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The past decade has witnessed the emergence of a new frontier in condensed matter physics: topological materials with an electronic band structure belonging to a different topological class from that of ordinary insulators and metals. This non-trivial band topology gives rise to robust, spin-polarized electronic states with linear energy–momentum dispersion at the edge or surface of the materials. For topological materials to be useful in electronic devices, precise control and accurate detection of the topological states must be achieved in nanostructures, which can enhance the topological states because of their large surface-to-volume ratios. In this Review, we discuss notable synthesis and electron transport results of topological nanomaterials, from topological insulator nanoribbons and plates to topological crystalline insulator nanowires and Weyl and Dirac semimetal nanobelts. We also survey superconductivity in topological nanowires, a nanostructure platform that might enable the controlled creation of Majorana bound states for robust quantum computations. Two material systems that can host Majorana bound states are compared: spin–orbit coupled semiconducting nanowires and topological insulating nanowires, a focus of this Review. Finally, we consider the materials and measurement challenges that must be overcome before topological nanomaterials can be used in next-generation electronic devices.
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Synthesis, growth mechanisms, and applications of palladium-based nanowires and other one-dimensional nanostructures
Palladium-based nanostructures have attracted the attention of researchers due to their useful catalytic properties and unique ability to form hydrides, which finds application in hydrogen storage and hydrogen detection. Palladium-based nanowires have some inherent advantages over other Pd nanomaterials, combining high surface-to-volume ratio with good thermal and electron transport properties, and exposing high-index crystal facets that can have enhanced catalytic activity. Over the past two decades, both synthesis methods and applications of 1D palladium nanostructures have advanced greatly. In this review, we start by discussing different types of 1D palladium nanostructures before moving on to the different synthesis approaches that can produce them. Next, we discuss factors including kinetic vs. thermodynamic control of growth, oxidative etching, and surface passivation that affect palladium nanowire synthesis. We also review efforts to gain insight into growth mechanisms using different characterization tools. We discuss the effects of concentration of capping agents, reducing agents, metal halides, pH, and sacrificial oxidation on the growth of Pd-based nanowires in solution, from shape control, to yield, to aspect ratio. Various applications of palladium and palladium alloy nanowires are then discussed, including electrocatalysis, hydrogen storage, and sensing of hydrogen and other chemicals. We conclude with a summary and some perspectives on future research directions for this category of nanomaterials.
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- Award ID(s):
- 1804996
- PAR ID:
- 10191380
- Date Published:
- Journal Name:
- Nanoscale
- Volume:
- 11
- Issue:
- 41
- ISSN:
- 2040-3364
- Page Range / eLocation ID:
- 19058 to 19085
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/c9nr05835d
