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1. Small Gd(III) Tags for Gd(III)–Gd(III) Distance Measurements in Proteins by EPR Spectroscopy

   https://doi.org/10.1021/acs.inorgchem.8b00133  

   Prokopiou, Georgia; Lee, Michael D.; Collauto, Alberto; Abdelkader, Elwy H.; Bahrenberg, Thorsten; Feintuch, Akiva; Ramirez-Cohen, Marie; Clayton, Jessica; Swarbrick, James D.; Graham, Bim; et al (April 2018, Inorganic Chemistry)
2. Ag(III)···Ag(III) Argentophilic Interaction in a Cofacial Corrole Dyad

   https://doi.org/10.1021/acs.inorgchem.2c02285  

   Lemon, Christopher M.; Powers, David C.; Huynh, Michael; Maher, Andrew G.; Phillips, Austin A.; Tripet, Brian P.; Nocera, Daniel G. (January 2023, Inorganic Chemistry)
3. Synthesis and structural characterization of the heavy tricysteinylpnictines, models of protein-bound As(III), Sb(III), and Bi(III)

   https://doi.org/10.1039/D4DT02476A  

   Hollow, Sophia E; Johnstone, Timothy C (December 2024, Dalton Transactions)

   We synthesize and characterize As(Cys)₃, Sb(Cys)₃, and Bi(Cys)₃, describe their crystal structures, analyze structural trends across Pn(SR)₃compounds, and compare their features to the structures of proteins with these centers bound to Cys₃motifs. 

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4. Tempered Homogeneous Spaces III

   Benoist, Y.; Kobayashi, T. (January 2021, Journal of Lie Theory)

   Abstract. Let 𝘎 be a real semisimple algebraic Lie group and 𝘏 a real reductive algebraic subgroup. We describe the pairs (𝘎,𝘏) for which the representation of 𝘎 in L²(𝘎/𝘏) is tempered. The proof gives the complete list of pairs (𝘎,𝘏) for which L²(𝘎/𝘏) is not tempered. When 𝘎 and 𝘏 are complex Lie groups, the temperedness condition is characterized by the fact that 𝘵𝘩𝘦 𝘴𝘵𝘢𝘣𝘪𝘭𝘪𝘻𝘦𝘳 𝘪𝘯 𝘏 𝘰𝘧 𝘢 𝘨𝘦𝘯𝘦𝘳𝘪𝘤 𝘱𝘰𝘪𝘯𝘵 𝘰𝘯 𝘎/𝘏 𝘪𝘴 𝘷𝘪𝘳𝘵𝘶𝘢𝘭𝘭𝘺 𝘢𝘣𝘦𝘭𝘪𝘢𝘯. 𝘔𝘢𝘵𝘩𝘦𝘮𝘢𝘵𝘪𝘤𝘴 𝘚𝘶𝘣𝘫𝘦𝘤𝘵 𝘊𝘭𝘢𝘴𝘴𝘪𝘧𝘪𝘤𝘢𝘵𝘪𝘰𝘯: Primary 22𝐄46; secondary 43𝐀85, 22𝐅30. 𝘒𝘦𝘺 𝘞𝘰𝘳𝘥𝘴: Lie groups, homogeneous spaces, tempered representations, unitary representations, matrix coefficients, symmetric spaces. 

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5. 2.2.2-Cryptand complexes of neptunium( iii ) and plutonium( iii )

   https://doi.org/10.1039/D1CC05904A  

   Goodwin, Conrad A.; Ciccone, Sierra R.; Bekoe, Samuel; Majumdar, Sourav; Scott, Brian L.; Ziller, Joseph W.; Gaunt, Andrew J.; Furche, Filipp; Evans, William J. (January 2022, Chemical Communications)

   New coordination environments are reported for Np( iii ) and Pu( iii ) based on pilot studies of U( iii ) in 2.2.2-cryptand (crypt). The U( iii )-in-crypt complex, [U(crypt)I 2 ][I], obtained from the reaction between UI 3 and crypt, is treated with Me 3 SiOTf (OTf = O 3 SCF 3 ) in benzene to form the [U(crypt)(OTf) 2 ][OTf] complex. Similarly, the isomorphous Np( iii ) and Pu( iii ) complexes were obtained similarly starting from [AnI 3 (THF) 4 ]. All three complexes (1-An; An = U, Np, Pu) contain an encapsulated actinide in a THF-soluble complex. Absorption spectroscopy and DFT calculations are consistent with 5f 3 U( iii ), 5f 4 Np( iii ), and 5f 5 Pu( iii ) electron configurations. 

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