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Award ID contains: 2108266

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  1. ; ; ; ; ; (, The Journal of Physical Chemistry Letters)
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  2. ; ; ; ; ; ; ; ; ; ; et al (, Journal of the American Chemical Society)
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  3. ; ; ; ; ; ; (, Reactive and Functional Polymers)
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  4. ; ; ; (, Macromolecules)
    Presented is the synthesis of cyclic polyacetylenes from alkynes and a study probing the functional group tolerance of catalyst 1. The synthesized polymers were characterized by employing GPC, NMR, and IR spectroscopy. The cyclic polyacetylenes spontaneously degrade, leading to the formation of lower molecular weight linear analogues. The degradation rate varied significantly based on the monomer substituents. These discoveries collectively reveal the functional group limits of catalyst 1 and the subsequent stability of the synthesized polymers, thus opening new avenues for advanced polymer design and applications. 
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  5. ; ; ; ; ; ; (, Chemical Communications)
    Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms. 
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  6. ; ; ; ; (, Polymer Chemistry)
    Demonstrated is the successful A 2 + B 2 RAFT step-growth polymerization of bis-acrylamides using a bifunctional trithiocarbonate chain transfer agent as the comonomer. Remarkably, homopropagation typical of acrylamides leading to branching and crosslinking was not observed. Moreover, synthesized poly(acrylamides) can be degraded by simply adding excess ethanolamine or PBu 3 . 
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  7. ; ; ; ; ; (, Macromolecules)
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