The heterogeneous microstructure of semicrystalline polymers complicates the relationship between their electrical conductivity and carrier concentration. Charge transport models typically describe conductivity with an assumption of uniform doping throughout the material. Here, the evolution in morphology and optoelectronic properties of poly(3‐hexylthiophene) (P3HT) is reported as a function of carrier concentration in an organic electrochemical transistor using a polymeric ionic liquid (PIL) as the gate insulator.
The microstructure dependence of carrier mobility and recombination rates of neat films of poly 3‐hexylthyophene (P3HT) were determined for a range of materials of weight‐average molecular weights,
- NSF-PAR ID:
- 10046283
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science Part B: Polymer Physics
- Volume:
- 56
- Issue:
- 1
- ISSN:
- 0887-6266
- Page Range / eLocation ID:
- p. 31-35
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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