More Like this

1. Zn ₂ MnSbO ₆ and Zn ₂ FeSbO ₆ : Two New Polar High-Pressure Ordered Corundum-Type Compounds

   https://doi.org/10.1021/acs.chemmater.4c02146  

   Provino, Alessia; Emge, Thomas J; Walker, David; Frank, Corey E; Yoshida, Suguru; Gopalan, Venkatraman; Croft, Mark; Deng, Zheng; Jin, Changqing; Manfrinetti, Pietro; et al (December 2024, Chemistry of Materials)

   Two new compounds, Zn2FeSbO6 and Zn2MnSbO6, have been synthesized under high-pressure and high-temperature conditions. The synthesis, single-crystal and powder X-ray diffraction, X-ray absorption near-edge spectroscopy (XANES), optical second harmonic generation (SHG), and magnetic and heat capacity measurements were carried out for both compounds and are described. The lattice parameters are a = 5.17754(6) Å and c = 13.80045(16) Å for Zn2FeSbO6 and a = 5.1889(10) Å and c = 14.0418(3) Å for Zn2MnSbO6. Single-crystal X-ray diffraction analyses indicate that Zn2FeSbO6 consists of a cocrystal of superimposed Ni3TeO6 (NTO) and ordered ilmenite (OIL) components with a ratio of approximately 2:1 and Zn2MnSbO6 contains two nearly identical, but noncrystallographically related, OIL components in a ratio of approximately 6:1. 

   more » « less
2. Eu ₁₁ Zn ₄ Sn ₂ As ₁₂ : A Ferromagnetic Zintl Semiconductor with a Layered Structure Featuring Extended Zn ₄ As ₆ Sheets and Ethane-like Sn ₂ As ₆ Units

   https://doi.org/10.1021/acs.chemmater.8b02749  

   Devlin, Kasey P.; Kazem, Nasrin; Zaikina, Julia V.; Cooley, Joya A.; Badger, Jackson R.; Fettinger, James C.; Taufour, Valentin; Kauzlarich, Susan M. (September 2018, Chemistry of Materials)
3. σ‐Aromaticity‐Induced Stabilization of Heterometallic Supertetrahedral Clusters [Zn ₆ Ge ₁₆ ] ⁴⁻ and [Cd ₆ Ge ₁₆ ] ⁴⁻

   https://doi.org/10.1002/anie.202008276  

   Xu, Hong‐Lei; Popov, Ivan A.; Tkachenko, Nikolay V.; Wang, Zi‐Chuan; Muñoz‐Castro, Alvaro; Boldyrev, Alexander I.; Sun, Zhong‐Ming (September 2020, Angewandte Chemie International Edition)

   null (Ed.)
4. Advancing Heteroanionicity in Zintl Phases: Crystal Structures, Thermoelectric and Magnetic Properties of Two Quaternary Semiconducting Arsenide Oxides, Eu ₈ Zn ₂ As ₆ O and Eu ₁₄ Zn ₅ As ₁₂ O

   https://doi.org/10.1021/acs.inorgchem.4c01580  

   Ishtiyak, Mohd; Watts, Spencer_R; Thipe, Bhushan; Womack, Frank; Adams, Philip; Bai, Xiaojian; Young, David_P; Bobev, Svilen; Baranets, Sviatoslav (June 2024, Inorganic Chemistry)
5. Generating Ferromagnetic Kagomé Metal by Magnetic Phase Boundary Mapping in the YFe ₆ Ge ₆ –YCo ₆ Ge ₆ System

   https://doi.org/10.1021/acs.chemmater.4c02382  

   Li, Victoria M; Adams, Milo; Shatruk, Michael (January 2025, Chemistry of Materials)