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Existing transfer technologies in the construction of film-based electronics and devices are deeply established in the framework of native solid substrates. Here, we report a capillary approach that enables a fast, robust, and reliable transfer of soft films from liquid in a defect-free manner. This capillary transfer is underpinned by the transfer front of dynamic contact among receiver substrate, liquid, and film, and can be well controlled by a selectable motion direction of receiver substrates at a high speed. We demonstrate in extensive experiments, together with theoretical models and computational analysis, the robust capabilities of the capillary transfer using a versatile set of soft films with a broad material diversity of both film and liquid, surface-wetting properties, and complex geometric patterns of soft films onto various solid substrates in a deterministic manner. 

Two-dimensional (2-D) atomically thin graphene has exhibited overwhelming excellent properties over its bulk counterpart graphite, yet the broad applications and explorations of its unprecedented properties require a diversity of its geometric morphologies, beyond its inherently planar structures. In this study, we present a self-folding approach for converting 2-D planar free-standing graphene to 2-D and 3-D folded structures through the evaporation of its liquid solutions. This approach involves competition between the surface energy of the liquid, and the deformation energy and van der Waals energy of graphene. An energy-based theoretical model is developed to describe the self-folding process during liquid evaporation by incorporating both graphene dimensions and surface wettability. The critical elastocapillary length by liquid evaporation is extracted and exemplified by investigating three typical graphene geometries with rectangular, circular and triangular shapes. After the complete evaporation of the liquid, the critical self-folding length of graphene that can enable a stable folded pattern by van der Waals energy is also obtained. In parallel, full-scale molecular dynamics (MD) simulations are performed to monitor the evolution of deformation energies and folded patterns with liquid evaporation. The simulation results demonstrate the formation of 2-D folded racket-like and 3-D folded cone-like patterns and show remarkable agreement with theoretical predictions in both energy variations and folded patterns. This work offers quantitative guidance for controlling the self-folding of graphene and other 2-D materials into complex structures by liquid evaporation.