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Abstract. Air trapped in polar ice provides unique records of the pastatmospheric composition ranging from key greenhouse gases such as methane(CH4) to short-lived trace gases like ethane (C2H6) andpropane (C3H8). Recently, the comparison of CH4 recordsobtained using different extraction methods revealed disagreements in theCH4 concentration for the last glacial in Greenland ice. Elevatedmethane levels were detected in dust-rich ice core sections measureddiscretely, pointing to a process sensitive to the melt extraction technique. To shed light on the underlying mechanism, we performed targeted experiments and analyzed samples for methane and the short-chain alkanes ethane and propane covering the time interval from 12 to 42 kyr. Here, we report our findings of these elevated alkane concentrations, which scale linearly with the amount of mineral dust within the ice samples. The alkane production happens during the melt extraction step of the classic wet-extraction technique and reaches 14 to 91 ppb of CH4 excess in dusty ice samples. We document for the first time a co-production of excess methane, ethane, and propane, with the observed concentrations for ethane and propane exceeding their past atmospheric background at least by a factor of 10. Independent of the produced amounts, excess alkanes were produced in a fixed molar ratio of approximately 14:2:1, indicating a shared origin. The measured carbon isotopic signature of excess methane is (-47.0±2.9) ‰ and its deuterium isotopic signature is (-326±57) ‰. With the co-production ratios of excess alkanesand the isotopic composition of excess methane we established a fingerprintthat allows us to constrain potential formation processes. This fingerprintis not in line with a microbial origin. Moreover, an adsorption–desorptionprocess of thermogenic gas on dust particles transported to Greenlanddoes not appear very likely. Instead, the alkane pattern appears to beindicative of abiotic decomposition of organic matter as found in soils andplant leaves. 

Here we use high-precision carbon isotope data (δ¹³C-CO₂) to show atmospheric CO₂during Marine Isotope Stage 4 (MIS 4, ~70.5-59 ka) was controlled by a succession of millennial-scale processes. Enriched δ¹³C-CO₂during peak glaciation suggests increased ocean carbon storage. Variations in δ¹³C-CO₂in early MIS 4 suggest multiple processes were active during CO₂drawdown, potentially including decreased land carbon and decreased Southern Ocean air-sea gas exchange superposed on increased ocean carbon storage. CO₂remained low during MIS 4 while δ¹³C-CO₂fluctuations suggest changes in Southern Ocean and North Atlantic air-sea gas exchange. A 7 ppm increase in CO₂at the onset of Dansgaard-Oeschger event 19 (72.1 ka) and 27 ppm increase in CO₂during late MIS 4 (Heinrich Stadial 6, ~63.5-60 ka) involved additions of isotopically light carbon to the atmosphere. The terrestrial biosphere and Southern Ocean air-sea gas exchange are possible sources, with the latter event also involving decreased ocean carbon storage.

 

Abstract. Here we present a newly developed ice core gas-phase proxy that directlysamples a component of the large-scale atmospheric circulation:synoptic-scale pressure variability. Surface pressure changes weakly disrupt gravitational isotopic settling in the firn layer, which is recorded in krypton-86 excess (86Krxs). The 86Krxs may therefore reflect the time-averaged synoptic pressure variability over several years (site “storminess”), but it likely cannot record individual synoptic events as ice core gas samples typically average over several years. We validate 86Krxs using late Holocene ice samples from 11 Antarctic ice cores and 1 Greenland ice core that collectively represent a wide range of surface pressure variability in the modern climate. We find a strong spatial correlation (r=-0.94, p<0.01) between site average 86Krxs and time-averaged synoptic variability from reanalysis data. The main uncertainties in the analysis are the corrections for gas loss and thermal fractionation and the relatively large scatter in the data. Limited scientific understanding of the firn physics and potential biases of 86Krxs require caution in interpreting this proxy at present. We show that Antarctic 86Krxs appears to be linked to the position of the Southern Hemisphere eddy-driven subpolar jet (SPJ), with a southern position enhancing pressure variability. We present a 86Krxs record covering the last 24 kyr from the West Antarctic Ice Sheet (WAIS) Divide ice core. Based on the empirical spatial correlation of synoptic activity and 86Krxs at various Antarctic sites, we interpret this record to show that West Antarctic synoptic activity is slightly below modern levels during the Last Glacial Maximum (LGM), increases during the Heinrich Stadial 1 and Younger Dryas North Atlantic cold periods, weakens abruptly at the Holocene onset, remains low during the early and mid-Holocene, and gradually increases to its modern value. The WAIS Divide 86Krxs record resembles records of monsoon intensity thought to reflect changes in the meridional position of the Intertropical Convergence Zone (ITCZ) on orbital and millennial timescales such that West Antarctic storminess is weaker when the ITCZ is displaced northward and stronger when it is displaced southward. We interpret variations in synoptic activity as reflecting movement of the South Pacific SPJ in parallel to the ITCZ migrations, which is the expected zonal mean response of the eddy-driven jet in models and proxy data. Past changes to Pacific climate and the El Niño–Southern Oscillation (ENSO) may amplify the signal of the SPJ migration. Our interpretation is broadly consistent with opal flux records from the Pacific Antarctic zone thought to reflect wind-driven upwelling. We emphasize that 86Krxs is a new proxy, and more work is called for to confirm, replicate, and better understand these results; until such time, our conclusions regarding past atmospheric dynamics remainspeculative. Current scientific understanding of firn air transport andtrapping is insufficient to explain all the observed variations in86Krxs. A list of suggested future studies is provided. 

The history of atmospheric oxygen ( P O 2 ) and the processes that act to regulate it remain enigmatic because of difficulties in quantitative reconstructions using indirect proxies. Here, we extend the ice-core record of P O 2 using 1.5-million-year-old (Ma) discontinuous ice samples drilled from Allan Hills Blue Ice Area, East Antarctica. No statistically significant difference exists in P O 2 between samples at 1.5 Ma and 810 thousand years (ka), suggesting that the Late-Pleistocene imbalance in O 2 sources and sinks began around the time of the transition from 40- to 100-ka glacial cycles in the Mid-Pleistocene between ~1.2 Ma and 700 ka. The absence of a coeval secular increase in atmospheric CO 2 over the past ~1 Ma requires negative feedback mechanisms such as P co 2 -dependent silicate weathering. Fast processes must also act to suppress the immediate P co 2 increase because of the imbalance in O 2 sinks over sources beginning in the Mid-Pleistocene. 

Abstract. The S27 ice core, drilled in the Allan Hills Blue IceArea of East Antarctica, is located in southern Victoria Land, ∼80 km away from the present-day northern edge of the RossIce Shelf. Here, we utilize the reconstructed accumulation rate of S27covering the Last Interglacial (LIG) period between 129 ka and 116 ka (where ka indicates thousands of years before present) to infer moisture transport into the region. Theaccumulation rate is based on the ice-age–gas-age differences calculatedfrom the ice chronology, which is constrained by the stable water isotopesof the ice, and an improved gas chronology based on measurements of oxygenisotopes of O2 in the trapped gases. The peak accumulation rate in S27occurred at 128.2 ka, near the peak LIG warming in Antarctica. Even the mostconservative estimate yields an order-of-magnitude increase in theaccumulation rate during the LIG maximum, whereas other Antarctic ice coresare typically characterized by a glacial–interglacial difference of a factorof 2 to 3. While part of the increase in S27 accumulation rates mustoriginate from changes in the large-scale atmospheric circulation,additional mechanisms are needed to explain the large changes. Wehypothesize that the exceptionally high snow accumulation recorded in S27reflects open-ocean conditions in the Ross Sea, created by reduced sea iceextent and increased polynya size and perhaps by a southward retreat of theRoss Ice Shelf relative to its present-day position near the onset of the LIG.The proposed ice shelf retreat would also be compatible with a sea-levelhigh stand around 129 ka significantly sourced from West Antarctica. Thepeak in S27 accumulation rates is transient, suggesting that if the Ross IceShelf had indeed retreated during the early LIG, it would have re-advancedby 125 ka. 

Abstract. The last deglaciation, which occurred from 18 000 to 11 000 years ago,is the most recent large natural climatic variation of global extent. Withaccurately dated paleoclimate records, we can investigate the timings ofrelated variables in the climate system during this major transition. Here,we use an accurate relative chronology to compare temperature proxy data andglobal atmospheric CO2 as recorded in Antarctic ice cores. In addition tofive regional records, we compare a δ18O stack, representingAntarctic climate variations with the high-resolution robustly dated WAISDivide CO2 record (West Antarctic Ice Sheet). We assess the CO2 and Antarctic temperature phaserelationship using a stochastic method to accurately identify the probabletimings of changes in their trends. Four coherent changes are identified forthe two series, and synchrony between CO2 and temperature is within the95 % uncertainty range for all of the changes except the end of glacial termination 1 (T1). During the onset of the last deglaciation at 18 ka and the deglaciationend at 11.5 ka, Antarctic temperature most likely led CO2 by several centuries (by 570 years, within a range of 127 to 751 years, 68 %probability, at the T1 onset; and by 532 years, within a range of 337 to 629years, 68 % probability, at the deglaciation end). At 14.4 ka, the onsetof the Antarctic Cold Reversal (ACR) period, our results do not show a clearlead or lag (Antarctic temperature leads by 50 years, within a range of−137 to 376 years, 68 % probability). The same is true at the end of the ACR(CO2 leads by 65 years, within a range of 211 to 117 years, 68 %probability). However, the timings of changes in trends for the individualproxy records show variations from the stack, indicating regional differencesin the pattern of temperature change, particularly in the WAIS Divide recordat the onset of the deglaciation; the Dome Fuji record at the deglaciationend; and the EDML record after 16 ka (EPICA Dronning Maud Land, where EPICA is the European Project for Ice Coring in Antarctica). In addition, two changes – one at 16 ka in the CO2 record and one after the ACR onset in three of theisotopic temperature records – do not have high-probability counterparts in the other record. The likely-variable phasing we identify testify to thecomplex nature of the mechanisms driving the carbon cycle and Antarctictemperature during the deglaciation. 

Well-dated records of alpine glacier fluctuations provide important insights into the temporal and spatial structure of climate variability. Cirque moraine records from the western United States have historically been interpreted as a resurgence of alpine glaciation in the middle-to-late Holocene (i.e., Neoglaciation), but these moraines remain poorly dated because of limited numerical age constraints at most locations. Here we present 130¹⁰Be ages on 19 moraines deposited by 14 cirque glaciers across this region that have been interpreted as recording these Neoglacial advances. Our¹⁰Be chronology indicates instead that these moraines were deposited during the latest Pleistocene to earliest Holocene, with several as old as 14–15ka. Our results thus show that glaciers retreated from their Last Glacial Maximum (LGM) extent into cirques relatively early during the last deglaciation, experienced small fluctuations during the Bølling–Allerød–Younger Dryas interval, and remained within the maximum limit of the Little Ice Age (LIA) advance of the last several centuries throughout most of the Holocene. Climate modeling suggests that increasing local summer insolation and greenhouse gases were the primary controls on early glacier retreat from their LGM positions. We then infer that subsequent intrinsic climate variability and Younger Dryas cooling caused minor fluctuations during the latest Pleistocene, while the LIA advance represents the culmination of a cooling trend through the Holocene in response to decreasing boreal summer insolation.

 

Abstract. In 2013 an ice core was recovered from Roosevelt Island, an ice dome between two submarine troughs carved by paleo-ice-streams in the Ross Sea, Antarctica. The ice core is part of the Roosevelt Island Climate Evolution (RICE) project and provides new information about the past configuration of the West Antarctic Ice Sheet (WAIS) and its retreat during the last deglaciation. In this work we present the RICE17 chronology, which establishes the depth–age relationship for the top 754 m of the 763 m core. RICE17 is a composite chronology combining annual layer interpretations for 0–343 m (Winstrup et al., 2019) with new estimates for gas and ice ages based on synchronization of CH4 and δ18Oatm records to corresponding records from the WAIS Divide ice core and by modeling of the gas age–ice age difference. Novel aspects of this work include the following: (1) an automated algorithm for multiproxy stratigraphic synchronization of high-resolution gas records; (2) synchronization using centennial-scale variations in methane for pre-anthropogenic time periods (60–720 m, 1971 CE to 30 ka), a strategy applicable for future ice cores; and (3) the observation of a continuous climate record back to ∼65 ka providing evidence that the Roosevelt Island Ice Dome was a constant feature throughout the last glacial period.