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Free, publicly-accessible full text available July 8, 2025
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Free, publicly-accessible full text available July 15, 2025
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A Photothermal Solar Tunnel Radiator (PSTR) is designed and developed by employing multiple transparent photothermal glass panels (TPGP). The primary objective is to pioneer a transformative approach to achieve energy-neutral building heating utilities, exemplified by a lab-scale "Photothermal Solar Box" (PSB) exclusively heated with TPGP under natural sunlight. The PSTR presents a novel paradigm for sustainable energy, enabling direct solar energy capture through transparent glass substrates with photothermal coatings. The high transparency of Fe3O4@Cu2-xS coated glass substrates enhance efficient solar harvesting and photothermal energy generation within the Photothermal Solar Box. The system demonstrates an impressive thermal energy output, reaching up to 9.1x105 joules with 8 photothermal panels in parallel. Even under colder conditions (ambient temperature: -10 °C), with accelerated heat loss, the interior temperatures of the PSB with partial thermal insulation achieve a commendable 35 °C, showcasing effective photothermal heating in cold weather. These findings indicate the system's resilience and efficiency in harnessing solar energy under diverse conditions, including partial cloudy weather. The initiative contributes to broader sustainability goals by providing a scalable and practical alternative to traditional solar heating methods, aligning with the global mission for a cleaner, greener future.more » « less
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Among major energy conversion methods, photovoltaic (PV) solar cells have been the most popular and widely employed for a variety of applications. Although a PV solar panel has been shown as one of the most efficient green energy sources, its 2D surface solar light harvesting has reached great limitations as it requires large surface areas. There is, therefore, an increasing need to seek solar harvest in a three-dimensional fashion for enhanced energy density. In addition to a conventional 2D solar panel in the x-y area, we extend another dimension of solar harvesting in the z-axis through multiple CdTe solar panels arranged in parallel. The high transparency allows sunlight to partially penetrate multiple solar panels, resulting in significantly increased solar harvesting surface area in a 3D fashion. The advantages of the 3D multi-panel solar harvesting system include: i) enlarged solar light collecting surface area, therefore increased energy density, ii) the total output power from multiple panels can exceed that of the single panel, and iii) significantly reduced surface area needed for densely populated cities. With five CdTe solar panels of different transparencies in parallel, the multilayer system can produce collective output power 233% higher than that of the single solar panel under the same surface area when arranged in descending (i.e., PV panel with the highest transparency on top and lowest at bottom). The PCE of the multi-panel system has also increased 233% in descending order indicating the viability of 3D solar harvesting. The multi-panel system will dimensionally transform solar harvesting from 2D to 3D for more efficient energy generation.more » « less
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The efficiencies of photovoltaic (PV) and thermoelectric (TE) have been limited by the intrinsic properties to ~ 25 % and ~ 10 %, respectively. In current applications, photovoltaics utilizes the shorter wavelength end of the solar spectrum but suffer decreases in efficiency from heating caused by IR absorption. The novel tunable nanostructures of new hybrids eliminate this problem by directing thermal energy from longer wavelengths to the thermoelectric device. Solar light is harvested through transparent hybrid and segregated into different wavelengths: the IR is absorbed by the hybrid which is photothermally heated up to ~100 °C for the required thermoelectric temperature span; the UV/visible is directed to PV with reduced IR components, therefore significantly reducing heating. In this way, both PV and TE operate jointly by separately utilizing the full spectrum of solar light. The novel hybrid functions not only as a photothermal heater for TE but also a wavelength segregator enabling the PV and TE devices to synergistically produce electrical energy with much greater system efficiency. Also identified is the operating structural mechanism on spectral tunability and photothermal effect of the photonic hybrids.more » « less
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A Cold Atmospheric Plasma (CAP) apparatus was designed and developed for SARS-CoV-2 killing as evaluated by pseudotyped viral infectivity assays. The reactive species generated by the plasma system was fully characterized by using Optical Emission Spectroscopy (OES) measurement under given conditions such as plasma power, flow rate, and treatment time. A variety of reactive oxygen species (ROS) and reactive nitrogen species (RNS) were identified from plasma plume with energies of 15–72 eV in the frequency range between 500–1000 nm. Systematic virus killing experiments were carried out, and the efficacy of CAP treatment in reducing SARS-CoV-2 viral infectivity was significant following treatment for 8 s, with further enhancement of killing upon longer exposures of 15–120 s. We correlated killing efficacy with the reactive species in terms of type, intensity, energy, and frequency. These experimental results demonstrate effective cold plasma virus killing via ROS and RNS under ambient conditions.more » « less
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Molecular dynamics (MD) simulations are invoked to simulate the diffusion process and microstructural evolution at the solid–liquid, cast-rolled Al–Cu interfaces. K-Means clustering algorithm is used to identify the formation and composition of two types of nanostructural features in the Al-rich and Cu-rich regions of the interface (i.e., the intermetallic Al2Cu near the Al-rich interface and the intermetallic Al4Cu9 near the Cu-rich interface). MD simulations are also used to assess the effects of annealing temperature on the evolution of the compositionally graded microstructural features at the Al–Cu interfaces and to characterize the mechanical strength of the Al–Cu interfaces. It is found that the failure of the Al–Cu interface takes place at the Al-rich side of the interface (Al2Cu–Al) which is mechanically weaker than the Cu-rich side of the interface (Cu–Al4Cu9), which is also verified by the nanoindentation studies of the interfaces. Centrosymmetry parameter analyses and dislocation analyses are used to understand the microstructural features that influence deformation behavior leading to the failure of the Al–Cu interfaces. Increasing the annealing temperature reduces the stacking fault density at the Al–Cu interface, suppresses the generation of nanovoids which are precursors for the initiation of fracture at the Al-rich interface, and increases the strength of the interface.more » « less