An official website of the United States government
For this experimental study on evaporation of water from graphene, two graphene samples with different thickness and microstructure were used. Figure 1 shows the representative optical and scanning electron microscope (SEM) images of the two samples. Sample 1, shown in Figure 1a-b, is a 3 to 4 atomic layer of continuous graphene sheet grown on copper substrate via chemical vapor deposition (CVD) and was subsequently transferred to a quartz substrate using a wet chemical method reported previously [5]. The graphene thickness is at 1.2 nm to 1.4 nm, as measured by Atomic Force Microscopy. Sample 2, shown in Figure 1c-d, represents an inkjet-printed reduced graphene oxide on silicon and subsequently treated with a direct pulsed laser writing (DPLW) process for surface 3D-nanostructuring. The layer thickness is between 6 µm and 7 µm.
more »
« less
Photoacoustic laser streaming with non-plasmonic metal ion implantation in transparent substrates
Photoacoustic laser streaming provides a versatile technique to manipulate liquids and their suspended objects with light. However, only gold was used in the initial demonstrations. In this work, we first demonstrate that laser streaming can be achieved with common non-plasmonic metals such as Fe and W by their ion implantations in transparent substrates. We then investigate the effects of ion dose, substrate material and thickness on the strength and duration of streaming. Finally, we vary laser pulse width, repetition rate and power to understand the observed threshold power for laser streaming. It is found that substrate thickness has a negligible effect on laser streaming down to 0.1 mm, glass and quartz produce much stronger streaming than sapphire because of their smaller thermal conductivity, while quartz exhibits the longest durability than glass and sapphire under the same laser intensity. Compared with Au, Fe and W with higher melting points show a longer lifetime although they require a higher laser intensity to achieve a similar speed of streaming. To generate a continuous laser streaming, the laser must have a minimum pulse repetition rate of 10 Hz and meet the minimum pulse width and energy to generate a transient vapor layer. This vapor layer enhances the generation of ultrasound waves, which are required for observable fluid jets. Principles of laser streaming and temperature simulation are used to explain these observations, and our study paves the way for further materials engineering and device design for strong and durable laser streaming.
more »
« less
- Award ID(s):
- 1932734
- PAR ID:
- 10264988
- Publisher / Repository:
- Optical Society of America
- Date Published:
- Journal Name:
- Optics Express
- Volume:
- 29
- Issue:
- 14
- ISSN:
- 1094-4087; OPEXFF
- Format(s):
- Medium: X Size: Article No. 22567
- Size(s):
- Article No. 22567
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
We report a quantum-well-intermixing-free three-section mode-locked laser diode at 1580nm, featuring 1.70 psec pulse width. The fixed-point frequency analysis shows four different laser parameters conducive for compensating repetition rate and carrier frequency variations in space environment.more » « less
-
Abstract Sapphire is an attractive material that stands to benefit from surface functionalization effects stemming from micro/nanostructures. Here we investigate the use of ultrafast lasers for fabricating sapphire nanostructures by exploring the relationship between irradiation parameters, morphology change, and selective etching. In this approach a femtosecond laser pulse is focused on the substrate to change the crystalline morphology to amorphous or polycrystalline, which is characterized by examining different vibrational modes using Raman spectroscopy. The irradiated regions are removed using a subsequent hydrofluoric acid etch. Laser confocal measurements quantify the degree of selective etching. The results indicate a threshold laser pulse intensity required for selective etching. This process was used to fabricate hierarchical sapphire nanostructures over large areas with enhanced hydrophobicity, with an apparent contact angle of 140 degrees, and a high roll-off angle, characteristic of the rose petal effect. Additionally, the structures have high broadband diffuse transmittance of up to 81.8% with low loss, with applications in optical diffusers. Our findings provide new insights into the interplay between the light-matter interactions, where Raman shifts associated with different vibrational modes can predict selective etching. These results advance sapphire nanostructure fabrication, with applications in infrared optics, protective windows, and consumer electronics.more » « less
-
In the Raman probing of multilayer thin film materials, the intensity of the measured Raman scattered light will be impacted by the thickness of the thin film layers. The Raman signal intensity will vary non-monotonically with thickness due to interference from the multiple reflections of both the incident laser light and the Raman scattered light of thin film interfaces. Here, a method for calculating the Raman signal intensity from a multilayer thin film system based on the transfer matrix method with a rigorous treatment of the Raman signal generation (discontinuity) is presented. This calculation methodology is valid for any thin film stack with an arbitrary number of layers with arbitrary thicknesses. This approach is applied to several thin film material systems, including silicon-on-sapphire thin films, graphene on Si with a SiO2capping layer, and multilayer MoS2with the presence of a gap between layers and substrate. Different applications where this method can be used in the Raman probing of thin film material properties are discussed.more » « less
-
Chan, Jenna F; Rajaraman, Swaminathan (Ed.)We have successfully demonstrated a novel, passive layer-free, curved piezoelectric micromachined ultrasound transducer (PMUT) array, using a sacrificial curved glass template and 30% scandium-doped aluminum nitride (Sc-AlN) as the active layer. The PMUTs were fabricated using a curved, suspended borosilicate glass template created via a chip-scale glass-blowing technique, onto which electrodes and the piezoelectric layer were deposited. The glass layer was thereafter selectively removed. We characterized the performance of a 13 × 13 curved PMUT (cPMUT) array using an electrical impedance analyzer, a Laser Doppler Vibrometer (LDV), and hydrophone pressure measurements. Our results reveal a device resonance frequency of approximately 1.8 MHz in air, with LDV analysis indicating a significantly enhanced low-frequency response of 1.68 nm/V—a fivefold improvement over conventional curved PMUTs with a passive layer. Additionally, acoustic characterization in water showed that this array generates an acoustic pressure of approximately 80 kPa at a 4.4 mm focal distance, with a beam width of 5 mm, and achieves a spatial peak pulse average intensity (ISPPA) of 216 mW/cm2 when driven off-resonance. Furthermore, we demonstrate 20-degree steering capability using our data acquisition system. These advancements highlight significant potential for enhancing the precision and efficacy of medical imaging and therapeutic applications, particularly in ultrasonic diagnostics and treatments.more » « less
