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Title: Cationic magnesium hydride [MgH] + stabilized by an NNNN-type macrocycle
A magnesium hydride cation [(L)MgH] + supported by a macrocyclic ligand (L = Me 4 TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH 2 Mg{N(SiMe 3 ) 2 } 2 ] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
Authors:
; ; ; ; ; ;
Award ID(s):
1658652
Publication Date:
NSF-PAR ID:
10088162
Journal Name:
Chemical Communications
Volume:
55
Issue:
22
Page Range or eLocation-ID:
3199 to 3202
ISSN:
1359-7345
Sponsoring Org:
National Science Foundation
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