Abstract Cuprous oxide ($$\hbox {Cu}{}_2\hbox {O}$$ ) has recently emerged as a promising material in solid-state quantum technology, specifically for its excitonic Rydberg states characterized by large principal quantum numbers (n). The significant wavefunction size of these highly-excited states (proportional to$$n^2$$ ) enables strong long-range dipole-dipole (proportional to$$n^4$$ ) and van der Waals interactions (proportional to$$n^{11}$$ ). Currently, the highest-lying Rydberg states are found in naturally occurring$$\hbox {Cu}_2\hbox {O}$$ . However, for technological applications, the ability to grow high-quality synthetic samples is essential. The fabrication of thin-film$$\hbox {Cu}{}_2\hbox {O}$$ samples is of particular interest as they hold potential for observing extreme single-photon nonlinearities through the Rydberg blockade. Nevertheless, due to the susceptibility of high-lying states to charged impurities, growing synthetic samples of sufficient quality poses a substantial challenge. This study successfully demonstrates the CMOS-compatible synthesis of a$$\hbox {Cu}{}_2\hbox {O}$$ thin film on a transparent substrate that showcases Rydberg excitons up to$$n = 8$$ which is readily suitable for photonic device fabrications. These findings mark a significant advancement towards the realization of scalable and on-chip integrable Rydberg quantum technologies.
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Roaming pathways and survival probability in real-time collisional dynamics of cold and controlled bialkali molecules
Abstract Perfectly controlled molecules are at the forefront of the quest to explore chemical reactivity at ultra low temperatures. Here, we investigate for the first time the formation of the long-lived intermediates in the time-dependent scattering of cold bialkali$$^{23}\hbox {Na}^{87}$$ Rb molecules with and without the presence of infrared trapping light. During the nearly 50 nanoseconds mean collision time of the intermediate complex, we observe unconventional roaming when for a few tens of picoseconds either NaRb or$$\hbox {Na}_2$$ and$$\hbox {Rb}_2$$ molecules with large relative separation are formed before returning to the four-atom complex. We also determine the likelihood of molecular loss when the trapping laser is present during the collision. We find that at a wavelength of 1064 nm the$$\hbox {Na}_2\hbox {Rb}_2$$ complex is quickly destroyed and thus that the$$^{23}\hbox {Na}^{87}$$ Rb molecules are rapidly lost.
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- Award ID(s):
- 1908634
- PAR ID:
- 10229582
- Publisher / Repository:
- Nature Publishing Group
- Date Published:
- Journal Name:
- Scientific Reports
- Volume:
- 11
- Issue:
- 1
- ISSN:
- 2045-2322
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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