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Title: Crystal structure of tris(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl-κ P )-μ-oxoethenylidene- triangulo -trigold(I) bis(trifluoromethanesulfonyl)imide
The title ketenylidene, [Au 3 (C 2 O)(C 26 H 35 O 2 P) 3 ](C 2 F 6 NO 4 S 2 ), was obtained upon exposure of [2-(dicyclohexylphosphino)-2′,6′-dimethoxy-1,1′-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide to acetic anhydride at elevated temperature. The ketenylidene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenylidene with atomic distances indicative of bonding interaction between the gold atoms.  more » « less
Award ID(s):
1665139 1919565
NSF-PAR ID:
10223492
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Acta Crystallographica Section E Crystallographic Communications
Volume:
77
Issue:
5
ISSN:
2056-9890
Page Range / eLocation ID:
537 to 541
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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