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Abstract The functionalization of polycyclic aromatic hydrocarbons (PAHs) via B←N Lewis pair formation offers an opportunity to judiciously fine‐tune the structural features and optoelectronic properties, to suit the demands of applications in organic electronic devices, bioimaging, and as sensitizers for singlet oxygen generation. We demonstrate that the N‐directed electrophilic borylation of 2,6‐di(pyrid‐2‐yl)anthracene offers access to linearly extended acene derivativesPy‐BR(R=Et, Ph, C₆F₅). In comparison to indeno‐fused 9,10‐diphenylanthracene, the formal “BN for CC” replacement inPy‐BRselectively lowers the LUMO, resulting in a much reduced HOMO–LUMO gap. An even more extended conjugated system with seven six‐membered rings in a row (Qu‐BEt) is obtained by borylation of 2,6‐di(quinolin‐8‐yl)anthracene. FluorinatedPy‐BPfshows particularly advantageous properties, including relatively lower‐lying HOMO and LUMO levels, strong yellow‐green fluorescence, and effective singlet oxygen sensitization, while resisting self‐sensitized conversion to its endoperoxide. 

Abstract Polycationic macrocycles are attractive as they display unique molecular switching capabilities arising from their redox properties. Although diverse polycationic macrocycles have been developed, those based on cationic boron systems remain very limited. We present herein the development of novel polycationic macrocycles by introducing organoboronium moieties into a conjugated organoboron macrocyclic framework. These macrocycles consist of four bipyridylboronium units that are connected by fluorene and either electron‐deficient arylborane or electron‐rich arylamine moieties. Electrochemical studies reveal that the macrocycles undergo reversible multi‐step redox processes with transfer of up to 10 electrons. Switchable electrochromic behavior is demonstrated via spectroelectrochemical studies and the observed color changes are rationalized by correlation with computed electronic transitions using DFT methods. 

Abstract The extension of conjugated organoboranes from monomeric species to oligomers, macrocycles, and polymers offers access to a plethora of fascinating new materials. The p–π* conjugation between empty orbitals on boron and the conjugated linkers not only affects the electronic structure and optical properties, but also enables mutual interactions between electron‐deficient boron centers. The unique properties of these electron‐deficient π‐conjugated systems are exploited in highly luminescent materials, organic optoelectronic devices, and sensing applications. 

Abstract We introduce a new boron‐doped cyclophane, the hexabora[1₆]cyclophaneB6‐^FMes, in which six tricoordinate borane moieties alternate with short conjugatedp‐phenylene linkers. Exocyclic 2,4,6‐tris(trifluoromethyl)phenyl (^FMes) groups serve not only to further withdraw electron density but at the same time sterically shield the boron atoms, resulting in a macrocycle that is both highly electron‐deficient and stable. The optical and electronic properties are compared with those of related linear oligomers and the electronic structure is further evaluated by computational methods. The studies uncover unique properties ofB6‐^FMes, including a low‐lying and extensively delocalized LUMO and a wide HOMO–LUMO gap, which arise from the combination of a cyclic π‐system, strong electronic communication between the closely spaced borons, and the attachment of electron‐deficient pendent groups. The binding of small anions to the electron‐deficient macrocycle and molecular model compounds is investigated and emissive exciplexes are detected in aromatic solvents. 

Abstract The past decade has witnessed tremendous advances in the synthesis of polymers that contain elements from the main groups beyond those found in typical organic polymers. Unique properties that arise from dramatic differences in bonding and molecular geometry, electronic structure, and chemical reactivity, are exploited in diverse application fields. Herein we highlight recent advances in inorganic backbone polymers, discuss how Lewis acid/base functionalization of polymers results in unprecedented reactivity, and survey conjugated hybrids with unique electronic structures for sensor and device applications. 

Abstract A new B–N functionalized polyaromatic building block for conjugated hybrid polymers is developed. Bromine‐functionalized dipyridylfluorene is first subjected to Lewis‐base‐directed electrophilic borylation and subsequently incorporated into conjugated polymers via transition‐metal‐catalyzed cross‐coupling reactions. The borane monomer exhibits bright blue luminescence in solution, as a result of the rigid ladder‐type structure generated upon electrophilic borylation. Yamamoto coupling gives rise to a homopolymer and Stille coupling to a vinylene‐bridged copolymer. Polymerization of the BN‐fused ladder molecules leads to large bathochromic shifts in absorption and emission, which are most pronounced for the vinylene‐bridged copolymer. The polymers display strong luminescence in solution with quantum yields of 55% and 78% and sub‐ns fluorescence lifetimes; the copolymer also exhibits bright yellow luminescence in the solid state when precipitated from solution. 

Applications of highly electron-deficient organoborenium ions in conjugated materials remain scarce due to their low stability toward air and moisture. We report here the preparation of benzo[ d ]dithieno[ b , f ]borepinium ions as air-stable π-conjugated heterocycles and their conversion into the first dimeric borenium cations, which exhibit very low lying LUMOs and enhanced fluorescence as a result of extended conjugation. 

We report a p-π* conjugated organic molecule based on triarylborane as n-type organic semiconductor with unique alcohol solubility. Its favorable alcohol solubility even in the absence of polar side chains is mainly due to the large dipole moment and enhanced flexibility of the conjugated backbone once the boron atom is embedded. The p-π* conjugation directly affects the electronic structure as the LUMO is fully delocalized, including the boron atom, whereas the HOMO has the boron atom residing on a node. As a result, the molecule exhibits low-lying LUMO/HOMO energy levels of −3.61 eV/−5.73 eV paired with a good electron mobility of 1.37 × 10 −5 cm 2 V −1 s −1 . We further demonstrate its application as an electron acceptor in alcohol-processed organic solar cells (OSCs). To our best knowledge, this p-π* conjugated molecule is the first alcohol-processable non-fullerene electron acceptor, a feature that is in strong demand for environmentally friendly processing of OSCs.