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Abstract The red hypergiant VY CMa is remarkable for its very visible record of high-mass-loss events observed over the range of wavelengths from the optical and infrared to the submillimeter region with Atacama Large Millimeter/submillimeter Array (ALMA). The SW Clump or SW knots are unique in the ejecta of VY CMa. Except for the central star, they are the brightest sources of dusty infrared emission in its complex ejecta. In this paper we combine the proper motions from the Hubble Space Telescope images, and infrared fluxes from 2 to 12μm with the¹²CO images from ALMA to determine their ages and mass estimates. The SW knots were ejected more than 200 yr ago with an active period lasting about 30 yr, and with a total mass in the Clump > 2 × 10⁻²M_⊙. 

Abstract TheJ= 5.5 → 4.5 andJ= 5 → 4 transitions of PO and PN, respectively, have been imaged in the envelope of hypergiant star VY Canis Majoris (VY CMa) using the Atacama Large Millimeter/submillimeter Array with angular resolutions of 0.″2 and 1.″5 and data from the Submillimeter Telescope of the Arizona Radio Observatory. These maps are the first high-fidelity images of PO and PN in a circumstellar envelope. Both molecules are primarily present in a spherical, star-centered region with a radius ∼60R_*(0.″5), indicating formation by LTE chemistry and then condensation into grains. PN, however, shows additional, fan-shaped emission 2″ southwest of the star, coincident with dust features resolved by Hubble Space Telescope (HST), as well as four newly identified distinct structures 1″–2″ toward the north, east, and west (Cloudlets I–IV), not visible in HST images. The “SW Fan” and the cloudlets are also prominent in theJ= 5.5 → 4.5 transition of NS. The correlation of PN with NS, SiO, and dust knots in the SW Fan suggests a formation in shocked gas enhanced with nitrogen. Excess nitrogen is predicted to favor PN synthesis over PO. Abundances for PN and PO in the spherical source aref∼ 4.4 × 10⁻⁸and 1.4 × 10⁻⁷, respectively, relative to H₂. Given a cosmic abundance of phosphorus, an unusually high fraction (∼35%) is contained in PO and PN. Alternatively, the stellar winds may be enriched in P (and N) by dredge-up from the interior of VY CMa. 

Abstract Molecular observations of four planetary nebulae (PNe), M4-17, Hu 1-1, M1-59, and Na 2, were conducted at 1–3 mm using the Arizona Radio Observatory’s 12 m antenna and Submillimeter Telescope, and the Institut de Radioastronomie Millimétrique 30 m Telescope. Toward M4-17, HNC (J= 3 → 2), CCH (N= 2 → 1,N= 3 → 2), CN (N= 1 → 0,N= 2 → 1), H₂CO (J_Ka,Kc= 2_1,2→ 1_1,1,J_Ka,Kc= 2_0,2→ 1_0,1,J_Ka,Kc= 2_1,1→ 1_1,0), CS (J= 3 → 2,J= 5 → 4), and H¹³CN (J= 2 → 1) were detected. An almost identical set of transitions was identified toward Hu 1-1. Moreover, c–C₃H₂was detected in Hu 1-1 via three 2 mm lines:J_Ka,Kc= 3_1,2→ 2_2,1,J_Ka,Kc= 4_1,4→ 3_0,3, andJ_Ka,Kc= 3_{2, 2}→ 2_1,1. HNC, CCH, CN, CS, and H¹³CN were found in M1-59, as well as H₂S via itsJ_Ka,Kc= 1_1,0→ 1_0,1line—the first detection of this key sulfur species in PNe. In addition, CCH and CN were identified in the 27,000 yr old Na 2. Among these four sources, CN and CCH were the most prevalent molecules (after CO and H₂) with fractional abundances, relative to H₂, off∼ 0.9–7.5 × 10⁻⁷and 0.8–7.5 × 10⁻⁷, respectively. CS and HNC have abundances in the rangef∼ 0.5–5 × 10⁻⁸, the latter resulting in HCN/HNC ∼ 3 across all three PNe. The unusual species H₂CO, c–C₃H₂, and H₂S hadf∼ 3–4 × 10⁻⁷, 10⁻⁸, and 6 × 10⁻⁸. This study suggests that elliptical PNe such as Hu 1-1 can have a diverse molecular composition. The presence of CN, CCH, and HCO⁺in Na 2, with comparable abundances to younger PNe, demonstrates that molecular content is maintained into the late PN stage. 

Abstract Despite model predictions, many planetary nebulae appear to have a relatively rich molecular content. Observational studies of over 30 such objects show the presence of a variety of gas-phase molecules, from simple species such as CN and CS, to more complex organics including H₂CO, HC₃N, c-C₃H₂, and CH₃CN. Other PNe contain fullerenes; carbonaceous and silicate dust features are also found. Molecular abundances also do not appear to vary with nebular age. Remnant material from the asymptotic giant branch appears to undergo chemical processing in the protoplanetary nebula phase and then is frozen out in planetary nebulae. PN ejecta are thus in part molecular in content and may account for the observation of complex molecules in diffuse clouds. 

Abstract The red hypergiant VY CMa is famous for its very visible record of high-mass-loss events. Recent CO observations with the Atacama Large Millimeter/submillimeter Array (ALMA) revealed three previously unknown large-scale outflows (Singh et al). In this paper, we use the CO maps to investigate the motions of a cluster of four clumps close to the star, not visible in the optical or infrared images. We present their proper motions measured from two epochs of ALMA images and determine the line-of-sight velocities of the gas in emission at the clumps. We estimate their masses and ages, or time since ejection, and conclude that all four were ejected during VY CMa’s active period in the early 20th century. Together with two additional knots observed with the Hubble Space Telescope, VY CMa experienced at least six massive outflows during a 30 yr period, with a total mass lost ≥0.07M_⊙. The position–velocity map of the¹²CO emission reveals previously unnoticed attributes of the older outer ejecta. In a very narrow range of Doppler velocities,¹²CO absorption and emission causes some of this outer material to be quite opaque. At those frequencies the inner structure is hidden and we see only emission from an extended outer region. This fact produces a conspicuous but illusory dark spot if one attempts to subtract the continuum in a normal way. 

Abstract A new interstellar molecule, FeC (X³Δ_i), has been identified in the circumstellar envelope of the carbon-rich asymptotic giant branch star IRC+10216. FeC is the second iron-bearing species conclusively observed in the interstellar medium, in addition to FeCN, also found in IRC+10216. TheJ= 4 → 3, 5 → 4, and 6 → 5 rotational transitions of this free radical near 160, 201, and 241 GHz, respectively, were detected in the lowest spin–orbit ladder, Ω = 3, using the Submillimeter Telescope of the Arizona Radio Observatory (ARO) for the 1 mm lines and the ARO 12 m at 2 mm. Because the ground state of FeC is inverted, these transitions are the lowest energy lines. The detected features exhibit slight U shapes with LSR velocities nearV_LSR≈ −26 km s⁻¹and linewidths of ΔV_1/2≈ 30 km s⁻¹, line parameters characteristic of IRC+10216. Radiative transfer modeling of FeC suggests that the molecule has a shell distribution with peak radius near 300R_*(∼6″) extending out to ∼500R_*(∼10″) and a fractional abundance, relative to H₂, off∼ 6 × 10⁻¹¹. The previous FeCN spectra were also modeled, yielding an abundance off∼ 8 × 10⁻¹¹in a larger shell situated near 800R_*. These distributions suggest that FeC may be the precursor species for FeCN. Unlike cyanides and carbon-chain molecules, diatomic carbides with a metallic element are rare in IRC+10216, with FeC being the first such detection. 

The envelopes of Red Supergiants (RSGs) have a unique chemical environment not seen in other types of stars. They foster an oxygen-rich synthesis but are tempered by sporadic and chaotic mass loss, which distorts the envelope and creates complex outflow sub-structures consisting of knots, clumps, and arcs. Near the stellar photosphere, molecules and grains form under approximate LTE conditions, as predicted by chemical models. However, the complicated outflows appear to have distinct chemistries generated by shocks and dust destruction. Various RSG envelopes have been probed for their molecular content, mostly by radio and millimeter observations; however, VY Canis Majoris (VY CMa) and NML Cygni (NML Cyg) display the highest chemical complexity, and also the most complicated envelope structure. Thus far, over 29 different molecules have been identified in the envelopes of RSGs. Some molecules are common for circumstellar gas, including CO, SiO, HCN and H2O, which have abundances of ∼10−6–10−4, relative to H2. More exotic oxides have additionally been discovered, such as AlO, AlOH, PO, TiO2, and VO, with abundances of ∼10−9–10−7. RSG shells support intricate maser emission in OH, H2O and SiO, as well. Studies of isotope ratios in molecules suggest dredge-up at least into the H-burning shell, but further exploration is needed. 

The discovery of over 200 gas-phase chemical compounds in interstellar space has led to the speculation that this non-terrestrial synthesis may play a role in the origin of life. These identifications were possible because of laboratory spectroscopy, which provides the molecular “fingerprints” for astronomical observations. Interstellar chemistry produces a wide range of small, organic molecules in dense clouds, such as NH2COCH3, CH3OCH3, CH3COOCH3, and CH2(OH)CHO. Carbon is also carried in fullerenes C60 and C70, which can preserve C-C bonds from circumstellar environments for future synthesis. Elusive phosphorus is now found in molecular clouds, the sites of star formation, in the molecules PO and PN. Such clouds can collapse into solar systems, although the chemical/physical processing of the emerging planetary disk is uncertain. The presence of molecule-rich interstellar starting material, as well as the link to planetary bodies such as meteorites and comets, suggests astrochemical processes set a prebiotic foundation.