skip to main content


Search for: All records

Award ID contains: 1665139

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. null (Ed.)
    The title ketenylidene, [Au 3 (C 2 O)(C 26 H 35 O 2 P) 3 ](C 2 F 6 NO 4 S 2 ), was obtained upon exposure of [2-(dicyclohexylphosphino)-2′,6′-dimethoxy-1,1′-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide to acetic anhydride at elevated temperature. The ketenylidene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenylidene with atomic distances indicative of bonding interaction between the gold atoms. 
    more » « less
  2. Miller, S. (Ed.)
    Two new complementary Au(I)-catalyzed methods for the preparation of ester-substituted indolizines from easily accessible 2-propargyloxypyridines and either acetoacetates or dimethyl malonate are reported. These reactions tolerate a wide range of functionality, allowing for diversification at three distinct positions of the product (R, R1, R2). For electron-poor substrates, the highest yields are observed upon reaction with acetoacetates, while neutral and electron-rich substrates give higher yields upon treatment with dimethyl malonate. 
    more » « less