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Abstract Mercury (Hg) is a global pollutant whose atmospheric deposition is a major input to the terrestrial and oceanic ecosystems. Gas‐particle partitioning (GPP) of gaseous oxidized mercury (GOM) redistributes speciated Hg between gas and particulate phase and can subsequently alter Hg deposition flux. Most 3‐dimensional chemical transport models either neglected the Hg GPP process or parameterized it with measurement data limited in time and space. In this study, CMAQ‐newHg‐Br (Ye et al., 2018,https://doi.org/10.1002/2017ms001161) was updated to CMAQ‐newHg‐Br v2 by implementing a new GPP scheme and the most up‐to‐date Hg redox chemistry and was run for the northeastern United States over January‐November 2010. CMAQ‐newHg‐Br v2 reproduced the measured spatiotemporal distributions of gaseous elemental mercury (GEM) and particulate bound mercury (PBM) concentrations and Hg wet deposition flux within reasonable ranges and simulated dry deposition flux in agreement with previous studies. The GPP scheme improved the simulation of PBM via increasing winter‐, spring‐ and fall‐time PBM concentrations by threefold. It also improved simulated Hg wet deposition flux with an increase of 2.1 ± 0.7 μgm²in the 11‐month accumulated amount, offsetting half of the decreasing effect of the updated chemistry (−4.2 ± 1.8 μgm²). Further, the GPP scheme captured the observedK_p‐T relationship as reported in previous studies without using measurement data and showed advantages at night and in rural/remote areas where existing empirical parameterizations failed. Our study demonstrated CMAQ‐newHg‐Br v2 a promising assessment tool to quantify impacts of climate change and emission reduction policy on Hg cycling. 

Abstract Mercury (Hg) is a global pollutant whose atmospheric deposition is a major input to the terrestrial and oceanic ecosystems. Gas‐particle partitioning (GPP) of gaseous oxidized mercury (GOM) redistributes speciated Hg between gas and particulate phase and can subsequently alter Hg deposition flux. Most 3‐dimensional chemical transport models either neglected the Hg GPP process or parameterized it with measurement data limited in time and space. In this study, CMAQ‐newHg‐Br (Ye et al., 2018,https://doi.org/10.1002/2017ms001161) was updated to CMAQ‐newHg‐Br v2 by implementing a new GPP scheme and the most up‐to‐date Hg redox chemistry and was run for the northeastern United States over January‐November 2010. CMAQ‐newHg‐Br v2 reproduced the measured spatiotemporal distributions of gaseous elemental mercury (GEM) and particulate bound mercury (PBM) concentrations and Hg wet deposition flux within reasonable ranges and simulated dry deposition flux in agreement with previous studies. The GPP scheme improved the simulation of PBM via increasing winter‐, spring‐ and fall‐time PBM concentrations by threefold. It also improved simulated Hg wet deposition flux with an increase of 2.1 ± 0.7 μgm²in the 11‐month accumulated amount, offsetting half of the decreasing effect of the updated chemistry (−4.2 ± 1.8 μgm²). Further, the GPP scheme captured the observedK_p‐T relationship as reported in previous studies without using measurement data and showed advantages at night and in rural/remote areas where existing empirical parameterizations failed. Our study demonstrated CMAQ‐newHg‐Br v2 a promising assessment tool to quantify impacts of climate change and emission reduction policy on Hg cycling. 

Measurements of semi-inclusive deep-inelastic scattering multiplicities for ${\pi }^{+}$and ${\pi }^{-}$from proton and deuteron targets are reported on a grid of hadron kinematic variables $z, P_T$, and ${\varphi }^{*}$for leptonic kinematic variables in the range $0.3<x<0.6$and $3<Q^2<5{\mathrm{GeV}}^2$. Data were acquired in 2018 and 2019 at Jefferson Lab Hall C with a 10.6 GeV electron beam impinging on 10-cm-long liquid hydrogen and deuterium targets. Scattered electrons and charged pions were detected in the High Momentum Spectrometer and Super High Momentum Spectrometer, respectively. The multiplicities were fitted for each bin in $(x,Q^2,z,P_t)$to extract the ${\varphi }^{*}$—independent $M_0$and the azimuthal modulations $\langle cos\left({\varphi }^{*}\right)\rangle$and $\langle cos\left(2{\varphi }^{*}\right)\rangle$. The $P_t$dependence of the $M_0$results was found to be remarkably consistent for the four cases studied: $ep\to e{\pi }^{+}X, ep\to e{\pi }^{-}X, ed\to e{\pi }^{+}X, ed\to e{\pi }^{-}X$over the range $0\text{GeV}<P_t<0.4\text{GeV}$, as were the multiplicities evaluated near ${\varphi }^{*}={180}^{\circ }$over the extended range $0\text{GeV}<P_t<0.7\text{GeV}$. The Gaussian widths of the $P_t$dependence exhibit a quadratic increase with $z$. The $cos\left({\varphi }^{*}\right)$modulations were found to be consistent with zero for ${\pi }^{+}$, in agreement with previous world data, while the ${\pi }^{-}$moments were, in many cases, significantly greater than zero. The $cos\left(2{\varphi }^{*}\right)$modulations were found to be consistent with zero. The higher statistical precision of this dataset of about 20 000 individual multiplicity values, compared with previously published data, should allow improved determinations of quark transverse momentum distributions and higher twist contributions.