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Abstract Previous studies found conflicting results on the importance of temperature and precipitation versus geochemical variables for predicting soil organic carbon (SOC) concentrations and trends with depth, and most utilized linear statistical models. To reconcile the controversy, we used data from 2574 mineral horizons from 675 pits from National Ecological Observatory Network sites across North America, typically collected to 1 m depth. Climate was a fundamental predictor of SOC and played similarly important roles as some geochemical predictors. Yet, this only emerged in the generalized additive mixed model and random forest model and was obscured in the linear mixed model. Relationships between water availability and SOC were strongest in very dry ecosystems and SOC increased most strongly at mean annual temperature < 0°C. In all models, depth, oxalate‐extractable Al (Al_ox), pH, and exchangeable calcium plus exchangeable magnesium were important while silt + clay, oxalate‐extractable Fe (Fe_ox), and vegetation type were weaker predictors. Climate and pH were independently related to SOC and also interacted with geochemical composition: Fe_oxand Al_oxrelated more strongly to SOC in wet or cold climates. Most predictors had nonlinear threshold relationships with SOC, and a saturating response to increasing reactive metals indicates soils where SOC might be limited by C inputs. We observed a mostly constant relative importance of geochemical and climate predictors of SOC with increasing depth, challenging previous statements. Overall, our findings challenge the notion that climate is redundant after accounting for geochemistry and demonstrate that considering their nonlinearities and interactions improves spatial predictions of SOC. 

We used incubations of soil and stable isotope measurements to measure lignin, litter, and SOC decomposition over an 18-month lab incubation and assessed their relationships with geochemical, microbial, N-related and climatic factors across 156 mineral soils collected from 20 National Ecological Observatory Network (NEON) sites, which span broad biophysical gradients (climate, soil, and vegetation type) across North America. The soils were collected in 2019. Lignin decomposition and biogeochemical variables were also measured in an approximately 12-month field incubation. 

To understand controls on soil organic matter chemical composition across North America, we collected 13C NMR spectra and conducted and synthesized additional biogeochemical measurements from NEON Megapit soil samples as well as additional samples (total n = 42). This dataset supports the findings described in the associated manuscript by Hall, Ye et al. (2020).