More Like this

1. Dispersion forces play a role in (Me 2 IPr)Fe(NAd)R 2 (Ad = adamantyl; R = neo Pe, 1-nor) insertions and Fe–R bond dissociation enthalpies (BDEs)

   https://doi.org/10.1039/c7dt04145d  

   Cundari, Thomas R. ; Jacobs, Brian P. ; MacMillan, Samantha N. ; Wolczanski, Peter T. ( January 2018 , Dalton Transactions)

   The effects of dispersion on migratory insertion reactions and related iron–carbon bond dissociation energies pertaining to (Me 2 IPr)FeR 2 (R = neo Pe, 1-nor), and the conversion of (Me 2 IPr)Fe(NAd)R 2 to (Me 2 IPr)Fe{N(Ad}R)R are investigated via calculations and structural comparisons. Dispersion appears to be an underappreciated, major contributor to common structure and reactivity relationships. 

   more » « less
2. Electronic Structures, Spectroscopy, and Electrochemistry of [M(diimine)(CN-BR 3 ) 4 ] 2– (M = Fe, Ru; R = Ph, C 6 F 5 ) Complexes

   https://doi.org/10.1021/acs.inorgchem.0c00632  

   Ngo, Danh X. ; Del Ciello, Sarah A. ; Barth, Alexandra T. ; Hadt, Ryan G. ; Grubbs, Robert H. ; Gray, Harry B. ; McNicholas, Brendon J. ( July 2020 , Inorganic Chemistry)

   null (Ed.)
3. Solid-State End-On to Side-On Isomerization of (N═N) 2– in {[(R 2 N) 3 Nd] 2 N 2 } 2– (R = SiMe 3 ) Connects In Situ Ln III (NR 2 ) 3 /K and Isolated [Ln II (NR 2 ) 3 ] 1– Dinitrogen Reduction

   https://doi.org/10.1021/jacs.2c06716  

   Chung, Amanda B. ; Rappoport, Dmitrij ; Ziller, Joseph W. ; Cramer, Roger E. ; Furche, Filipp ; Evans, William J. ( September 2022 , Journal of the American Chemical Society)
4. Formation of the End-on Bound Lanthanide Dinitrogen Complexes [(R 2 N) 3 Ln–N═N–Ln(NR 2 ) 3 ] 2– from Divalent [(R 2 N) 3 Ln] 1– Salts (R = SiMe 3 )

   https://doi.org/10.1021/jacs.0c01021  

   Ryan, Austin J. ; Balasubramani, Sree ganesh ; Ziller, Joseph W. ; Furche, Filipp ; Evans, William J. ( May 2020 , Journal of the American Chemical Society)

   null (Ed.)
5. A 10 6 -Fold Enhancement in N 2 -Binding Affinity of an Fe 2 (μ-H) 2 Core upon Reduction to a Mixed-Valence Fe II Fe I State

   https://doi.org/10.1021/ja507217v  

   Rittle, Jonathan ; McCrory, Charles C. ; Peters, Jonas C. ( October 2014 , Journal of the American Chemical Society)