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We report the detailed mechanism behind the β to γ phase transformation in Sn-doped and Si-implanted Ga2O3 that we determined based on the direct observation of the atomic scale structure using scanning transmission electron microscopy (STEM). Quantitative analysis of the STEM images revealed that the high concentration of impurity atoms favored the formation of interstitial–divacancy complexes, which then leads to the secondary relaxation that creates additional interstitial atoms and cation vacancies, resulting in a local structure that closely resembles γ-Ga2O3. We explain the mechanism of how the impurity atoms facilitate the transformation, as well as the detailed sequence of the local γ phase transformation. The findings here offer an insight on how the lattice respond to the external stimuli, such as doping and strain, and transform into different structures, which is important for advancing Ga2O3 but also a variety of low symmetry crystals and oxides with multiple polymorphs.

 

Abstract Using resolved optical stellar photometry from the Panchromatic Hubble Andromeda Treasury Triangulum Extended Region survey, we measured the star formation history near the position of 85 supernova remnants (SNRs) in M33. We constrained the progenitor masses for 60 of these SNRs, finding that the remaining 25 remnants had no local star formation in the last 56 Myr, consistent with core-collapse supernovae, making them potential Type Ia candidates. We then infer a progenitor mass distribution from the age distribution, assuming single star evolution. We find that the progenitor mass distribution is consistent with being drawn from a power law with an index of − 2.9 − 1.0 + 1.2 . Additionally, we infer a minimum progenitor mass of 7.1 − 0.2 + 0.1 M ⊙ from this sample, consistent with several previous studies, providing further evidence that stars with ages older than the lifetimes of single 8 M ⊙ stars are producing supernovae.