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1. A method for controlling the magnetic field near a superconducting boundary in the ARIADNE axion experiment

   https://doi.org/10.1088/2058-9565/abf1cc  

   Fosbinder-Elkins, H. ; Kim, Y. ; Dargert, J. ; Harkness, M. ; Geraci, A. A. ; Levenson-Falk, E. ; Mumford, S. ; Fang, A. ; Kapitulnik, A. ; Matlashov, A. ; et al ( January 2022 , Quantum Science and Technology)

   The QCD axion is a particle postulated to exist since the 1970s to explain the strong-CP problem in particle physics. It could also account for all of the observed dark matter in the Universe. The axion resonant interaction detection experiment (ARIADNE) intends to detect the QCD axion by sensing the fictitious ‘magnetic field’ created by its coupling to spin. Short-range axion-mediated interactions can occur between a sample of laser-polarized³He nuclear spins and an unpolarized source-mass sprocket. The experiment must be sensitive to magnetic fields below the 10⁻¹⁹T level to achieve its design sensitivity, necessitating tight control of the experiment’s magnetic environment. We describe a method for controlling three aspects of that environment which would otherwise limit the experimental sensitivity. Firstly, a system of superconducting magnetic shielding is described to screen ordinary magnetic noise from the sample volume at the 10⁸level, which should be sufficient to reduce the contribution of Johnson noise in the sprocket-shaped source mass, expected to be at the 10⁻¹²T$/\sqrt{\mathrm{H}\mathrm{z}}$level, to below the threshold for signal detection. Secondly, a method for reducing magnetic field gradients within the sample up to 10²times is described, using a simple and cost-effective design geometry. Thirdly,more »a novel coil design is introduced which allows the generation of fields similar to those produced by Helmholtz coils in regions directly abutting superconducting boundaries. This method allows the nuclear Larmor frequency of the sample to be tuned to match the axion field modulation frequency set by the sprocket rotation. Finally, we experimentally investigate the magnetic shielding factor of sputtered thin-film superconducting niobium on quartz substrates for various geometries and film thicknesses relevant for the ARIADNE axion experiment using SQUID magnetometry. The methods may be generally useful for magnetic field control near superconducting boundaries in other experiments where similar considerations apply.

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2. Overview of the Cosmic Axion Spin Precession Experiment (CASPEr)

   Jackson Kimball, D. F. ; Afach, S. ; Aybas, D. ; Blanchard, J. W. ; Budker, D. ; Centers, G. ; Engler, M. ; Figueroa, N. L. ; Garcon, A. ; Graham, P. W. ; et al ( January 2020 , Springer proceedings in physics)

   Carosi, G. ; Rybka, G. (Ed.)

   An overview of our experimental program to search for axion and axion-like-particle (ALP) dark matter using nuclear magnetic resonance (NMR) techniques is presented. An oscillating axion field can exert a time-varying torque on nuclear spins either directly or via generation of an oscillating nuclear electric dipole moment (EDM). Magnetic resonance techniques can be used to detect such an effect. The first-generation experiments explore many decades of ALP parameter space beyond the current astrophysical and laboratory bounds. It is anticipated that future versions of the experiments will be sensitive to the axions associated with quantum chromodynamics (QCD) having masses <10^(−9) eV/c^2.
3. J -Driven dynamic nuclear polarization for sensitizing high field solution state NMR

   https://doi.org/10.1039/d1cp04186j  

   Concilio, Maria Grazia ; Kuprov, Ilya ; Frydman, Lucio ( January 2022 , Physical Chemistry Chemical Physics)

   Dynamic nuclear polarization (DNP) is widely used to enhance solid state nuclear magnetic resonance (NMR) sensitivity. Its efficiency as a generic signal-enhancing approach for liquid state NMR, however, decays rapidly with magnetic field B 0 , unless mediated by scalar interactions arising only in exceptional cases. This has prevented a more widespread use of DNP in structural and dynamical solution NMR analyses. This study introduces a potential solution to this problem, relying on biradicals with exchange couplings J ex of the order of the electron Larmor frequency ω E . Numerical and analytical calculations show that in such J ex ≈ ± ω E cases a phenomenon akin to that occurring in chemically induced DNP (CIDNP) happens, leading to different relaxation rates for the biradical singlet and triplet states which are hyperfine-coupled to the nuclear α or β states. Microwave irradiation can then generate a transient nuclear polarization build-up with high efficiency, at all magnetic fields that are relevant in contemporary NMR, and for all rotational diffusion correlation times that occur in small- and medium-sized molecules in conventional solvents.
4. Search for point sources of ultra-high-energy photons with the Telescope Array surface detector

   https://doi.org/10.1093/mnras/stz3618  

   Abbasi, R.U. ( February 2020 , Monthly notices of the Royal Astronomical Society)

   Ultra-high-energy (UHE) photons are an important tool for studying the high-energy Universe. A plausible source of photons with exa-eV (EeV) energy is provided by UHE cosmic rays (UHECRs) undergoing the Greisen–Zatsepin–Kuzmin process (Greisen 1966; Zatsepin & Kuzmin 1966) or pair production process (Blumenthal 1970) on a cosmic background radiation. In this context, the EeV photons can be a probe of both UHECR mass composition and the distribution of their sources (Gelmini, Kalashev & Semikoz 2008; Hooper, Taylor & Sarkar 2011). At the same time, the possible flux of photons produced by UHE protons in the vicinity of their sources by pion photoproduction or inelastic nuclear collisions would be noticeable only for relatively near sources, as the attenuation length of UHE photons is smaller than that of UHE protons; see, for example, Bhattacharjee & Sigl (2000) for a review. There also exists a class of so-called top-down models of UHECR generation that efficiently produce the UHE photons, for instance by the decay of heavy dark-matter particles (Berezinsky, Kachelriess & Vilenkin 1997; Kuzmin & Rubakov 1998) or by the radiation from cosmic strings (Berezinsky, Blasi & Vilenkin 1998). The search for the UHE photons was shown to be the most sensitive methodmore »of indirect detection of heavy dark matter (Kalashev & Kuznetsov 2016, 2017; Kuznetsov 2017; Kachelriess, Kalashev & Kuznetsov 2018; Alcantara, Anchordoqui & Soriano 2019). Another fundamental physics scenario that could be tested with UHE photons (Fairbairn, Rashba & Troitsky 2011) is the photon mixing with axion-like particles (Raffelt & Stodolsky 1988), which could be responsible for the correlation of UHECR events with BL Lac type objects observed by the High Resolution Fly’s Eye (HiRes) experiment (Gorbunov et al. 2004; Abbasi et al. 2006). In most of these scenarios, a clustering of photon arrival directions, rather than diffuse distribution, is expected, so point-source searches can be a suitable test for photon - axion-like particle mixing models. Finally, UHE photons could also be used as a probe for the models of Lorentz-invariance violation (Coleman & Glashow 1999; Galaverni & Sigl 2008; Maccione, Liberati & Sigl 2010; Rubtsov, Satunin & Sibiryakov 2012, 2014). The Telescope Array (TA; Tokuno et al. 2012; Abu-Zayyad et al. 2013c) is the largest cosmic ray experiment in the Northern Hemisphere. It is located at 39.3° N, 112.9° W in Utah, USA. The observatory includes a surface detector array (SD) and 38 fluorescence telescopes grouped into three stations. The SD consists of 507 stations that contain plastic scintillators, each with an area of 3 m2 (SD stations). The stations are placed in the square grid with 1.2 km spacing and cover an area of ∼700 km2. The TA SD is capable of detecting extensive air showers (EASs) in the atmosphere caused by cosmic particles of EeV and higher energies. The TA SD has been operating since 2008 May. A hadron-induced EAS significantly differs from an EAS induced by a photon because the depth of the shower maximum Xmax for a photon shower is larger, and a photon shower contains fewer muons and has a more curved front (see Risse & Homola 2007 for a review). The TA SD stations are sensitive to both muon and electromagnetic components of the shower and therefore can be triggered by both hadron-induced and photon-induced EAS events. In the present study, we use 9 yr of TA SD data for a blind search for point sources of UHE photons. We utilize the statistics of the SD data, which benefit from a high duty cycle. The full Monte Carlo (MC) simulation of proton-induced and photon-induced EAS events allows us to perform the photon search up to the highest accessible energies, E ≳ 1020 eV. As the main tool for the present photon search, we use a multivariate analysis based on a number of SD parameters that make it possible to distinguish between photon and hadron primaries. While searches for diffuse UHE photons were performed by several EAS experiments, including Haverah Park (Ave et al. 2000), AGASA (Shinozaki et al. 2002; Risse et al. 2005), Yakutsk (Rubtsov et al. 2006; Glushkov et al. 2007, 2010), Pierre Auger (Abraham et al. 2007, 2008a; Bleve 2016; Aab et al. 2017c) and TA (Abu-Zayyad et al. 2013b; Abbasi et al. 2019a), the search for point sources of UHE photons has been done only by the Pierre Auger Observatory (Aab et al. 2014, 2017a). The latter searches were based on hybrid data and were limited to the 1017.3 < E < 1018.5 eV energy range. In the present paper, we use the TA SD data alone. We perform the searches in five energy ranges: E > 1018, E > 1018.5, E > 1019, E > 1019.5 and E > 1020 eV. We find no significant evidence of photon point sources in all energy ranges and we set the point-source flux upper limits from each direction in the TA field of view (FOV). The search for unspecified neutral particles was also previously performed by the TA (Abbasi et al. 2015). The limit on the point-source flux of neutral particles obtained in that work is close to the present photon point-source flux limits.« less
5. The Landscape of Gold Nanocrystal Surface Chemistry

   https://doi.org/10.1021/acs.accounts.3c00109  

   Greskovich, Katherine M. ; Powderly, Kelly M. ; Kincanon, Maegen M. ; Forney, Nathan B. ; Jalomo, Catherine A. ; Wo, Anita ; Murphy, Catherine J. ( January 2023 , Accounts of Chemical Research)

   ConspectusGold nanoparticles (AuNPs) exhibit unique size- and shape-dependent properties not obtainable at the macroscale. Gold nanorods (AuNRs), with their morphology-dependent optical properties, ability to convert light to heat, and high surface-to-volume ratios, are of great interest for biosensing, medicine, and catalysis. While the gold core provides many fascinating properties, this Account focuses on AuNP soft surface coatings, which govern the interactions of nanoparticles with the local environments. Postmodification of AuNP surface chemistry can greatly alter NP colloidal stability, nano-bio interactions, and functionality. Polyelectrolyte coatings provide controllable surface-coating thickness and charge, which impact the composition of the acquired corona in biological settings. Covalent modification, in which covalently bound ligands replace the original capping layer, is often performed with thiols and disulfides due to their ability to replace native coatings. N-heterocyclic carbenes and looped peptides expand the possible functionalities of the ligand layer.The characterization of surface ligands bound to AuNPs, in terms of ligand density and dynamics, remains a challenge. Nuclear magnetic resonance (NMR) spectroscopy is a powerful tool for understanding molecular structures and dynamics. Our recent NMR work on AuNPs demonstrated that NMR data were obtainable for ligands on NPs with diameters up to 25 nm for the first time. Thismore »was facilitated by the strong proton NMR signals of the trimethylammonium headgroup, which are present in a distinct regime from other ligand protons’ signals. Ligand density analyses showed that the smallest AuNPs (below 4 nm) had the largest ligand densities, yet spin–spin T2 measurements revealed that these smallest NPs also had the most mobile ligand headgroups. Molecular dynamics simulations were able to reconcile these seemingly contradictory results.While NMR spectroscopy provides ligand information averaged over many NPs, the ligand distribution on individual particles’ surfaces must also be probed to fully understand the surface coating. Taking advantage of improvements in electron energy loss spectroscopy (EELS) detectors employed with scanning transmission electron microscopy (STEM), a single-layer graphene substrate was used to calibrate the carbon K-edge EELS signal, allowing quantitative imaging of the carbon atom densities on AuNRs with sub-nanometer spatial resolution. In collaboration with others, we revealed that the mean value for surfactant-bilayer-coated AuNRs had 10–30% reduced ligand density at the ends of the rods compared to the sides, confirming prior indirect evidence for spatially distinct ligand densities.Recent work has found that surface ligands on nanoparticles can, somewhat surprisingly, enhance the selectivity and efficiency of the electrocatalytic reduction of CO2 by controlling access to the active site, tuning its electronic and chemical environment, or denying entry to impurities that poison the nanoparticle surface to facilitate reduction. Looking to the future, while NMR and EELS are powerful and complementary techniques for investigating surface coatings on AuNPs, the frontier of this field includes the development of methods to probe the surface ligands of individual NPs in a high-throughput manner, to monitor nano-bio interactions within complex matrices, and to study structure–property relationships of AuNPs in biological systems.« less