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1. Hematite (U-Th)/He thermochronometry detects asperity flash heating during laboratory earthquakes

   https://doi.org/10.1130/G46965.1  

   Calzolari, Gabriele ; Ault, Alexis K. ; Hirth, Greg ; McDermott, Robert G. ( March 2020 , Geology)

   Abstract Evidence for coseismic temperature rise that induces dynamic weakening is challenging to directly observe and quantify in natural and experimental fault rocks. Hematite (U-Th)/He (hematite He) thermochronometry may serve as a fault-slip thermometer, sensitive to transient high temperatures associated with earthquakes. We test this hypothesis with hematite deformation experiments at seismic slip rates, using a rotary-shear geometry with an annular ring of silicon carbide (SiC) sliding against a specular hematite slab. Hematite is characterized before and after sliding via textural and hematite He analyses to quantify He loss over variable experimental conditions. Experiments yield slip surfaces localized in an ∼5–30-µm-thick layer of hematite gouge with <300-µm-diameter fault mirror (FM) zones made of sintered nanoparticles. Hematite He analyses of undeformed starting material are compared with those of FM and gouge run products from high-slip-velocity experiments, showing >71% ± 1% (1σ) and 18% ± 3% He loss, respectively. Documented He loss requires short-duration, high temperatures during slip. The spatial heterogeneity and enhanced He loss from FM zones are consistent with asperity flash heating (AFH). Asperities >200–300 µm in diameter, producing temperatures >900 °C for ∼1 ms, can explain observed He loss. Results provide new empirical evidence describing AFH and the rolemore »of coseismic temperature rise in FM formation. Hematite He thermochronometry can detect AFH and thus seismicity on natural FMs and other thin slip surfaces in the upper seismogenic zone of Earth’s crust.« less
2. Seismicity recorded in hematite fault mirrors in the Rio Grande rift

   https://doi.org/10.1130/GES02426.1  

   Odlum, M.L. ; Ault, A.K. ; Channer, M.A. ; Calzolari, G. ( November 2021 , Geosphere)

   Abstract Exhumed fault rocks provide a textural and chemical record of how fault zone composition and architecture control coseismic temperature rise and earthquake mechanics. We integrated field, microstructural, and hematite (U-Th)/He (He) thermochronometry analyses of exhumed minor (square-centimeter-scale surface area) hematite fault mirrors that crosscut the ca. 1400 Ma Sandia granite in two localities along the eastern flank of the central Rio Grande rift, New Mexico. We used these data to characterize fault slip textures; evaluate relationships among fault zone composition, thickness, and inferred magnitude of friction-generated heat; and document the timing of fault slip. Hematite fault mirrors are collocated with and crosscut specular hematite veins and hematite-cemented cataclasite. Observed fault mirror microstructures reflect fault reactivation and strain localization within the comparatively weaker hematite relative to the granite. The fault mirror volume of some slip surfaces exhibits polygonal, sintered hematite nanoparticles likely created during coseismic temperature rise. Individual fault mirror hematite He dates range from ca. 97 to 5 Ma, and ~80% of dates from fault mirror volume aliquots with high-temperature crystal morphologies are ca. 25–10 Ma. These aliquots have grain-size–dependent closure temperatures of ~75–108 °C. A new mean apatite He date of 13.6 ± 2.6 Ma from the Sandiamore »granite is consistent with prior low-temperature thermochronometry data and reflects rapid, Miocene rift flank exhumation. Comparisons of thermal history models and hematite He data patterns, together with field and microstructural observations, indicate that seismicity along the fault mirrors at ~2–4 km depth was coeval with rift flank exhumation. The prevalence and distribution of high-temperature hematite grain morphologies on different slip surfaces correspond with thinner deforming zones and higher proportions of quartz and feldspar derived from the granite that impacted the bulk strength of the deforming zone. Thus, these exhumed fault mirrors illustrate how evolving fault material properties reflect but also govern coseismic temperature rise and associated dynamic weakening mechanisms on minor faults at the upper end of the seismogenic zone.« less
3. Iron Oxide (U–Th)/He Thermochronology: New Perspectives on Faults, Fluids, and Heat

   https://doi.org/10.2138/gselements.16.5.319  

   Cooperdock, Emily H. ; Ault, Alexis K. ( October 2020 , Elements)

   Fault zones record the dynamic motion of Earth’s crust and are sites of heat exchange, fluid–rock interaction, and mineralization. Episodic or long-lived fluid flow, frictional heating, and/or deformation can induce open-system chemical behavior and make dating fault zone processes challenging. Iron oxides are common in a variety of geologic settings, including faults and fractures, and can grow at surface-to magmatic temperatures. Recently, iron oxide (U–Th)/He thermochronology, coupled with microtextural and trace element analyses, has enabled new avenues of research into the timing and nature of fluid–rock interactions and deformation. These constraints are important for understanding fault zone evolution in space and time.
4. Nanoscale evidence for temperature-induced transient rheology and postseismic fault healing

   https://doi.org/10.1130/G46317.1  

   Ault, A.K. ; Jensen, J.L. ; McDermott, R.G. ; Shen, F.-A. ; Van Devener, B.R. ( October 2019 , Geology)

   Abstract Friction-generated heat and the subsequent thermal evolution control fault material properties and thus strength during the earthquake cycle. We document evidence for transient, nanoscale fault rheology on a high-gloss, light-reflective hematite fault mirror (FM). The FM cuts specularite with minor quartz from the Pleistocene El Laco Fe-ore deposit, northern Chile. Scanning and transmission electron microscopy data reveal that the FM volume comprises a <50-μm-thick zone of polygonal hematite nanocrystals with spherical silica inclusions, rhombohedral twins, no shape or crystallographic preferred orientation, decreasing grain size away from the FM surface, and FM surface magnetite nanoparticles and Fe2+ suboxides. Sub–5-nm-thick silica films encase hematite grains and connect to amorphous interstitial silica. Observations imply that coseismic shear heating (temperature >1000 °C) generated transiently amorphous, intermixed but immiscible, and rheologically weak Fe-oxide and silica. Hematite regrowth in a fault-perpendicular thermal gradient, sintering, twinning, and a topographic network of nanometer-scale ridges from crystals interlocking across the FM surface collectively restrengthened fault material. Results reveal how temperature-induced weakening preconditions fault healing. Nanoscale transformations may promote subsequent strain delocalization and development of off-fault damage.
5. Investigating temperature and origin of fluids that circulated within a brittle fault array in the West Antarctic Rift System

   Pollatsek, Emory ; Siddoway, Christine ; and Gevedon, Michelle ( September 2022 , 29th West Antarctic Ice Sheet Workshop)

   Outcrops of brittle faults are rare in Marie Byrd Land, West Antarctica, because fault damage zones commonly undergo enhanced erosion and form bedrock troughs occupied by glacier ice. Where exposures do exist, faults yield information about regional strain in the West Antarctic Rift System (WARS) and may host minerals that contain a record of the temperature and chemistry of fluids during regional-scale faulting. In MBL’s southern Ford Ranges, bordering Ross Sea, a distinctive fault array was sampled that hosts tourmaline and quartz, a mineral-pair that can provide temperature and composition of fault-associated fluids, using 18O. Host rocks are tourmaline-free. At three separate sites, fault surfaces display strongly aligned tourmaline, suggesting that mineralization occurred during tectonism. One site features highly polished, or mirrored, surfaces, a characteristic that may indicate tourmaline precipitation during seismic slip. The orientation and kinematics of the high angle faults are NNW-striking: normal-slip, and WNW-ESE striking: right-lateral strike-slip. The timing of mineralization is yet to be determined, but viable possibilities are that the faults formed during broad intracontinental extension during formation of Ross Embayment in the Cretaceous, or during development of deep, narrow basins beneath the RIS grounding zone, in the Neogene (newly detected, see Tankersley et al.,more »this meeting). Once formed, tourmaline is resistant to chemical and isotopic re-equilibration, and therefore can retain a record of its conditions during formation. We used oxygen isotope compositions of tourmaline and quartz pairs to investigate temperatures, fluid-rock ratios, and fluid sources, with bearing on fault-localized flux of fluids and geothermal heat. Analyzed tourmaline and quartz were separated from the upper ~2mm of the fault surfaces, as well as quartz separated from host rock in the same hand samples. Tourmaline 18O ratios (n=4) fall within a range of +9.2 to +10.4 ± 0.1 ‰ VSMOW (average 9.7‰, StDev = 0.7). Paired quartz yield 18O values of +11.1 to +10.3 ± 0.1 ‰. Relative isotopic homogeneity between sites suggests similar fluid conditions were present across the region and supports field evidence for that the structures form a regional fault array. ∆Qtz-Trm values fall between 1.3 and 2.0, and 18O of quartz in faults closely resembles 18O of host rock quartz. We tentatively determine the water oxygen isotope ratio as greater than ~7.7 ‰. Plutonic-metamorphic associations in the immediate region, and comparisons with similar faults elsewhere (i.e. Isola d’Elba, Italy), suggest temperatures as high as 500°C for the fluids that circulated into the faults. The data are interpreted to show that brittle faults provided pathways for hot fluids derived from mid-crustal processes to make their way to shallow crustal depths. 18O values indicate magmatic and/or metamorphic fluid sources, with minor to no introduction of meteoric fluids. Tourmaline-quartz pairs did not attain equilibrium, likely due to tourmaline’s rapid crystallization. On-going investigation includes analysis of H and B isotopes in tourmaline, which will better characterize the relationship between fault-hosted and mid-crustal fluids.« less