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Element isotopes are characterized by distinct atomic masses and nuclear spins, which can significantly influence material properties. Notably, however, isotopes in natural materials are homogenously distributed in space. Here, we propose a method to configure material properties by repositioning isotopes in engineered van der Waals (vdW) isotopic heterostructures. We showcase the properties of hexagonal boron nitride (hBN) isotopic heterostructures in engineering confined photon-lattice waves—hyperbolic phonon polaritons. By varying the composition, stacking order, and thicknesses of h¹⁰BN and h¹¹BN building blocks, hyperbolic phonon polaritons can be engineered into a variety of energy-momentum dispersions. These confined and tailored polaritons are promising for various nanophotonic and thermal functionalities. Due to the universality and importance of isotopes, our vdW isotope heterostructuring method can be applied to engineer the properties of a broad range of materials.

 

We present a catalog of 315 protostellar outflow candidates detected in SiOJ= 5 − 4 in the ALMA-IMF Large Program, observed with ∼2000 au spatial resolution, 0.339 km s⁻¹velocity resolution, and 2–12 mJy beam⁻¹(0.18–0.8 K) sensitivity. We find median outflow masses, momenta, and kinetic energies of ∼0.3M_⊙, 4M_⊙km s⁻¹, and 10⁴⁵erg, respectively. Median outflow lifetimes are 6000 yr, yielding median mass, momentum, and energy rates of$\dot{M}$= 10^−4.4M_⊙yr⁻¹,$\dot{P}$= 10^−3.2M_⊙km s⁻¹yr⁻¹, and$\dot{E}$= 1L_⊙. We analyze these outflow properties in the aggregate in each field. We find correlations between field-aggregated SiO outflow properties and total mass in cores (∼3σ–5σ), and no correlations above 3σwith clump mass, clump luminosity, or clump luminosity-to-mass ratio. We perform a linear regression analysis and find that the correlation between field-aggregated outflow mass and total clump mass—which has been previously described in the literature—may actually be mediated by the relationship between outflow mass and total mass in cores. We also find that the most massive SiO outflow in each field is typically responsible for only 15%–30% of the total outflow mass (60% upper limit). Our data agree well with the established mechanical force−bolometric luminosity relationship in the literature, and our data extend this relationship up toL≥ 10⁶L_⊙and$\dot{P}$≥ 1M_⊙km s⁻¹yr⁻¹. Our lack of correlation with clumpL/Mis inconsistent with models of protocluster formation in which all protostars start forming at the same time.

 

Use of structured roles to facilitate cooperative learning is an evidence-based practice that has been shown to improve student performance, attitude, and persistence. The combination of structured roles and activities also helps build students’ process skills including communication and metacognition. While these benefits have been shown in a variety of disciplines, most prior work has focused on in-person, synchronous settings, and few studies have looked at online, synchronous settings. With the ongoing COVID-19 pandemic, we need a better understanding of how cooperative learning takes place online and what differences may exist between online and in-person modalities. This work-in-progress serves to document our development of an observation protocol to help us answer research questions such as the following: Do group members participate equally? Do group members’ contributions match their role? How do groups connect and bond with each other? How do groups seek help?