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1. Topology Optimization of Multimaterial Thermoelectric Structures

   https://doi.org/10.1115/1.4047435  

   Xu, Xiaoqiang; Wu, Yongjia; Zuo, Lei; Chen, Shikui (January 2021, Journal of Mechanical Design)

   Abstract A large amount of energy from power plants, vehicles, oil refining, and steel or glass making process is released to the atmosphere as waste heat. The thermoelectric generator (TEG) provides a way to reutilize this portion of energy by converting temperature differences into electricity using Seebeck phenomenon. Because the figures of merit zT of the thermoelectric materials are temperature-dependent, it is not feasible to achieve high efficiency of the thermoelectric conversion using only one single thermoelectric material in a wide temperature range. To address this challenge, the authors propose a method based on topology optimization to optimize the layouts of functional graded TEGs consisting of multiple materials. The multimaterial TEG is optimized using the solid isotropic material with penalization (SIMP) method. Instead of dummy materials, both the P-type and N-type electric conductors are optimally distributed with two different practical thermoelectric materials. Specifically, Bi2Te3 and Zn4Sb3 are selected for the P-type element while Bi2Te3 and CoSb3 are employed for the N-type element. Two optimization scenarios with relatively regular domains are first considered with one optimizing on both the P-type and N-type elements simultaneously, and the other one only on single P-type element. The maximum conversion efficiency could reach 9.61% and 12.34% respectively in the temperature range from 25 °C to 400 °C. CAD models are reconstructed based on the optimization results for numerical verification. A good agreement between the performance of the CAD model and optimization result is achieved, which demonstrates the effectiveness of the proposed method. 

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2. Multiprinter Additive Manufacturing of Flexible and Lightweight Thermoelectric Energy Harvesters Using Colloidal Nanoparticles

   Varghese, Tony; Weltner, Ariel; Manzi, Jacob; Hill, Curtis; Subbaraman, Harish; Estrada, David (August 2021, The 10th annual International Space Station Research and Development Conference (ISSRDC))

   Thermoelectric generators are being used as a successful power sources for space applications since 1960's in radioisotope-thermoelectric generators (RTGs) to supply power to space systems in deep space. RTG’s are capable of directly converting heat energy to uninterrupted electric power with no moving parts involved. The ability of thermoelectric materials to convert heat energy to electrical energy is defined by a dimensionless value known as the thermoelectric figure of merit (ZT) 1. This value quantifies the maximum thermoelectric efficiency of a thermoelectric generator (TEG) and is calculated by ZT= S2σT/κ, where S, σ, T, and κ represent Seebeck coefficient, electrical conductivity, temperature, and thermal conductivity, respectively. Among all of the thermoelectric materials, Bi2Te3 and its alloys have been reported to have high ZT values for low temperature energy harvesting and are highly suitable for powering wearables and self-powering sensors2, 3. 

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3. Performance Optimization and Exergy Analysis of Thermoelectric Heat Recovery System for Gas Turbine Power Plants

   https://doi.org/10.3390/e25121583  

   Alsaghir, Ahmad M.; Bahk, Je-Hyeong (December 2023, Entropy)

   Thermoelectric (TE) waste heat recovery has attracted significant attention over the past decades, owing to its direct heat-to-electricity conversion capability and reliable operation. However, methods for application-specific, system-level TE design have not been thoroughly investigated. This work provides detailed design optimization strategies and exergy analysis for TE waste heat recovery systems. To this end, we propose the use of TE system equipped on the exhaust of a gas turbine power plant for exhaust waste heat recovery and use it as a case study. A numerical tool has been developed to solve the coupled charge and heat current equations with temperature-dependent material properties and convective heat transfer at the interfaces with the exhaust gases at the hot side and with the ambient air at the heat sink side. Our calculations show that at the optimum design with 50% fill factor and 6 mm leg thickness made of state-of-the-art Bi2Te3 alloys, the proposed system can reach power output of 10.5 kW for the TE system attached on a 2 m-long, 0.5 × 0.5 m2-area exhaust duct with system efficiency of 5% and material cost per power of 0.23 $/W. Our extensive exergy analysis reveals that only 1% of the exergy content of the exhaust gas is exploited in this heat recovery process and the exergy efficiency of the TE system can reach 8% with improvement potential of 85%. 

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4. Stencil-Printed Scalable Radial Thermoelectric Device Using Sustainable Manufacturing Methods

   https://doi.org/10.3390/su16093560  

   Jang, Eunhwa; Ambade, Rohan B; Banerjee, Priyanshu; Topoleski, LD Timmie; Madan, Deepa (May 2024, Sustainability)

   In this study, we used n-chitosan-Bi2Te2.7Se0.3 and p-chitosan-Bi0.5Sb1.5Te3 composite inks to print a circular thermoelectric generator (TEG) device using a low-energy-input curing method. Thermoelectric (TE) composite films were fabricated using varying sizes of thermoelectric particles and a small chitosan binder (0.05 wt. %). The particles and binder were hot pressed at an applied pressure of 200 MPa and cured at 200 °C for 30 min. We achieved ZT of 0.35 for the n-type and 0.7 for the p-type TE composite films measured at room temperature. A radial TEG was fabricated using the best-performing n-type and p-type composite inks and achieved a power output of 87 µW and a power density of 727 µW/cm2 at a temperature difference of 35 K; these are among the best-reported values for printed TEG devices. Using a low-energy-input fabrication method, we eliminated the need for high-temperature and long-duration curing processes to fabricate printing devices. Thus, we envisage that the low-energy-input curing process and cost-effective printable strategy presented in this work pave the way for sustainable manufacturing of large-scale energy harvesting TEG devices. 

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5. New Directions for Thermoelectrics: A Roadmap from High‐Throughput Materials Discovery to Advanced Device Manufacturing

   https://doi.org/10.1002/smsc.202300359  

   Song, Kaidong; Tanvir, Ali_Newaz_Mohammad; Bappy, Md_Omarsany; Zhang, Yanliang (April 2024, Small Science)

   Thermoelectric materials, which can convert waste heat into electricity or act as solid‐state Peltier coolers, are emerging as key technologies to address global energy shortages and environmental sustainability. However, discovering materials with high thermoelectric conversion efficiency is a complex and slow process. The emerging field of high‐throughput material discovery demonstrates its potential to accelerate the development of new thermoelectric materials combining high efficiency and low cost. The synergistic integration of high‐throughput material processing and characterization techniques with machine learning algorithms can form an efficient closed‐loop process to generate and analyze broad datasets to discover new thermoelectric materials with unprecedented performances. Meanwhile, the recent development of advanced manufacturing methods provides exciting opportunities to realize scalable, low‐cost, and energy‐efficient fabrication of thermoelectric devices. This review provides an overview of recent advances in discovering thermoelectric materials using high‐throughput methods, including processing, characterization, and screening. Advanced manufacturing methods of thermoelectric devices are also introduced to realize the broad impacts of thermoelectric materials in power generation and solid‐state cooling. In the end, this article also discusses the future research prospects and directions. 

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