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A swimming microorganism stirs the surrounding fluid, creating a flow field that governs not only its locomotion and nutrient uptake, but also its interactions with other microorganisms and the environment. Despite its fundamental importance, capturing this flow field and unraveling its biological implications remains a challenge. Here, we report direct, time-resolved measurements of the three-dimensional (3D) flow field generated by a single, free-swimming microalga, , a model organism for microbial locomotion and flagellar dynamics. Supported by hydrodynamic modeling and simulations, our measurements resolve how established two-dimensional (2D) flow features such as in-plane vortices and the stagnation point emerge from and shape the full algal flow in 3D. Moreover, we reveal unexpected low-Reynolds-number flow phenomena including micron-sized vortex rings and periodically recurring translating vortices and uncover topological changes in the underlying flow structure associated with the puller-to-pusher transition of an alga. Biologically, access to the 3D flow field enables rigorous quantification of the alga’s energy expenditure, as well as its swimming and feeding efficiency, improving the precision of these physiological metrics. Taken together, our study demonstrates rich vortex dynamics in inertialess flows and shows their influence on microbial motility. The work also introduces an experimental method for mapping the fluid environment sculpted by beating flagella. 

Privacy policies are often complex. An exception is the two-page standardized notice that U.S. financial institutions must provide under the Gramm-Leach-Bliley Act (GLBA). However, banks now operate websites, mobile apps, and other services that involve complex data sharing practices that require additional privacy notices and do-not-sell opt-outs. We conducted a large-scale analysis of how U.S. banks implement privacy policies and controls in response to GLBA; other federal privacy policy requirements; and the California Consumer Privacy Act (CCPA), a key example for U.S. state privacy laws. We focused on the disclosure and control of a set of especially privacy-invasive practices: third-party data sharing for marketing-related purposes. We collected privacy policies for the 2,067 largest U.S. banks, 45.2% of which provided multiple policies. Across disclosures and controls for the same bank, we identified frequent, concerning inconsistencies---53.8% of banks with multiple privacy policies indicated in GLBA notices that they do not share with third parties but disclosed sharing in other policies. This multiplicity of policies, with the inconsistencies it causes, may create consumer confusion and undermine the transparency goals of the very laws that require them. Our findings call into question whether current policy requirements, such as the GLBA notice, are achieving their intended goals in today's online banking landscape. We discuss potential avenues for reforming and harmonizing privacy policies and control requirements across federal and state laws. 

Abstract Electron-deficient olefin (EDO) ligands are known to promote a variety of nickel-catalyzed cross-coupling reactions, presumably by accelerating the reductive elimination step and preventing undesired β-hydride elimination. While there is a growing body of experimental and computational evidence elucidating the beneficial effects of EDO ligands, significant gaps remain in our understanding of the underlying coordination chemistry of the Ni–EDO species involved. In particular, most procedures rely on in situ assembly of the active catalyst, and there is a paucity of preligated Ni–EDO precatalysts. Herein, we investigate the 16-electron, heteroleptic nickel complex, Ni(COD)(DMFU), and examine the performance of this complex as a precatalyst in 1,2-diarylation of alkenes.