The sorption properties of [Zr 6 O 4 (OH) 4 (NH 3 + -BDC) 6 ]Cl 6 · x H 2 O ( MOR-1 ) and H 16 [Zr 6 O 16 (H 2 PATP) 4 ]Cl 8 · x H 2 O ( MOR-2 ) towards ReO 4 − and TcO 4 − were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO 4 − and TcO 4 − anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g −1 ) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO 4 − sensing properties, demonstrated for the first time for MOF materials.
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A novel reversible fluorescent probe for the highly sensitive detection of nitro and peroxide organic explosives using electrospun BaWO 4 nanofibers
Fabrication of highly stable, reversible, and efficient portable sensors for the detection of explosives for safety and security is challenging due to the robustness of the currently available detection tools, limiting their mass deployment to the explosion prone areas. This paper reports a new direction towards the sensing of nitro- and peroxide-based explosives using highly stable rare-earth-doped BaWO 4 nanofibers with remarkable sensitivity and reversibility. BaWO 4 nanofibers doped with Tb 3+ and Eu 3+ ions are fabricated through a sol–gel electrospinning process, and their emission characteristics and application as a fluorescent probe for the sensing of 2-nitrotoluene and H 2 O 2 , explosive taggants representing a broad class of explosives, are studied in detail. Scheelite structured BaWO 4 nanofibers exhibit excellent luminescence characteristics, and the rare-earth ion doping in the polycrystalline BaWO 4 nanofibers is tailored to achieve blue, green, red, and white light emissions. These nanofibers are extremely sensitive to 2-nitrotoluene and H 2 O 2 with rapid response time, and sensitivity is observed within the range of 1–400 ppb and 1–10 ppm, towards 2-nitrotoluene and H 2 O 2 , respectively. The fluorescence quenching of BaWO 4 nanofibers in the presence of 2-nitrotoluene and H 2 O 2 is exponential with the quenching constants up to 1.73 × 10 6 and 2.73 × 10 4 L mol −1 , respectively, which are significantly higher than those of most of the fluorescent probes based on metal–organic frameworks and conjugated organic materials. After exposing to 2-nitrotoluene, the luminescence of the nanofibers is retained completely upon heating at 120 °C for 10 min and the sensory response is retained as fresh nanofibers, and currently available fluorescent explosive sensors could not achieve such a recovery. The high sensitivity and selectivity of scalable rare-earth-doped BaWO 4 nanofibers provide a new platform for the simultaneous detection of two classes of explosives.
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- Award ID(s):
- 1626376
- NSF-PAR ID:
- 10172646
- Date Published:
- Journal Name:
- Journal of Materials Chemistry C
- Volume:
- 7
- Issue:
- 47
- ISSN:
- 2050-7526
- Page Range / eLocation ID:
- 14949 to 14961
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/c9tc05068j
