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Abstract The termination of the last glacial period is marked by the northward migration of the ITCZ and the weakening of the South American Summer Monsoon (SASM). The transition between the wetter glacial period and the more arid Holocene period across the South American continent is punctuated by several abrupt millennial-scale tropical hydroclimatic events. While the Northern Hemisphere temperature forcing of these millennial-scale events is generally accepted, recently, equatorial forcing mechanisms have been put forward. In particular, the dipole between northeastern Brazil and the western Andes of Peru is absent during Heinrich 1, with wet conditions recorded in both regions. To explain this anomalous atmospheric behavior, researchers have suggested changes in the ENSO and Walker circulation over South America and questioned whether the ‘amount effect’ relationship between δ18O and precipitation persists through time. To better resolve tropical hydroclimate changes over the last glacial termination, more robust paleoclimate proxies are needed. Here, we present a new paleo-precipitation reconstruction based on trace metal (Mg/Ca, Sr/Ca, and Ba/Ca) and isotope (δ18O and δ13C) speleothem records from Antipayarguna cave in the Peruvian Andes (3800 masl). Our records date from 2,600 to 4,700 and 7,700 to 19,000 years BP, with an average age resolution of 44 years. These records overlap the previously published speleothem records from nearby Pacupahuain and Huagapo caves. The Antipayarguna δ18O data are highly correlated with southern hemisphere summer insolation and the Huascaran ice core δ18O record. The Antipayarguna trace metal ratios and δ18O isotope values correlate well over most of the record, suggesting that the δ18O at our site reflects the amount of local precipitation. However, at the end of the Younger Dryas (11.5-10.3 ka) and Heinrich Stadial 1 (16.4-14.9 ka), there is a decoupling of these proxies. These anomalies may be due to changes in δ18O caused by shifts in moisture source region or precipitation condensation factors (e.g. convergence level or subcloud evaporation). Alternatively, this could be due to a change in trace metal sources. We explore potential causes for these brief decoupling events through comparison with other paleoclimate records. 

Abstract The South American monsoon is central to the continent’s water and energy cycles, however, the relationships between the monsoon, regional water balance, and global climate change is poorly understood. Sediment records at Lake Junín (11°S, 76°W) provide an opportunity to explore these connections over the last 650 ka. Here, we focus on two interglacials, the Holocene (11.7–0 ka) and MIS 15 (621–563 ka), when sediment proxies suggest rapid regional hydroclimate fluctuations occurred. Clumped isotope distributions of lake carbonates reveal that interglacial water temperatures were similar to present, though analytical limitations preclude detecting the small temperature differences expected in the tropics (<2 °C). Combining the reconstructed water temperatures with carbonate oxygen (δ18O) and triple oxygen (Δ′17O) isotope values, we reconstruct precipitation δ18O values and lake water Δ′17O values. Precipitation δ18O values, a proxy of monsoon strength, range from -18.6 to -12.3 ‰ with lower values reflecting a stronger monsoon. Lake water Δ′17O values are -14 to 43 per meg and indicate the extent of lake water evaporation; lower values reflect a higher proportion of evaporation to inputs (i.e., more negative P-E). The precipitation δ18O and lake water Δ′17O values from both interglacials vary with the pacing of local summertime insolation, which follows an orbital pacing. These data document the close connection between Andean water balance, the South American monsoon, and global climate. Further, we analyze the relationship between precipitation δ18O and insolation, and we find that the relationship is consistent among interglacials, suggesting a similar response of the monsoon to orbital forcings over time. In contrast, while lake water Δ′17O and insolation are also correlated during both interglacials, water balance was overall more positive during MIS 15 than the Holocene. This suggests that either other global forcings or local basin dynamics can also contribute to water balance at Lake Junín. Together, these data provide new evidence of the connections between global climate, monsoon strength, and regional water balance. 

Abstract Climate variability over glacial-interglacial timescales is not well characterized in the tropical Andes, and paleoclimate records are lacking in this region. To offset this gap in knowledge, we analyzed organic compounds from sediment cores from Lake Junin (the Peruvian Andes) to better understand climate variability in the region since the LGM. We measured the δD of long and mid-chain n-alkanes (nC29 – terrestrial vegetation and nC23 – aquatic vegetation) to characterize changes in the intensity of the South American Summer Monsoon (SASM) and evaporative enrichment of lake water. We also measured the δ13C of these compounds to better understand the hydrology of the region and constrain the sources of organic matter through time. Additionally, we used the fractional abundances of brGDGTs to estimate changes in temperature over the same time period. Our results suggest that SASM intensity is controlled by insolation in the southern hemisphere. During the late Pleistocene, the δD of both nC29 and nC23 are relatively D-depleted indicating a wetter time period. This is followed by progressive D-enrichment of both nC29 and nC23 which suggests increasing aridity until the Holocene. The early Holocene is characterized by a decoupling between the δD of nC23 and nC29.The δD of nC23 becomes relatively more D-enriched, matching trends in a carbonate oxygen isotope record from Lake Junin, indicating increased lake-water evaporation during this time. Finally, the late Holocene is characterized by a return to wetter conditions. The δ13C of both nC29 and nC23 further confirms the hydrologic history of this region, while shedding light on vegetation dynamics. During the Pleistocene, the δ13C of both n-alkanes suggests DIC uptake, but at the start of the Holocene they diverge, showing two distinct plant communities, one entirely aquatic and one entirely terrestrial. Our brGDGT-based temperature reconstruction shares similar trends with alkenone-based SST reconstructions off the coast of Peru, indicating a consistent regional climate signal. 

Speleothem paleoclimate records from the Peruvian Andes have been interpreted to reflect the strength of the South American monsoon. While these interpretations have been verified through comparison with other regional and global climate records, the mechanics of the cave environment that facilitate the preservation of this signal with such consistency remain unstudied. Here, we present four years of environmental data from Huagapo and Pacupahuain cave, and one year from Antipayarguna cave. The data reveal that the cave environment is very stable with little to no change in temperature and 100% relative humidity year-round. This stability in cave air is juxtaposed with the monsoonal drip water pulse that increases drip rates over 40 times on average across all seven monitored drip sites. Compared to the amount-weighted precipitation average δ18Oprecip value, the cave drip water δ18ODW values are evaporatively 18O enriched during infiltration through the soil/epikarst. As the monsoonal precipitation pulse fades and drip rates decrease, changes in the drip water chemistry (trace elements Mg/Ca and Sr/Ca, dissolved inorganic carbon δ13CDW, and δ18ODW values) indicate that prior calcite precipi- tation (PCP) drives the trace element and δ13CDW variability. The δ13Cc and δ18Oc values of farmed slide calcite are highly variable. However, high drip rate and lower cave air pCO2 during the monsoon combine to increase calcite precipitation rates. This causes speleothem records from these caves to be weighted toward annual monsoon conditions. Calcite isotope values from actively growing stalagmite tops support this finding. These results suggest that speleothems from these caves are sensitive to changes in monsoon precipitation amount, because it determines the duration of the monsoon drip water pulse, and therein, the extent of dry season PCP. Further, these data indicate that heterogeneity in the dolomitic limestone massif causes offsets between the carbon isotopes and trace metal concentrations between the caves, highlighting the need to normalize these datasets when chronology-stacking these proxies. 

For the past few decades, many researchers have sought to understand how tropical hydroclimate responds to climate change via lakes, marine sediments, and speleothems records. Speleothem δ18O records throughout South America have shown that regional rainfall responds to Northern Hemisphere forcing on the millennial scale. Areas under the influence of the South Atlantic Convergence Zone (SACZ) have also shown a close relationship with local insolation on longer timescales. However, apart from the Cruz et al. (2007) record in Southern Brazil, long-term speleothem records throughout the continent have relied primarily on stable oxygen isotopes and are therefore limited to describing large-scale regional variability in rainfall. As such, many areas in South America still lack long-term records of local hydroclimate, which is critical to understanding how different components of the monsoon system respond to orbital and millennial-scale climate change. One proxy that has gained more attention in recent years is trace metal-to-calcium ratios (TM/Ca). Sr, Mg, and Ba to Ca ratios in speleothems are known in certain situations to respond to the degree of Prior Calcite Precipitation (PCP) above a drip site, a phenomenon directly tied to local aridity. In this study, we have obtained high-resolution TM/Ca measurements to pair with stable isotopes from samples spanning 23 to 66 ka from Huagapo Cave in the Peruvian Andes (11.27°S; 75.79°W). TM/Ca ratios in these samples are strongly correlated (R2>0.89), making them suitable for use as PCP proxies. We see that decreases in δ18O during Heinrich events are accompanied by a drop in TM/Ca. The period defined by the MIS 4/3 transition is accompanied by a simultaneous increase in TM/Ca and δ18O. TM/Ca and δ18O negatively correlate with local insolation for the entire record. Interestingly, the Paraíso Cave record from the Amazon Basin shows no correlation between regional or local hydroclimate and insolation during the last glacial period. The discrepancy between the two records and the close relationship between TM/Ca, δ18O, and local insolation in Huagapo samples, may call for a revised interpretation of Andes speleothem δ18O variability, which was originally thought to reflect rainout over the Amazon Basin. 

Climate variability at glacial-interglacial timescales is not well characterized in the tropical Andes, and paleoclimate records are lacking in this region. Lake Junin, in the Peruvian Andes, offers a unique and continuous paleoclimate archive that spans the last 700,000 years. Here, we use organic compounds to characterize climate variability in the region since the Last Glacial Maximum. First, we determined the preservation of organic matter in the sediments using the Carbon Preference Index (CPI), which suggests that n-alkanes have not been altered, and their H isotope composition can be used as paleo precipitation proxies. To reconstruct the isotopic composition of lake water, biomarkers from Eustigmatophyte algae (long chain diols) and diatoms (loliolide/isololiolide) have been identified. This will allow us to better understand aridity and evaporation as well as lake water inputs through time. Additionally, we will use the changes in n-alkane chain length distributions to constrain changes in terrestrial plants (long chain n-alkanes) and aquatic macrophytes (mid-chain n-alkanes) as a potential proxy for changes in lake level as a response to climate. Finally, temperature will be reconstructed using the distributions of br-GDGTs (branched glycerol dialkyl glycerol tetraethers). Using these set of proxies, we aim to characterize climate variability during the Holocene and the end of the LGM in the context of teleconnections between the South American Summer Monsoon and global climate patterns 

Paleoclimate records from the tropical Andes are scarce, and the variability of glacial-interglacial cycles is still not well characterized. Lake Junin, in the Peruvian Andes, offers a unique and continuous paleoclimate archive that spans the last 700,000 years. Here, we explore the potential of organic compounds in reconstructing Andean paleoclimate over the last 20,000 years. To address this, we first evaluated the preservation of organic matter in the lake’s sediments. The Carbon Preference Index (CPI) suggests that n-alkanes have not been altered, and their H isotope composition can be used as paleo precipitation proxies. Furthermore, biomarkers from Eustigmatophyte algae (long chain diols) and diatoms (loliolide/isololiolide) have been identified, and can be used to reconstruct the hydrogen isotopic composition of lake water. The contrast between rainfall and lake water will be a good tool for understanding lake water inputs through time as well as evaporation and aridity. Changes in n-alkane chain length will be used to identity the terrestrial plant (long chain n-alkanes) and aquatic macrophyte inputs (mid-chain n-alkanes), with potential implications for interpreting past lake level change as a function of climate. Finally, distributions of br-GDGTs (branched glycerol dialkyl glycerol tetraethers) will be used to reconstruct past temperature changes. With these proxies, we aim to characterize climate variability at the end of the Last Glacial Maximum (LGM) and the Holocene, with a focus on characterizing climate variability in the light of teleconnections between the South American Summer Monsoon and global climate patterns and their relationship with hydroclimate in the Amazon Basin. 

Glacial-interglacial transitions and abrupt millennial-scale events are the most prominent features in many paleoclimate records. Understanding these oscillations requires high-resolution time series from multiple locations to constrain the latitudinal response to forcings. Few high-resolution records exist from the Southern Hemisphere tropics that predate the last two glaciations. We present a high-resolution speleothem oxygen and carbon isotope record from Huagapo Cave in the Central Peruvian Andes covering Marine Isotope Stage (MIS) 8 glacial and MIS 9 interglacial (339 to 249 ka). Uranium-series dates on three stalagmites (n=18) with small age uncertainty ±1% allows us to resolve abrupt climate events similar in structure and duration to Dansgaard-Oescchger and Heinrich events. The South American Summer Monsoon (SASM) controls modern hydroclimate variability in the Andes, and previous records from Huagapo Cave have provided records of past SASM variability. Termination three (T-III) in our record has a steep increase in δ18O values of 5‰, punctuated by two stadial event decreases of ~3‰ (S8.1 and S8.2). This pattern is mirrored in the δ13C record, indicating that these millennial-scale events record hydroclimate and vegetation productivity changes. The same structure as our T-III record is found in other records globally, where they are noted to be Heinrich-like events. Frequency analysis indicates that the occurrence of these abrupt events changes between glacial cycles. Precession is weakly expressed in the δ18O record during MIS 8; similar to speleothem records from the region dating to the Last Glacial Maximum (LGM). Global ice cover and sea levels were similar in the LGM and MIS 8, but the Milankovitch insolation forcing differed. This change in SASM behavior is not observed in the East Asian monsoon, where the precession signal is dominant throughout. Interglacial precessional control is apparent during the latter half of MIS 9 and during Huagapo Cave intervals dating to MIS 6 and 7. These data indicate that the response to high-latitude forcing in the Southern Hemisphere tropics fluctuates through time, and potential explanations for low-latitude sensitivity to forcing factors are further explored. 

Atmospheric water vapor is predominately sourced from the tropics, such that characterizing the link between the tropical water cycle and global climate is of critical importance. Studies of central Andean climate from Lake Junín (11 °S, Peru) show that tropical glacial extent tracks global ice volume at a ~100 ka periodicity for the last 6 glacial cycles, indicating a tight coupling between tropical water balance and high latitude climate. However, it can be difficult to decouple temperature, precipitation, and water balance histories from records of glacial extent, especially for older intervals. In this work, we focus on one such interval, MIS 15 (621–563 ka), when the connections between tropical Andean water balance and global climate seem different than the last glacial cycle. Globally, MIS 15 was a weak interglacial, with cool temperatures and low GHG concentrations, however, the Lake Junín glacial record suggests an amplified hydroclimate response to this interglacial, stronger than any other over the last 700 ka. Causes for this apparent tropical amplification may be due to large, precession-paced changes in meridional insolation gradients that exceed other interglacials owning to enhanced orbital eccentricity. Given that the role of precession on South American monsoon strength over the last glacial cycle is well established, we hypothesize that monsoon strength may have been highly variable during MIS 15 and forced changes in central Andean water balance and glacial extent. To test this, we reconstructed temperature and evaporation histories using carbonate clumped and triple oxygen isotopes of Lake Junín sediments. Preliminary results suggest temperatures were relatively stable, but possibly lower than both the present and Holocene, consistent with cool global climate at that time. Triple oxygen isotope values vary substantially, indicating massive swings in lake hydrology, between open and (nearly?) closed basin hydrology on a ~12 ka cycle that exactly match insolation variations. From this work, we conclude that hydrologic change in the central Andes was rapid and extreme during MIS 15, owning to profound changes in monsoon strength. Given that monsoons in other sectors are also sensitive to insolation changes, our work could suggest pervasive hydrologic variability throughout the tropics at this time. 

Lake Junín, located in the uppermost Amazon Basin in central Peru, was drilled as part of the International Continental Drilling Program in 2015. A piston core with a composite length of ~95 m provides a continuous archive of upstream glacial activity spanning ~700,000 years. The age-depth model was established with 80 AMS 14C dates, 12 U-Th dated intervals of authigenic calcite, and 17 geomagnetic relative paleointensity tie points, and yields an age of 677±20 ka at 88 m. Four samples from near the base of the core reveal normal polarity paleomagnetic directions, consistent with an age younger than ~773 ka. The composite section comprises intervals of siliciclastic sediment intercalated with intervals dominated by authigenic calcite. The siliciclastic-rich intervals have a consistent signature, with relatively low concentrations of carbonate and organic carbon, and high values of bulk density, magnetic susceptibility and concentrations of elements derived from glacial erosion of the non-carbonate fraction of the regional bedrock. We find that tropical glaciers tracked changes in global ice volume and followed a clear ~100,000-year periodicity. Two caves, Huagapo and Pacupahuain, are located within 25 km of Lake Junín and provide a basis for testing and refining the age model of the Lake Junín drill core based on the high precision and accuracy of Uranium series dates for speleothems from these caves. The assumption here is that significant changes in regional ice volume will also be recorded in the 18O of cave drip water and thus in speleothems. Our initial target interval is the 9-8 marine isotope stage (MIS) boundary (~300 ka), which is recorded in the Junín drill core as an abrupt increase in the influx of glacigenic sediment, and in stalagmite 22-22 from Huagapo Cave as an abrupt 4.5‰ decrease in 18Ocalcite. The age of the onset of this transition in the Junín drill core is about 25 kyr older than that in Stal 22-22, and this difference is within the age model error envelope for the Junín drill core. Similar MIS boundaries provide the basis for adjustments in the Junín age model, which will improve the precision of correlation of this continuous record of tropical glaciation with paleoclimate archives in extra tropical regions.