Subduction zones impose an important control on the geochemical cycling between the surficial and internal reservoirs of the Earth. Sulphur and carbon are transferred into Earth’s mantle by subduction of pelagic sediments and altered oceanic lithosphere. Release of oxidizing sulphate- and carbonate-bearing fluids modifies the redox state of the mantle and the chemical budget of subduction zones. Yet, the mechanisms of sulphur and carbon cycling within subduction zones are still unclear, in part because data are typically derived from arc volcanoes where fluid compositions are modified during transport through the mantle wedge. We determined the bulk rock elemental, and sulphur and carbon isotope compositions of exhumed ultramafic and metabasic rocks from Syros, Greece. Comparison of isotopic data with major and trace element compositions indicates seawater alteration and chemical exchange with sediment-derived fluids within the subduction zone channel. We show that small bodies of detached slab material are subject to metasomatic processes during exhumation, in contrast to large sequences of obducted ophiolitic sections that retain their seafloor alteration signatures. In particular, fluids circulating along the plate interface can cause sulphur mobilization during several stages of exhumation within high-pressure rocks. This takes place more pervasively in serpentinites compared to mafic rocks.
The dehydration and decarbonation in the subducting slab are intricately related and the knowledge of the physical properties of the resulting C–H–O fluid is crucial to interpret the petrological, geochemical, and geophysical processes associated with subduction zones. In this study, we investigate the C–H–O fluid released during the progressive devolatilization of carbonate-bearing serpentine-polymorph chrysotile, with in situ electrical conductivity measurements at high pressures and temperatures. The C–H–O fluid produced by carbonated chrysotile exhibits high electrical conductivity compared to carbon-free aqueous fluids and can be an excellent indicator of the migration of carbon in subduction zones. The crystallization of diamond and graphite indicates that the oxidized C–H–O fluids are responsible for the recycling of carbon in the wedge mantle. The carbonate and chrysotile bearing assemblages stabilize dolomite during the devolatilization process. This unique dolomite forming mechanism in chrysotile in subduction slabs may facilitate the transport of carbon into the deep mantle.
more » « less- Award ID(s):
- 1753125
- NSF-PAR ID:
- 10224271
- Publisher / Repository:
- Nature Publishing Group
- Date Published:
- Journal Name:
- Scientific Reports
- Volume:
- 11
- Issue:
- 1
- ISSN:
- 2045-2322
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract This paper provides an overview of research on core from Oman Drilling Project Hole BT1B and the surrounding area, plus new data and calculations, constraining processes in the Tethyan subduction zone beneath the Samail ophiolite. The area is underlain by gently dipping, broadly folded layers of allochthonous Hawasina pelagic sediments, the metamorphic sole of the Samail ophiolite, and Banded Unit peridotites at the base of the Samail mantle section. Despite reactivation of some faults during uplift of the Jebel Akdar and Saih Hatat domes, the area preserves the tectonic “stratigraphy” of the Cretaceous subduction zone. Gently dipping listvenite bands, parallel to peridotite banding and to contacts between the peridotite and the metamorphic sole, replace peridotite at and near the basal thrust. Listvenites formed at less than 200°C and (poorly constrained) depths of 25–40 km by reaction with CO2‐rich, aqueous fluids migrating from greater depths, derived from devolatilization of subducting sediments analogous to clastic sediments in the Hawasina Formation, at 400°–500°. Such processes could form important reservoirs for subducted CO2. Listvenite formation was accompanied by ductile deformation of serpentinites and listvenites—perhaps facilitated by fluid‐rock reaction—in a process that could lead to aseismic subduction in some regions. Addition of H2O and CO2to the mantle wedge, forming serpentinites and listvenites, caused large increases in the solid mass and volume of the rocks. This may have been accommodated by fractures formed as a result of volume changes, mainly at a serpentinization front.
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null (Ed.)International Ocean Discovery Program (IODP) Expedition 357 successfully cored an east–west transect across the southern wall of Atlantis Massif on the western flank of the Mid-Atlantic Ridge to study the links between serpentinization processes and microbial activity in the shallow subsurface of highly altered ultramafic and mafic sequences that have been uplifted to the seafloor along a major detachment fault zone. The primary goals of this expedition were to (1) examine the role of serpentinization in driving hydrothermal systems, sustaining microbial communities, and sequestering carbon; (2) characterize the tectonomagmatic processes that lead to lithospheric heterogeneities and detachment faulting; and (3) assess how abiotic and biotic processes change with variations in rock type and progressive exposure on the seafloor. To accomplish these objectives, we developed a coring and sampling strategy based around the use of seabed rock drills—the first time that such systems have been used in the scientific ocean drilling programs. This technology was chosen in hopes of achieving high recovery of the carbonate cap sequences and intact contact and deformation relationships. The expedition plans also included several engineering developments to assess geochemical parameters during drilling; sample bottom water before and after drilling; supply synthetic tracers during drilling for contamination assessment; gather downhole electrical resistivity and magnetic susceptibility logs for assessing fractures, fluid flow, and extent of serpentinization; and seal boreholes to provide opportunities for future experiments. Seventeen holes were drilled at nine sites across Atlantis Massif, with two sites on the eastern end of the southern wall (Sites M0068 and M0075), three sites in the central section of the southern wall north of the Lost City hydrothermal field (Sites M0069, M0072, and M0076), two sites on the western end (Sites M0071 and M0073), and two sites north of the southern wall in the direction of the central dome of the massif and Integrated Ocean Drilling Program Site U1309 (Sites M0070 and M0074). Use of seabed rock drills enabled collection of more than 57 m of core, with borehole penetration ranging from 1.3 to 16.44 meters below seafloor and core recoveries as high as 75% of total penetration. This high level of recovery of shallow mantle sequences is unprecedented in the history of ocean drilling. The cores recovered along the southern wall of Atlantis Massif have highly heterogeneous lithologies, types of alteration, and degrees of deformation. The ultramafic rocks are dominated by harzburgites with intervals of dunite and minor pyroxenite veins, as well as gabbroic rocks occurring as melt impregnations and veins, all of which provide information about early magmatic processes and the magmatic evolution in the southernmost portion of Atlantis Massif. Dolerite dikes and basaltic rocks represent the latest stage of magmatic activity. Overall, the ultramafic rocks recovered during Expedition 357 revealed a high degree of serpentinization, as well as metasomatic talc-amphibole-chlorite overprinting and local rodingitization. Metasomatism postdates an early phase of serpentinization but predates late-stage intrusion and alteration of dolerite dikes and the extrusion of basalt. The intensity of alteration is generally lower in the gabbroic and doleritic rocks. Chilled margins in dolerite intruded into talc-amphibole-chlorite schists are observed at the most eastern Site M0075. Deformation in Expedition 357 cores is variable and dominated by brecciation and formation of localized shear zones; the degree of carbonate veining was lower than anticipated. All types of variably altered and deformed ultramafic and mafic rocks occur as components in sedimentary breccias and as fault scarp rubble. The sedimentary cap rocks include basaltic breccias with a carbonate sand matrix and/or fossiliferous carbonate. Fresh glass on basaltic components was observed in some of the breccias. The expedition also successfully applied new technologies, namely (1) extensively using an in situ sensor package and water sampling system on the seabed drills for evaluating real-time dissolved oxygen and methane, pH, oxidation-reduction potential, temperature, and conductivity during drilling; (2) deploying a borehole plug system for sealing seabed drill boreholes at four sites to allow access for future sampling; and (3) proving that tracers can be delivered into drilling fluids when using seabed drills. The rock drill sensor packages and water sampling enabled detection of elevated dissolved methane and hydrogen concentrations during and/or after drilling, with “hot spots” of hydrogen observed over Sites M0068–M0072 and methane over Sites M0070–M0072. Shipboard determination of contamination tracer delivery confirmed appropriate sample handling procedures for microbiological and geochemical analyses, which will aid all subsequent microbiological investigations that are part of the science party sampling plans, as well as verify this new tracer delivery technology for seabed drill rigs. Shipboard investigation of biomass density in select samples revealed relatively low and variable cell densities, and enrichment experiments set up shipboard reveal growth. Thus, we anticipate achieving many of the deep biosphere–related objectives of the expedition through continued scientific investigation in the coming years. Finally, although not an objective of the expedition, we were serendipitously able to generate a high-resolution (20 m per pixel) multibeam bathymetry map across the entire Atlantis Massif and the nearby fracture zone, Mid-Atlantic Ridge, and eastern conjugate, taking advantage of weather and operational downtime. 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Abstract A large part of the hydrated oceanic lithosphere consists of serpentinites exposed in ophiolites. Serpentinites constitute reactive chemical and thermal systems and potentially represent an effective sink for CO2. Understanding carbonation mechanisms within ophiolites are almost exclusively based on studies of outcrops, which can limit the interpretation of fossil hydrothermal systems. We present stable and radiogenic carbon isotope data that provide insights into the isotopic trends and fluid evolution of peridotite carbonation in ICDP Oman Drilling Project drill holes BA1B (400‐m deep) and BA3A (300‐m deep). Geochemical investigations of the carbonates in serpentinites indicate formation in the last 50 kyr, implying a distinctly different phase of alteration than the initial oceanic hydration and serpentinization of the Samail Ophiolite. The oldest carbonates (∼31 to >50 kyr) are localized calcite, dolomite, and aragonite veins, formed between 26°C and 43°C and related to focused fluid flow. Subsequent pervasive small amounts of dispersed carbonate precipitated in the last 1,000 years. Macroscopic brecciation and veining of the peridotite indicate that carbonation is influenced by tectonic features allowing infiltration of fluids over extended periods and at different structural levels such as along fracture planes and micro‐fractures and grain boundaries, causing large‐scale hydration of the ophiolite. The formation of dispersed carbonate is related to percolating fluids with
δ 18O lower than modern ground and meteoric water. Our study shows that radiocarbon investigations are an essential tool to interpret the carbonation history and that stable oxygen and carbon isotopes alone can result in ambiguous interpretations. -
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Abstract The nature and cause of deep earthquakes remain enduring unknowns in the field of seismology. We present new models of thermal structures of subducted slabs traced to mantle transition zone depths that permit a detailed comparison between slab pressure/temperature (
P/T ) paths and hydrated/carbonated mineral phase relations. We find a remarkable correlation between slabs capable of transporting water to transition zone depths in dense hydrous magnesium silicates with slabs that produce seismicity below ∼300‐km depth, primarily between 500 and 700 km. This depth range also coincides with theP/T conditions at which oceanic crustal lithologies in cold slabs are predicted to intersect the carbonate‐bearing basalt solidus to produce carbonatitic melts. Both forms of fluid evolution are well represented by sublithospheric diamonds whose inclusions record the existence of melts, fluids, or supercritical liquids derived from hydrated or carbonate‐bearing slabs at depths (∼300–700 km) generally coincident with deep‐focus earthquakes. We propose that the hydrous and carbonated fluids released from subducted slabs at these depths lead to fluid‐triggered seismicity, fluid migration, diamond precipitation, and inclusion crystallization. Deep focus earthquake hypocenters could track the general region of deep fluid release, migration, and diamond formation in the mantle. The thermal modeling of slabs in the mantle and the correlation between sublithospheric diamonds, deep focus earthquakes, and slabs at depth demonstrate a deep subduction pathway to the mantle transition zone for carbon and volatiles that bypasses shallower decarbonation and dehydration processes.
