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Unrealized concepts of masked alkylidenes in (PNP)FeXY systems and alternative approaches to LnXmFe(IV)=CHR

https://doi.org/10.1016/j.poly.2020.114460

George, Gregory M. ; Wolczanski, Peter T. ; MacMillan, Samantha N. ; Cundari, Thomas R. ( May 2020 , Polyhedron)
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Oxidative Additions to Ti(IV) in [(dadi) 4– ]Ti IV (THF) Involve Carbon–Carbon Bond Formation and Redox-Noninnocent Behavior

https://doi.org/10.1021/acs.organomet.8b00930

Heins, Spencer P. ; Zhang, Bufan ; MacMillan, Samantha N. ; Cundari, Thomas R. ; Wolczanski, Peter T. ( March 2019 , Organometallics)

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Azaallyl-derived ring formation via redox coupling in first row transition metals

https://doi.org/10.1016/j.poly.2018.10.070

Hulley, Elliott B. ; Heins, Spencer P. ; Wolczanski, Peter T. ; Lancaster, Kyle M. ; Lobkovsky, Emil B. ( January 2019 , Polyhedron)

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Complexes of [(dadi)Ti(L/X)] m That Reveal Redox Non-Innocence and a Stepwise Carbene Insertion into a Carbon–Carbon Bond

https://doi.org/10.1021/acs.organomet.8b00188

Heins, Spencer P. ; Morris, Wesley D. ; Cundari, Thomas R. ; MacMillan, Samantha N. ; Lobkovsky, Emil B. ; Livezey, Nicholas M. ; Wolczanski, Peter T. ( June 2018 , Organometallics)

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Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides

https://doi.org/10.1021/acs.organomet.7b00753

Wolczanski, Peter T. ( February 2018 , Organometallics)

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Dispersion forces play a role in (Me 2 IPr)Fe(NAd)R 2 (Ad = adamantyl; R = neo Pe, 1-nor) insertions and Fe–R bond dissociation enthalpies (BDEs)

https://doi.org/10.1039/c7dt04145d

Cundari, Thomas R. ; Jacobs, Brian P. ; MacMillan, Samantha N. ; Wolczanski, Peter T. ( January 2018 , Dalton Transactions)

The effects of dispersion on migratory insertion reactions and related iron–carbon bond dissociation energies pertaining to (Me 2 IPr)FeR 2 (R = neo Pe, 1-nor), and the conversion of (Me 2 IPr)Fe(NAd)R 2 to (Me 2 IPr)Fe{N(Ad}R)R are investigated via calculations and structural comparisons. Dispersion appears to be an underappreciated, major contributor to common structure and reactivity relationships.
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Synthesis and Characterization of 5-Coordinate Tungsten Hydride Anions: [( t Bu 3 SiNH)( t Bu 3 SiN=) 2 HWR]M

https://doi.org/10.1002/ijch.201700042

Schafer, II, Daniel F. ; Wolczanski, Peter T. ; Lobkovsky, Emil B. ; MacMillan, Samantha N. ( November 2017 , Israel Journal of Chemistry)
High- and low-spin chelate complexes of iron featuring κ-C,X-CH 2 C 6 H 4 X (X = NMe 2 , PMe 2 , PPh 2 ) and κ-C,P-CH 2 PMe 2 ligands

https://doi.org/10.1016/j.jorganchem.2017.04.001

Jacobs, Brian P. ; Wolczanski, Peter T. ; MacMillan, Samantha N. ( October 2017 , Journal of Organometallic Chemistry)

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Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe—C Covalency in (Me 2 IPr)Fe(═NAd)R 2 (R = neo Pe, 1-nor)

https://doi.org/10.1021/jacs.7b06960

Jacobs, Brian P. ; Wolczanski, Peter T. ; Jiang, Quan ; Cundari, Thomas R. ; MacMillan, Samantha N. ( August 2017 , Journal of the American Chemical Society)

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