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Title: Reactivity of Ce( iv ) imido compounds with heteroallenes
The reactivity of alkali metal capped Ce( iv ) imido compounds [M(DME) 2 ][CeNAr F (TriNOx)] ( 1-M with M = K, Rb, Cs and Ar F = 3,5-bis(trifluoromethyl)phenyl) with CO 2 and organic isocyanates has been evaluated. 1-Cs reacted with CO 2 to yield an organocarbamate complex. Reaction of 1-K and 1-Rb with organic isocyanates yielded organoureate Ce( iv ) complexes.  more » « less
Award ID(s):
1664928
NSF-PAR ID:
10248418
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
56
Issue:
35
ISSN:
1359-7345
Page Range / eLocation ID:
4781 to 4784
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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