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Title: Roaming pathways and survival probability in real-time collisional dynamics of cold and controlled bialkali molecules
Abstract

Perfectly controlled molecules are at the forefront of the quest to explore chemical reactivity at ultra low temperatures. Here, we investigate for the first time the formation of the long-lived intermediates in the time-dependent scattering of cold bialkali$$^{23}\hbox {Na}^{87}$$23Na87Rb molecules with and without the presence of infrared trapping light. During the nearly 50 nanoseconds mean collision time of the intermediate complex, we observe unconventional roaming when for a few tens of picoseconds either NaRb or$$\hbox {Na}_2$$Na2and$$\hbox {Rb}_2$$Rb2molecules with large relative separation are formed before returning to the four-atom complex. We also determine the likelihood of molecular loss when the trapping laser is present during the collision. We find that at a wavelength of 1064 nm the$$\hbox {Na}_2\hbox {Rb}_2$$Na2Rb2complex is quickly destroyed and thus that the$$^{23}\hbox {Na}^{87}$$23Na87Rb molecules are rapidly lost.

 
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Award ID(s):
1908634
NSF-PAR ID:
10229582
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
Nature Publishing Group
Date Published:
Journal Name:
Scientific Reports
Volume:
11
Issue:
1
ISSN:
2045-2322
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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