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1. Ratepayer Perspectives on Mid- to Large-Scale Solar Development on Long Island, NY: Lessons for Reducing Siting Conflict through Supported Development Types

   https://doi.org/10.3390/en13215628  

   Schelly, Chelsea ; Prehoda, Emily ; Price, Jessica ; Delach, Aimee ; Thapaliya, Rupak ( November 2020 , Energies)

   The state of New York has ambitious mandates for reducing greenhouse gas emissions and increasing renewable energy generation. Solar energy will play an important role in reducing greenhouse gas emissions from the electric energy sector. Concerns over solar installations’ impacts to host communities and the environment have led to growing conflicts over solar energy siting on Long Island, in other parts of New York, and throughout the US. Understanding community members’ perspectives is critical for reducing conflict. Solar energy can be deployed more quickly and at lower cost if projects are structured to address the concerns and meet the needs of the community. This paper presents the results of a survey of residential utility ratepayers that examined their perceptions, preferences, and priorities concerning mid- to large-scale solar development on Long Island (250 kW and larger). The survey asked respondents to consider specific installation types, financial models, and other aspects of solar development. Results indicate that respondents were overwhelmingly supportive of mid- to large-scale solar development in their communities. The most highly supported development types were solar systems on rooftops and solar systems that are co-located with other land uses (mixed use) at a particular site, such as parking canopies, landfills,more »or integration with agriculture. The most highly supported financial models included privately funded projects by local developers and community solar projects. The largest concern about solar development expressed by respondents did not involve tree removal or visibility (as initially hypothesized to be the most significant considerations) but rather the fairness of the distribution of economic benefits associated with solar development. This paper provides concrete insight into particular models of solar development that may invoke less conflict and more community support.« less
2. High-throughput sequencing for community analysis: the promise of DNA barcoding to uncover diversity, relatedness, abundances and interactions in spider communities

   https://doi.org/10.1007/s00427-020-00652-x  

   Kennedy, Susan R. ; Prost, Stefan ; Overcast, Isaac ; Rominger, Andrew J. ; Gillespie, Rosemary G. ; Krehenwinkel, Henrik ( March 2020 , Development Genes and Evolution)

   Abstract Large-scale studies on community ecology are highly desirable but often difficult to accomplish due to the considerable investment of time, labor and, money required to characterize richness, abundance, relatedness, and interactions. Nonetheless, such large-scale perspectives are necessary for understanding the composition, dynamics, and resilience of biological communities. Small invertebrates play a central role in ecosystems, occupying critical positions in the food web and performing a broad variety of ecological functions. However, it has been particularly difficult to adequately characterize communities of these animals because of their exceptionally high diversity and abundance. Spiders in particular fulfill key roles as both predator and prey in terrestrial food webs and are hence an important focus of ecological studies. In recent years, large-scale community analyses have benefitted tremendously from advances in DNA barcoding technology. High-throughput sequencing (HTS), particularly DNA metabarcoding, enables community-wide analyses of diversity and interactions at unprecedented scales and at a fraction of the cost that was previously possible. Here, we review the current state of the application of these technologies to the analysis of spider communities. We discuss amplicon-based DNA barcoding and metabarcoding for the analysis of community diversity and molecular gut content analysis for assessing predator-prey relationships. We alsomore »highlight applications of the third generation sequencing technology for long read and portable DNA barcoding. We then address the development of theoretical frameworks for community-level studies, and finally highlight critical gaps and future directions for DNA analysis of spider communities.« less
3. Transformation, reaction and organization of functional nanostructures using solution-based microreactor-assisted nanomaterial deposition for solar photovoltaics

   https://doi.org/10.1557/s43581-022-00035-x  

   Doddapaneni, V. Vinay K. ; Dhas, Jeffrey A. ; Chang, Alvin ; Choi, Chang-Ho ; Han, Seung-Yeol ; Paul, Brian K. ; Chang, Chih-Hung ( July 2022 , MRS Energy & Sustainability)

   Microreactor-Assisted Nanomaterial Deposition (MAND) process offers unique capabilities in achieving large size and shape control levels while providing a more rapid path for scaling via process intensification for nanomaterial production. This review highlights the application of continuous flow microreactors to synthesize, assemble, transform, and deposit nanostructured materials for Solar Photovoltaics, the capabilities of MAND in the field, and the potential outlook of MAND.

   Microreactor-Assisted Nanomaterial Deposition (MAND) is a promising technology that synthesizes reactive fluxes and nanomaterials to deposit nanostructured materials at the point of use. MAND offers precise control over reaction, organization, and transformation processes to manufacture nanostructured materials with distinct morphologies, structures, and properties. In synthesis, microreactor technology offers large surface-area-to-volume ratios within microchannel structures to accelerate heat and mass transport. This accelerated transport allows for rapid changes in reaction temperatures and concentrations, leading to more uniform heating and mixing in the deposition process. The possibility of synthesizing nanomaterials in the required volumes at the point of application eliminates the need to store and transport potentially hazardous materials. Further, MAND provides new opportunities for tailoring novel nanostructures and nano-shaped features, opening the opportunity to assemble unique nanostructures and nanostructured thin films. MAND processes control the heat transfer,more »mass transfer, and reaction kinetics using well-defined microstructures of the active unit reactor cell that can be replicated at larger scales to produce higher chemical production volumes. This critical feature opens a promising avenue in developing scalable nanomanufacturing. This paper reviews advances in microreactor-assisted nanomaterial deposition of nanostructured materials for solar photovoltaics. The discussions review the use of microreactors to tailor the reacting flux, transporting to substrate surfaces via controlling process parameters such as flow rates, pH of the precursor solutions, and seed layers on the formation and/or transformation of intermediary reactive molecules, nanoclusters, nanoparticles, and structured assemblies. In the end, the review discusses the use of an industrial scale MAND to apply anti-reflective and anti-soiling coatings on the solar modules in the field and details future outlooks of MAND reactors.

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4. Photovoltaic Response of Thin-Film CdTe Solar Cells under Accelerated Neutron Radiation in a TRIGA Reactor

   Powell, Kaden ; Lund, Matthew ; Wang, Meng-Jen ; Qian, Yang ; Magginetti, David ; Reese, Matthew ; Cazalas, Edward ; Sjoden, Glenn ; Yoon, Heayoung ( June 2020 , Electronic Materials Symposium)

   Cadmium telluride (CdTe) solar cells are a promising photovoltaic (PV) technology for producing power in space owing to their high-efficiency (> 22.1 %), potential for specific power, and cost-effective manufacturing processes. In contrast to traditional space PVs, the high-Z (atomic number) CdTe absorbers can be intrinsically robust under extreme space radiation, offering long-term stability. Despite these advantages, the performance assessment of CdTe solar cells under high-energy particle irradiation (e.g., photons, neutrons, charged particles) is limited in the literature, and their stability is not comprehensively studied. In this work, we present the PV response of n-CdS / p-CdTe PVs under accelerated neutron irradiation. We measure PV properties of the devices at different neutron/photon doses. The equivalent dose deposited in the CdTe samples is simulated with deterministic and Monte Carlo radiation transport methods. Thin-film CdTe solar cells were synthesized on a fluorine-doped tin oxide (FTO) coated glass substrate (≈ 4 cm × 4 cm). CdS:O (≈ 100 nm) was reactively RF sputtered in an oxygen/argon ambient followed by a close-spaced sublimation deposition of CdTe (≈ 3.5 μm) in an oxygen/helium ambient. The sample was exposed to a 10 min vapor CdCl2 in oxygen/helium ambient at 430˚C. The samples were exposed to amore »wet CuCl2 solution prior to anneal 200ºC. A gold back-contact was formed on CdTe via thermal evaporation. The final sample contains 16 CdTe devices. For neutron irradiation, we cleaved the CdTe substrate into four samples and exposed two samples to ≈ 90 kW reactor power neutron radiation for 5.5 hours and 8.2 hours, respectively, in our TRIGA (Training, Research, Isotopes, General Atomics) reactor. We observed a noticeable color change of the glass substrates to brown after the neutron/gamma reactor exposure. Presumably, the injected high-energy neutrons caused the breaking of chemical bonds and the displacement of atoms in the glass substrates, creating point defects and color centers. The I-V characteristics showed noticeable deterioration with over 8 hour radiations. Specifically, the saturation current of the control devices was ≈ 25 nA increasing to 1 μA and 10 μA for the 5.5-hour and 8.2-hour radiated samples, respectively. The turn-on voltage of the control devices (≈ 0.85 V) decreased with the irradiated sample (≈ 0.75 V for 5.5-hour and ≈ 0.5 V for 8.2-hour exposures), implying noticeable radiation damage occurred at the heterojunction. The higher values of the ideality factor for irradiated devices (n > 2.2) compared to that of the control devices (n ≈ 1.3) also support the deterioration of the p-n junction. We observed the notable decrease in shunt resistance (RSH) and the increase in series resistance (Rs) with the neutron dose. It is possible that Cu ions introduced during the CuCl2 treatment may migrate into CdTe grain boundaries (GBs). The presence of Cu ions at GBs can create additional leakage paths for photocarrier transport, deteriorating the overall PV performance. We estimated the radiation dose of CdTe in comparison to Si (conventional PV) using a UUTR model (e.g., MCNP6 2D UTR Reactor simulations). In this model, we simulated Si and CdTe at the center point of the triangular fuel lattice and used an “unperturbed flux” tally in the water. Our simulations yielded a dose rate of 6916 Gy/s of neutrons and 16 Gy/s of photons for CdTe, and 1 Gy/s of neutrons and 21 Gy/s of photons for Si (doses +/- <1%). The large dose rate of neutrons in CdTe is mainly attributed to the large thermal neutron absorption cross-section of 113Cd. Based on this estimation, we calculate that the exposure of our CdTe PVs is equivalent to several million years in LEO (Low-Earth Orbit), or about 10,000 years for Si in LEO. Currently, we are working on a low-dose neutron/photon radiation on CdTe PVs and their light I-Vs and microstructural characterizations to gain better understanding on the degradation of CdTe PVs.« less
5. Remote-Region Interior Alaska Community Survey with Two Statistical Measures: Arctic Indigenous Entrepreneurial Readiness (ER); and Remote-Region Digital Technology Needs and Skills (DT).

   https://doi.org/10.18739/A20R9M54S  

   Pasch, Timothy ; Kuhlke, Olaf ; Linton, Renee ( January 2021 )

   Abstract

   Between 2018 and 2021 PIs for National Science Foundation Awards # 1758781 and 1758814 EAGER: Collaborative Research: Developing and Testing an Incubator for Digital Entrepreneurship in Remote Communities, in partnership with the Tanana Chiefs Conference, the traditional tribal consortium of the 42 villages of Interior Alaska, jointly developed and conducted large-scale digital and in-person surveys of multiple Alaskan interior communities. The survey was distributed via a combination of in-person paper surveys, digital surveys, social media links, verbal in-person interviews and telephone-based responses. Analysis of this measure using SAS demonstrated the statistically significant need for enhanced digital infrastructure and reworked digital entrepreneurial and technological education in the Tanana Chiefs Conference region. 1. Two statistical measures were created during this research: Entrepreneurial Readiness (ER) and Digital Technology needs and skills (DT), both of which showed high measures of internal consistency (.89, .81). 2. The measures revealed entrepreneurial readiness challenges and evidence of specific addressable barriers that are currently preventing (serving as hindrances) to regional digital economic activity. The survey data showed statistically significant correlation with the mixed-methodological in-person focus groups and interview research conducted by the PIs and TCC collaborators in Hughes and Huslia, AK, which further corroborated stated barriers to entrepreneurship development in the region. 3. Data generated by the survey and fieldwork is maintained by the Tanana Chiefs Conference under data sovereignty agreements. The survey and focus group data contains aggregated statistical/empirical data as well as qualitative/subjective detail that runs the risk of becoming personally identifiable especially due to (but not limited to) to concerns with exceedingly small Arctic community population sizes. 4. This metadata is being provided in order to serve as a record of the data collection and analysis conducted, and also to share some high-level findings that, while revealing no personal information, may be helpful for policymaking, regional planning and efforts towards educational curricular development and infrastructural investment. The sample demographics consist of 272 women, 79 men, and 4 with gender not indicated as a response. Barriers to Entrepreneurial Readiness were a component of the measure. Lack of education is the #1 barrier, followed closely by lack of access to childcare. Among women who participated in the survey measure, 30% with 2 or more children report lack of childcare to be a significant barrier to entrepreneurial and small business activity. For entrepreneurial readiness and digital economy, the scales perform well from a psychometric standpoint. The summary scores are roughly normally distributed. Cronbach’s alphas are greater than 0.80 for both. They are moderately correlated with each other (r &#61; 0.48, p &amp;amp;amp;lt; .0001). Men and women do not differ significantly on either measure. Education is significantly related to the digital economy measure. The detail provided in the survey related to educational needs enabled optimized development of the Incubator for Digital Entrepreneurship in Remote Communities. Enhanced digital entrepreneurship training with clear cultural linkages to traditions and community needs, along with additional childcare opportunities are two among several specific recommendations provided to the TCC. The project PIs are working closely with the TCC administration and community members related to elements of culturally-aligned curricular development that respects data tribal sovereignty, local data management protocols, data anonymity and adherence to human subjects (IRB) protocols. While the survey data is currently embargoed and unable to be submitted publicly for reasons of anonymity, the project PIs are working with the NSF Arctic Data Center towards determining pathways for sharing personally-protected data with the larger scientific community. These approaches may consist of aggregating and digitally anonymizing sensitive data in ways that cannot be de-aggregated and that meet agency and scientific community needs (while also fully respecting and protecting participants’ rights and personal privacy). At present the data sensitivity protocols are not yet adapted to TCC requirements and the datasets will remain in their care.
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