphere. Much debate concerns how anthropogenic activity will perturb these surface reservoirs, potentially exacerbating ongoing changes to the climate system. Uncertainties specifically persist in extrapolating point-source observations to ecosystem-scale budgets and fluxes, which require consideration of vertical and lateral processes on multiple temporal and spatial scales. To explore controls on organic carbon (OC) turnover at the river basin scale, we present radiocarbon ( 14 C) ages on two groups of molecular tracers of plant-derived carbon—leaf-wax lipids and lignin phenols—from a globally distributed suite of rivers. We find significant negative relationships between the 14 C age of these biomarkers and mean annual temperature and precipitation. Moreover, riverine biospheric-carbon ages scale proportionally with basin-wide soil carbon turnover times and soil 14 C ages, implicating OC cycling within soils as a primary control on exported biomarker ages and revealing a broad distribution of soil OC reactivities. The ubiquitous occurrence of a long-lived soil OC pool suggests soil OC is globally vulnerable to perturbations by future temperature and precipitation increase. Scaling of riverine biospheric-carbon ages with soil OC turnover shows the former can constrain the sensitivity of carbon dynamics to environmental controls on broad spatial scales. Extracting this information from fluvially dominated sedimentary sequences may inform past variations in soil OC turnover in response to anthropogenic and/or climate perturbations. In turn, monitoring riverine OC composition may help detect future climate-change–induced perturbations of soil OC turnover and stocks.more » « less
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Abstract EarthCube Data Discovery Studio (DDStudio) is a crossdomain geoscience data discovery and exploration portal. It indexes over 1.65 million metadata records harvested from 40+ sources and utilizes a configurable metadata augmentation pipeline to enhance metadata content, using text analytics and an integrated geoscience ontology. Metadata enhancers add keywords with identifiers that map resources to science domains, geospatial features, measured variables, and other characteristics. The pipeline extracts spatial location and temporal references from metadata to generate structured spatial and temporal extents, maintaining provenance of each metadata enhancement, and allowing user validation. The semantically enhanced metadata records are accessible as standard ISO 19115/19139 XML documents via standard search interfaces. A search interface supports spatial, temporal, and text‐based search, as well as functionality for users to contribute, standardize, and update resource descriptions, and to organize search results into shareable collections. DDStudio bridges resource discovery and exploration by letting users launch Jupyter notebooks residing on several platforms for any discovered datasets or dataset collection. DDStudio demonstrates how linking search results from the catalog directly to software tools and environments reduces time to science in a series of examples from several geoscience domains. URL: datadiscoverystudio.orgmore » « less