skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: A Tale of Two LIP- (Large-Igneous Province) Induced Hyperthermals: The end-Triassic extinction (ETE) and Toarcian OAE (T-OAE)
Although many sources of atmospheric CO2 have been identified, the major sinks are best understood in a deep-time context. Here, we focus on two Large Igneous Provinces (LIPs), the Central Atlantic Magmatic Province (CAMP) situated in the low latitude humid zone ~201.6 Ma and the Karoo-Ferrar located at high southern latitudes ~183 Ma. We use soil carbonate, lithologic, δD of n-alkanes, Sr data, and modeling to examine how these eruptions, hydrological cycling, and weathering impacted global atmospheric CO2, carbon cycling, and biotic extinction at the ETE and T-OAE hyperthermals. CAMP largely erupted in the tropics, doubled atmospheric CO2 from ~2,500 – 5,000 ppm at the ETE (observed in soil carbonates with an onset <1000 and a duration of <~20 ky) and rapidly sequestered CO2 (< 2,500 ppm) as recorded in Newark Supergroup basins (eastern US). These same strata preserve variations in the lake level expression of the climatic precession cycle based on lithology and δD. High cyclicity variance tracked high pCO2 (>~4000 ppm) and drove insolation-paced increases in precipitation. Leaf wax δD shows significant variability, reflecting an enhanced hydrological cycle at the ETE with repeated sudden shifts in relative evaporation for ~1 Myr. In marine strata, 87Sr/86Sr and 187Os/188Os values track changes in pCO2, suggesting a terrestrial/marine linkage through continental weathering, CO2, and runoff. Despite the northward movement of these basins into the arid belt, our data suggest lower evaporation relative to precipitation driven by lower temperatures, consistent with lower pCO2 due to CAMP weathering, which modeling estimates to have increased 6 to 10-fold for >1.6 Myr after the eruptive phase. Release of CO2 from the Karoo-Ferrar LIP similarly enhanced the hydrological cycle as evidenced from sedimentary observations (e.g., fine-scale turbidites and debris flow deposits) in Yorkshire (UK). The onset of the carbon isotope excursion at the T-OAE lasts 0.5 Myr with a 1.5 Myr duration modulated by astronomical pacing. Our leaf wax δD from the same strata show a transient enhancement in the hydrological cycle. Although the Karoo-Ferrar has a limited drawdown potential when compared with CAMP‐type basalts because of its higher latitude location, Toarcian weathering rates may have increased 2 to 5-fold, acting as a net sink 1–2 Myr after eruptions ceased.  more » « less
Award ID(s):
1654088
PAR ID:
10174840
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
American Geophysical Union Annual Conference
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Different sources and processes contribute to pCO2 and CO2 exchange with the atmosphere in the rivers and floodplains of the Amazon basin. We measured or estimated pCO2, CO2 fluxes with the atmosphere, planktonic community respiration (PCR), and environmental and landscape variables along the Negro and Amazon-Solimões rivers during different periods of the fluvial hydrological cycle. Values of pCO2 ranged from 307 to 7,527 μatm, while CO2 fluxes ranged from -9.3 to 1,128 mmol m-2 d-1 in the Amazon-Solimões basin. In the Negro basin, pCO2 values ranged from 648 to 6,526 μatm, and CO2 fluxes from 35 to 1,025 mmol m-2 d-1. In a general linear model including data from Negro and Amazon-Solimões basins, seasonal and spatial variation in flooded vegetated habitat area, dissolved oxygen, depth and water temperature explained 85% of surface pCO2 variation. Levels of pCO2 varied with inundation extent, with higher pCO2 values occurring in periods with greater water depth and inundation area, and lower dissolved oxygen concentrations and water temperatures. In a separate analysis for the Amazon-Solimões river and floodplains, ecosystem type (lotic or lentic), hydrological period, water temperature, dissolved oxygen, depth and dissolved phosphorus explained 83% of pCO2 variation. Our results demonstrate the influence of alluvial floodplains and seasonal variations in their limnological characteristics on the pCO2 levels in river channels of the lowland Amazon. 
    more » « less
  2. We analyzed the deuterium composition of individual plant-waxes in lake sediments from 28 watersheds that span a range of precipitation D/H, vegetation types and climates. The apparent isotopic fractionation (εa) between plant-wax n-alkanes and precipitation differs with watershed ecosystem type and structure, and decreases with increasing regional aridity as measured by enrichment of 2H and 18O associated with evaporation of lake waters. The most negative εa values represent signatures least affected by aridity; these values were −125 ± 5‰ for tropical evergreen and dry forests, −130‰ for a temperate broadleaf forest, −120 ± 9‰ for the high-altitude tropical páramo (herbs, shrubs and grasses), and −98 ± 6‰ for North American montane gymnosperm forests. Minimum εa values reflect ecosystem-dependent differences in leaf water enrichment and soil evaporation. Slopes of lipid/lake water isotopic enrichments differ slightly with ecosystem structure (i.e. open shrublands versus forests) and overall are quite small (slopes = 0–2), indicating low sensitivity of lipid δD variations to aridity compared with coexisting lake waters. This finding provides an approach for reconstructing ancient precipitation signatures based on plant-wax δD measurements and independent proxies for lake water changes with regional aridity. To illustrate this approach, we employ paired plant-wax δD and carbonate-δ18O measurements on lake sediments to estimate the isotopic composition of Miocene precipitation on the Tibetan plateau. 
    more » « less
  3. Studies reveal that the sea-surface temperature (SST) of the Northern Hemisphere decreased at a smaller amplitude than that of the Southern Hemisphere during the Eocene−Oligocene transition (EOT). This interhemispheric temperature asymmetry has been associated with intensified Atlantic Meridional Overturning Circulation (AMOC) that may have driven enhanced precipitation and weathering in low latitudes and the subsequent drawdown of atmospheric carbon dioxide. However, no quantitative constraints on paleo-precipitation have been reported in low latitudes to characterize the AMOC effect across the EOT. Here, we present the results of high-resolution (ca. 6 k.y. per sample) isotopic and biomarker records from the Gulf of Mexico. Reconstructed precipitation using leaf wax carbon isotopes shows an increase of 44% across the EOT (34.1−33.6 Ma), which is accompanied by a secular increase in SST of ∼2 °C during the latest Eocene. We attribute the enhanced precipitation in the Gulf of Mexico to the northward shift of the Intertropical Convergence Zone that was driven by an enlarged polar-tropic temperature gradient in the Southern Hemisphere and an invigorated AMOC. Our findings link changes in meridional temperature gradient and large-scale oceanic circulation to the low-latitude terrestrial hydroclimate and provide paleohydrological evidence that supports CO2-weathering feedback during the EOT “greenhouse” to “icehouse” transition. 
    more » « less
  4. The Common Era history of effective moisture in the Central Andes is poorly understood, as most Andean proxy records reflect large-scale atmospheric circulation over the South American lowlands rather than localized precipitation vs. evaporation. Here we present 1800-year leaf wax hydrogen and carbon isotope sedimentary records from Lake Chacacocha (13.96°S, 71.08°W, 4,860 m asl.) in the Central Andes. Leaf wax δ2H from different chain lengths offers information about large-scale atmospheric conditions and local-scale effective moisture. Our leaf wax δ2H data record a gradual intensification of the South American summer monsoon (SASM) beginning around ~1250 CE, prior to the external forcings of the Little Ice Age (LIA). Despite peak SASM intensification, our leaf wax δ13C data reveal a locally arid interval between ca. 1600 and 1800 CE. The arid interval was most likely driven by enhanced evaporation and reduced local precipitation, as indicated by the hydrogen isotope fractionation between mid- and long-chain n-alkanes as well as by climate model simulations. Our results help to reconcile conflicting interpretations of the SASM, glacial, and lake-level histories in the Central Andes during the Common Era. 
    more » « less
  5. Abstract. The warmer early Pliocene climate featured changes to global sea surface temperature (SST) patterns, namely a reduction in the Equator–pole gradient and the east–west SST gradient in the tropical Pacific, the so-called “permanent El Niño”. Here we investigate the consequences of the SST changes to silicate weathering and thus to atmospheric CO2 on geological timescales. Different SST patterns than today imply regional modifications of the hydrological cycle that directly affect continental silicate weathering in particular over tropical “hotspots” of weathering, such as the Maritime Continent, thus leading to a “weatherability pattern effect”. We explore the impact of Pliocene-like SST changes on weathering using climate model and silicate weathering model simulations, and we deduce CO2 and temperature at carbon cycle equilibrium between solid Earth degassing and silicate weathering. In general, we find large regional increases and decreases in weathering fluxes, and the net effect depends on the extent to which they cancel. Permanent El Niño conditions lead to a small amplification of warming relative to the present day by 0.4 ∘C, suggesting that the demise of the permanent El Niño could have had a small amplifying effect on cooling from the early Pliocene into the Pleistocene. For the reducedEquator–pole gradient, the weathering increases and decreases largely cancel, leading to no detectable difference in global temperature at carbon cycle equilibrium. A robust SST reconstruction of the Pliocene is needed for a quantitative evaluation of the weatherability pattern effect. 
    more » « less