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1. Amplitude analysis of the D+ → π−π+π+ decay and measurement of the π−π+ S-wave amplitude

   https://doi.org/10.1007/JHEP06(2023)044  

   Aaij, R.; Abdelmotteleb, A. S.; Abellan Beteta, C.; Abudinén, F.; Ackernley, T.; Adeva, B.; Adinolfi, M.; Afsharnia, H.; Agapopoulou, C.; Aidala, C. A.; et al (June 2023, Journal of High Energy Physics)

   A bstract An amplitude analysis of the D + → π − π + π + decay is performed with a sample corresponding to 1.5 fb − 1 of integrated luminosity of pp collisions at a centre-of-mass energy $$ \sqrt{s} $$ s = 8 TeV collected by the LHCb detector in 2012. The sample contains approximately six hundred thousand candidates with a signal purity of 95%. The resonant structure is studied through a fit to the Dalitz plot where the π − π + S-wave amplitude is extracted as a function of π − π + mass, and spin-1 and spin-2 resonances are included coherently through an isobar model. The S-wave component is found to be dominant, followed by the ρ (770) 0 π + and f 2 (1270) π + components. A small contribution from the ω (782) → π − π + decay is seen for the first time in the D + → π − π + π + decay. 

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2. Secondary-Sphere Chlorolanthanide(III) Complexes with a 1,3,5-Triazine-Based Ligand Supported by Anion−π, π–π, and Hydrogen-Bonding Interactions

   https://doi.org/10.1021/acs.inorgchem.9b01804  

   de Bettencourt-Dias, Ana; Beeler, Rose M.; Zimmerman, Joshua R. (September 2019, Inorganic Chemistry)
3. Phthalocyanines as a π–π Adsorption Strategy to Immobilize Catalyst on Carbon for Electrochemical Synthesis

   https://doi.org/10.1055/s-0037-1611792  

   Klunder, Kevin J.; Cass, Ashley C.; Anderson, Scott L.; Minteer, Shelley D. (May 2019, Synlett)

   In most electrochemical syntheses, reactions are happening at or near the electrode surface. For catalyzed reactions, ideally, the electrode surface would solely contain the catalyst, which then simplifies purification and lowers the amount of catalyst needed. Here, a new strategy involving phthalocyanines (Pc) to immobilize catalysts onto carbon electrode surfaces is presented. The large π structure of the Pc enables adsorption to the sp2-structure of graphitic carbon. TEMPO-modified Pc were chosen as a proof of concept to test the new immobilization strategy. It was found that the TEMPO-Pc derivatives functioned similarly or better than the widely used pyrene adsorption method. Interestingly, the new TEMPO-Pc catalyst appears to facilitate a cascade reaction involving both the anode and the cathode. The first step is the generation of an aryl aldehyde (anode) followed by the reduction of the aryl aldehyde in a pinacol-type coupling reaction at the cathode. The last step is the oxidation of a hydrobenzoin to create benzil. This work demonstrates the unique ability of electrochemistry and bifunctional catalysts to enable multistep chemical transformations, performing both reductive and oxidative transformations in one pot. 

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4. Search for the dark photon in B0 → A′A′, A′ → e+e−, μ+μ−, and π+π− decays at Belle

   https://doi.org/10.1007/JHEP04(2021)191  

   Park, S.-H.; Kwon, Y.-J.; Adachi, I.; Aihara, H.; Al Said, S.; Asner, D. M.; Atmacan, H.; Aushev, T.; Ayad, R.; Babu, V.; et al (April 2021, Journal of High Energy Physics)

   null (Ed.)

   A bstract We present a search for the dark photon A ′ in the B 0 → A ′ A ′ decays, where A ′ subsequently decays to e + e − , μ + μ − , and π + π − . The search is performed by analyzing 772 × 10 6 $$ B\overline{B} $$ B B ¯ events collected by the Belle detector at the KEKB e + e − energy-asymmetric collider at the ϒ(4 S ) resonance. No signal is found in the dark photon mass range 0 . 01 GeV /c 2 ≤ m A ′ ≤ 2 . 62 GeV /c 2 , and we set upper limits of the branching fraction of B 0 → A ′ A ′ at the 90% confidence level. The products of branching fractions, $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right)\times \mathrm{\mathcal{B}}{\left(A\prime \to {e}^{+}{e}^{-}\right)}^2 $$ ℬ B 0 → A ′ A ′ × ℬ A ′ → e + e − 2 and $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right)\times \mathrm{\mathcal{B}}{\left(A\prime \to {\mu}^{+}{\mu}^{-}\right)}^2 $$ ℬ B 0 → A ′ A ′ × ℬ A ′ → μ + μ − 2 , have limits of the order of 10 − 8 depending on the A ′ mass. Furthermore, considering A ′ decay rate to each pair of charged particles, the upper limits of $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right) $$ ℬ B 0 → A ′ A ′ are of the order of 10 − 8 –10 − 5 . From the upper limits of $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right) $$ ℬ B 0 → A ′ A ′ , we obtain the Higgs portal coupling for each assumed dark photon and dark Higgs mass. The Higgs portal couplings are of the order of 10 − 2 –10 − 1 at $$ {m}_{h\prime}\simeq {m}_{B^0} $$ m h ′ ≃ m B 0 ± 40 MeV /c 2 and 10 − 1 –1 at $$ {m}_{h\prime}\simeq {m}_{B^0} $$ m h ′ ≃ m B 0 ± 3 GeV /c 2 . 

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5. Electrical conductivity through π–π stacking in a two‐dimensional porous gallium catecholate metal–organic framework

   https://doi.org/10.1111/nyas.14906  

   Skorupskii, Grigorii; Chanteux, Géraldine; Le, Khoa N.; Stassen, Ivo; Hendon, Christopher H.; Dincă, Mircea (October 2022, Annals of the New York Academy of Sciences)

   Abstract Metal–organic frameworks (MOFs) are hybrid materials known for their nanoscale pores, which give them high surface areas but generally lead to poor electrical conductivity. Recently, MOFs with high electrical conductivity were established as promising materials for a variety of applications in energy storage and catalysis. Many recent reports investigating the fundamentals of charge transport in these materials focus on the role of the organic ligands. Less consideration, however, is given to the metal ion forming the MOF, which is almost exclusively a late first‐row transition metal. Here, we report a moderately conductive porous MOF based on trivalent gallium and 2,3,6,7,10,11‐hexahydroxytriphenylene. Gallium, a metal that has not been featured in electrically conductive MOFs so far, has a closed‐shell electronic configuration and is present in its trivalent state—in contrast to most conductive MOFs, which are formed by open‐shell, divalent transition metals. Our material, made without using any harmful solvents, displays conductivities on the level of 3 mS/cm and a surface area of 196 m²/g, comparable to transition metal analogs. 

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