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Abstract Sulfur‐water chemistry plays an important role in the middle atmosphere of Venus. Ground‐based observations have found that simultaneously observed SO2and H2O at ~64 km vary with time and are temporally anticorrelated. To understand these observations, we explore the sulfur‐water chemical system using a one‐dimensional chemistry‐diffusion model. We find that SO2and H2O mixing ratios above the clouds are highly dependent on mixing ratios of the two species at the middle cloud top (58 km). The behavior of sulfur‐water chemical system can be classified into three regimes, but there is no abrupt transition among these regimes. In particular, there is no bifurcation behavior as previously claimed. We also find that the SO2self‐shielding effect causes H2O above the clouds to respond to the middle cloud top in a nonmonotonic fashion. Through comparison with observations, we find that mixing ratio variations at the middle cloud top can explain the observed variability of SO2and H2O. The sulfur‐water chemistry in the middle atmosphere is responsible for the H2O‐SO2anticorrelation at 64 km. Eddy transport change alone cannot explain the variations of both species. These results imply that variations of species abundance in the middle atmosphere are significantly influenced by the lower atmospheric processes. Continued ground‐based measurements of the coevolution of SO2and H2O above the clouds and new spacecraft missions will be crucial for uncovering the complicated processes underlying the interaction among the lower atmosphere, the clouds, and the middle atmosphere of Venus.
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HDO and SO 2 thermal mapping on Venus: V. Evidence for a long-term anti-correlation
Since January 2012, we have been monitoring the behavior of sulfur dioxide and water on Venus, using the Texas Echelon Cross-Echelle Spectrograph imaging spectrometer at the NASA InfraRed Telescope Facility (IRTF, Mauna Kea Observatory). Here, we present new data recorded in February and April 2019 in the 1345 cm −1 (7.4 μ m) spectral range, where SO 2 , CO 2 , and HDO (used as a proxy for H 2 O) transitions were observed. The cloud top of Venus was probed at an altitude of about 64 km. As in our previous studies, the volume mixing ratio (vmr) of SO 2 was estimated using the SO 2 /CO 2 line depth ratio of weak transitions; the H 2 O volume mixing ratio was derived from the HDO/CO 2 line depth ratio, assuming a D/H ratio of 200 times the Vienna standard mean ocean water. As reported in our previous analyses, the SO 2 mixing ratio shows strong variations with time and also over the disk, showing evidence for the formation of SO 2 plumes with a lifetime of a few hours; in contrast, the H 2 O abundance is remarkably uniform over the disk and shows moderate variations as a function of time. We have used the 2019 data in addition to our previous dataset to study the long-term variations of SO 2 and H 2 O. The data reveal a long-term anti-correlation with a correlation coefficient of −0.80; this coefficient becomes −0.90 if the analysis is restricted to the 2014–2019 time period. The statistical analysis of the SO 2 plumes as a function of local time confirms our previous result with a minimum around 10:00 and two maxima near the terminators. The dependence of the SO 2 vmr with respect to local time shows a higher abundance at the evening terminator with respect to the morning. The dependence of the SO 2 vmr with respect to longitude exhibits a broad maximum at 120–200° east longitudes, near the region of Aphrodite Terra. However, this trend has not been observed by other measurements and has yet to be confirmed.
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- Award ID(s):
- 1740921
- PAR ID:
- 10183531
- Date Published:
- Journal Name:
- Astronomy & Astrophysics
- Volume:
- 639
- ISSN:
- 0004-6361
- Page Range / eLocation ID:
- A69
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1051/0004-6361/202037741
