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1. Deep abiotic weathering of pyrite

   https://doi.org/10.1126/science.abb8092  

   Gu, Xin; Heaney, Peter J.; Reis, Fabio D. A. Aarão; Brantley, Susan L. (October 2020, Science)

   Pyrite is a ubiquitous iron sulfide mineral that is oxidized by trace oxygen. The mineral has been largely absent from global sediments since the rise in oxygen concentration in Earth’s early atmosphere. We analyzed weathering in shale, the most common rock exposed at Earth’s surface, with chemical and microscopic analysis. By looking across scales from 10⁻⁹to 10²meters, we determined the factors that control pyrite oxidation. Under the atmosphere today, pyrite oxidation is rate-limited by diffusion of oxygen to the grain surface and regulated by large-scale erosion and clast-scale fracturing. We determined that neither iron- nor sulfur-oxidizing microorganisms control global pyrite weathering fluxes despite their ability to catalyze the reaction. This multiscale picture emphasizes that fracturing and erosion are as important as atmospheric oxygen in limiting pyrite reactivity over Earth’s history. 

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2. Inversions of landslide strength as a proxy for subsurface weathering

   https://doi.org/10.1038/s41467-022-33798-5  

   Alberti, Stefano; Leshchinsky, Ben; Roering, Josh; Perkins, Jonathan; Olsen, Michael J. (December 2022, Nature Communications)

   Abstract Distributions of landslide size are hypothesized to reflect hillslope strength, and consequently weathering patterns. However, the association of weathering and critical zone architecture with mechanical strength properties of parent rock and soil are poorly-constrained. Here we use three-dimensional stability to analyze 7330 landslides in western Oregon to infer combinations of strength - friction angles and cohesion - through analysis of both failed and reconstructed landslide terrain. Under a range of conditions, our results demonstrate that the failure envelope that relates shear strength and normal stress in landslide terrain is nonlinear owing to an exchange in strength with landslide thickness. Despite the variability in material strength at large scales, the observed gradient in proportional cohesive strength with landslide thickness may serve as a proxy for subsurface weathering. We posit that the observed relationships between strength and landslide thickness are associated with the coalescence of zones of low shear strength driven by fractures and weathering, which constitutes a first-order control on the mechanical behavior of underlying soil and rock mass. 

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3. A reactive transport model for Marcellus shale weathering

   https://doi.org/10.1016/j.gca.2017.08.011  

   Heidari, Peyman; Li, Li; Jin, Lixin; Williams, Jennifer Z.; Brantley, Susan L. (November 2017, Geochimica et Cosmochimica Acta)
4. Subaerial weathering drove stabilization of continents

   https://doi.org/10.1038/s41586-024-07307-1  

   Reimink, Jesse R; Smye, Andrew J (May 2024, Nature)

   Abstract Earth’s silica-rich continental crust is unique among the terrestrial planets and is critical for planetary habitability. Cratons represent the most imperishable continental fragments and form about 50% of the continental crust of the Earth, yet the mechanisms responsible for craton stabilization remain enigmatic¹. Large tracts of strongly differentiated crust formed between 3 and 2.5 billion years ago, during the late Mesoarchaean and Neoarchaean time periods². This crust contains abundant granitoid rocks with elevated concentrations of U, Th and K; the formation of these igneous rocks represents the final stage of stabilization of the continental crust^2,3. Here, we show that subaerial weathering, triggered by the emergence of continental landmasses above sea level, facilitated intracrustal melting and the generation of peraluminous granitoid magmas. This resulted in reorganization of the compositional architecture of continental crust in the Neoarchaean period. Subaerial weathering concentrated heat-producing elements into terrigenous sediments that were incorporated into the deep crust, where they drove crustal melting and the chemical stratification required to stabilize the cratonic lithosphere. The chain of causality between subaerial weathering and the final differentiation of Earth’s crust implies that craton stabilization was an inevitable consequence of continental emergence. Generation of sedimentary rocks enriched in heat-producing elements, at a time in the history of the Earth when the rate of radiogenic heat production was on average twice the present-day rate, resolves a long-standing question of why many cratons were stabilized in the Neoarchaean period. 

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5. Mineral Weathering and Bedrock Weakening: Modeling Microscale Bedrock Damage Under Biotite Weathering

   https://doi.org/10.1029/2019JF005068  

   Shen, Xianda; Arson, Chloe; Ferrier, Ken L.; West, Nicole; Dai, Sheng (November 2019, Journal of Geophysical Research: Earth Surface)

   Bedrock weakening is of wide interest because it influences landscape evolution, chemical weathering, and subsurface hydrology. A longstanding hypothesis states that bedrock weakening is driven by chemical weathering of minerals like biotite, which expand as they weather and create stresses sufficient to fracture rock. We build on recent advances in rock damage mechanics to develop a model for the influence of multimineral chemical weathering on bedrock damage, which is defined as the reduction in bedrock stiffness. We use biotite chemical weathering as an example application of this model to explore how the abundance, aspect ratio, and orientation affect the time‐dependent evolution of bedrock damage during biotite chemical weathering. Our simulations suggest that biotite abundance and aspect ratio have a profound effect on the evolution of bedrock damage during biotite chemical weathering. These characteristics exert particularly strong influences on the timing of the onset of damage, which occurs earlier under higher biotite abundances and smaller biotite aspect ratios. Biotite orientation, by contrast, exerts a relatively weak influence on damage. Our simulations further show that damage development is strongly influenced by the boundary conditions, with damage initiating earlier under laterally confined boundaries than under unconfined boundaries. These simulations suggest that relatively minor differences in biotite populations can drive significant differences in the progression of rock weakening. This highlights the need for observations of biotite abundance, aspect ratio, and orientation at the mineral and field scales and motivates efforts to upscale this microscale model to investigate the evolution of the macroscale fracture network. 

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