Aqueous self‐assembly of amphiphilic block copolymers form diverse nanostructured morphologies depending on block volume fraction and solvophilicity. Stimuli‐responsive motifs have been combined with self‐assembled micelles to afford spatiotemporal, on‐demand encapsulation and payload release. However, the role of modular polymer architecture (i.e., bottlebrushes) in stimuli‐responsive aqueous self‐assembly is not fully understood. The synthesis, aqueous self‐assembly, and photoirradiation of photolabile, amphiphilic bottlebrush block copolymers is presented herein. Specifically, the efficient photoscission of
- Award ID(s):
- 1904631
- NSF-PAR ID:
- 10157079
- Date Published:
- Journal Name:
- Polymer Chemistry
- Volume:
- 10
- Issue:
- 44
- ISSN:
- 1759-9954
- Page Range / eLocation ID:
- 6037 to 6046
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/c9py01259a
