Stereochemistry can have a profound impact on polymer and materials properties. Unfortunately, straightforward methods for realizing high levels of stereocontrolled polymerizations are often challenging to achieve. In a departure from traditional metal‐mediated ring‐opening metathesis polymerization (ROMP), we discovered a remarkably simple method for controlling alkene stereochemistry in photoredox mediated metal‐free ROMP. Ion‐pairing, initiator sterics, and solvation effects each had profound impact on the stereochemistry of polynorbornene (PNB). Simple modifications to the reaction conditions produced PNB with
- Award ID(s):
- 2108266
- PAR ID:
- 10539703
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 59
- Issue:
- 94
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 13993 to 13996
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Stereochemistry can have a profound impact on polymer and materials properties. Unfortunately, straightforward methods for realizing high levels of stereocontrolled polymerizations are often challenging to achieve. In a departure from traditional metal‐mediated ring‐opening metathesis polymerization (ROMP), we discovered a remarkably simple method for controlling alkene stereochemistry in photoredox mediated metal‐free ROMP. Ion‐pairing, initiator sterics, and solvation effects each had profound impact on the stereochemistry of polynorbornene (PNB). Simple modifications to the reaction conditions produced PNB with
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D3CC04167K
