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Award ID contains: 1361516

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  1. ; ; ; ; ; (, Journal of Raman Spectroscopy)
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  2. ; ; ; ; (, Photochemistry and Photobiology)
  3. ; ; ; ; (, Proceedings of the National Academy of Sciences)
  4. ; ; ; (, The Journal of Physical Chemistry Letters)
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  5. ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  6. ; ; ; ; (, Chemical Science)
    Core-resonant circular dichroism (CD) signals are induced by molecular chirality and vanish for achiral molecules and racemic mixtures. The highly localized nature of core excitations makes them ideal probes of local chirality within molecules. Simulations of the circular dichroism spectra of several molecular families illustrate how these signals vary with the electronic coupling to substitution groups, the distance between the X-ray chromophore and the chiral center, geometry, and chemical structure. Clear insight into the molecular structure is obtained through analysis of the X-ray CD spectra. 
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