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Title: Electron‐Deficient Conjugated Materials via p–π* Conjugation with Boron: Extending Monomers to Oligomers, Macrocycles, and Polymers
Abstract

The extension of conjugated organoboranes from monomeric species to oligomers, macrocycles, and polymers offers access to a plethora of fascinating new materials. The p–π* conjugation between empty orbitals on boron and the conjugated linkers not only affects the electronic structure and optical properties, but also enables mutual interactions between electron‐deficient boron centers. The unique properties of these electron‐deficient π‐conjugated systems are exploited in highly luminescent materials, organic optoelectronic devices, and sensing applications.

 
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Award ID(s):
1954122 1664975
NSF-PAR ID:
10236098
Author(s) / Creator(s):
 ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Chemistry – A European Journal
Volume:
27
Issue:
9
ISSN:
0947-6539
Page Range / eLocation ID:
p. 2973-2986
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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